228 research outputs found
Syntheses, characterizations, crystal structures, DFT/TD‐DFT, luminescence behaviors and cytotoxic effect of bicompartmental Zn (II)‐dicyanamide Schiff base coordination polymers: An approach to apoptosis, autophagy and necrosis type classical cell death
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Field-Induced Magnetic Transitions in Metal Phosphonates with Ladderlike Chain Structures: (NH3C6H4NH3)M2(hedpH)2H2O [M = Fe, Co, Mn, Zn; hedp = C(CH3)(OH)(PO3)2]
No full textCoordination Properties of Klaeui's Tripodal Oxygen Donor toward Zirconium(IV)
No full textThe coordination properties of [(η5-C5H5)Co{PR2(O)}3]- (R = OEt (LOEt-), Et (LEt-)) toward Zr(IV) have been investigated and compared to related cyclopentadienyl complexes. Addition of 2 equiv of LOEt- to [ZrCl4(THF)2] yields labile [Zr(LOEt)2Cl2] (2), which undergoes Arbuzov dealkylation to yield a dinuclear, seven-coordinate complex 1. Reaction of 2 with MeLi yields the metathesis product LiLOEt. Addition of 2 equiv of AgOTos to 2 affords octahedral [Zr(LOEt)2](OTos)2 (3). Reaction of [ZrCpCl3] with LOEt- leads to Cp- displacement to give [ZrLOEtCl3] (4). Addition of 2 equiv of LEt- to [ZrCl4(THF)2] yields octahedral [Zr(LEt)2](Cl)2 (5). Compounds 1, 3, 4, and 5 have been characterized by X-ray crystallography
Nonanuclear Ruthenium Carbonyl Cluster Complexes with a Novel Metallic Skeleton: Pentagonal Bipyramid with Two Equatorial Edges Spanned by Metal Atoms
No full textMagnetic Properties of Metal Diphosphonate Compounds with One-Dimensional Chain Structures
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