Removal of ammonium through adsorptive coagulation- flocculation process in drinking water treatment

The nitrogen compounds such as ammonia (NH3) and ammonium (NH4 + ) are the most common pollutants in surface water, groundwater and wastewater. The increasing amount of NH4 + in the source of water supply emitted from agricultural activities, sewage and industries has caused problems to the existing drinking water treatment system to remove it to meet the required drinking water standards. The adsorption removal of NH4 + using natural zeolites and thus the adsorptive coagulation/flocculation process (ACF) was studied aiming for application in drinking water treatment process. The natural zeolites (i.e. NZ01, NZ02, and NZ03) were characterized using scanning electron microscope (SEM), X-ray diffractometer (XRD), nitrogen adsorption-desorption (NAD) analyzer, Fourier transform infrared spectrophotometer (FTIR), X-ray fluorescence (XRF) spectrophotometer. The cation exchange capacity (CEC) of natural zeolites was also determined. The NH4 + removal experiments were conducted in batch adsorption and adsorptive coagulation/flocculation (ACF) methods carried out at various experimental conditions. It was found that all natural zeolites used were of Clinoptilolite and Heundlite types. Natural zeolite (NZ01) had the highest (64.42 cmol/kg) cation exchange capacity (CEC) compared to NZ02 and NZ03 which both had 62.18 cmol/kg and 59.97 cmol/kg respectively. The time taken for NH4 + adsorption performance to reach equilibrium was detected in 12 hours contact time with adsorption capacity of 2.5mg/g observed at NH4 + concentration of 20 mg/l and pH 7. The high NH4 + removal was observed at pH 8 with 2.76 mg/g adsorption capacity. The NH4 + adsorption capacity increased with increasing the initial NH4 + concentration from 1 mg/l to 200 mg/l. Adsorption data followed the Langmuir isotherm at 34.48mg/g maximum adsorption capacity and it shows that the surface of NZ01 is homogeneous. The adsorption process obeys pseudo-second order kinetic models. The thermodynamic properties (?G, ?S, and ?H) were also studied at different temperatures (30, 40, 50, 70°C). The negative value of ?H for NH4 + adsorption confirmed the process is exothermic in nature. The adsorptive coagulation-flocculation (ACF) results revealed that the NH4 + removal increased with adsorbent dosage, ranging from 0.2 to 2.0 mg/ml at 5 hours contact time. The percentage removal of NH4 + in ACF for the effect of initial NH4 + concentrations (i.e. 1 mg/l, 20 mg/l, 50 mg/l and 100 mg/l) showed the increasing value up to 20% efficiency compared to adsorption. The NH4 + adsorption isotherm data for ACF followed the Temkin isotherm model and the kinetic adsorption data was observed to obey a pseudo-second order. All these results demonstrate that the natural zeolites can be potentially used for the removal of NH4 + in drinking water treatment process

Removal of ammonium through adsorptive coagulation- flocculation process in drinking water treatment

The nitrogen compounds such as ammonia (NH3) and ammonium (NH4 + ) are the most common pollutants in surface water, groundwater and wastewater. The increasing amount of NH4 + in the source of water supply emitted from agricultural activities, sewage and industries has caused problems to the existing drinking water treatment system to remove it to meet the required drinking water standards. The adsorption removal of NH4 + using natural zeolites and thus the adsorptive coagulation/flocculation process (ACF) was studied aiming for application in drinking water treatment process. The natural zeolites (i.e. NZ01, NZ02, and NZ03) were characterized using scanning electron microscope (SEM), X-ray diffractometer (XRD), nitrogen adsorption-desorption (NAD) analyzer, Fourier transform infrared spectrophotometer (FTIR), X-ray fluorescence (XRF) spectrophotometer. The cation exchange capacity (CEC) of natural zeolites was also determined. The NH4 + removal experiments were conducted in batch adsorption and adsorptive coagulation/flocculation (ACF) methods carried out at various experimental conditions. It was found that all natural zeolites used were of Clinoptilolite and Heundlite types. Natural zeolite (NZ01) had the highest (64.42 cmol/kg) cation exchange capacity (CEC) compared to NZ02 and NZ03 which both had 62.18 cmol/kg and 59.97 cmol/kg respectively. The time taken for NH4 + adsorption performance to reach equilibrium was detected in 12 hours contact time with adsorption capacity of 2.5mg/g observed at NH4 + concentration of 20 mg/l and pH 7. The high NH4 + removal was observed at pH 8 with 2.76 mg/g adsorption capacity. The NH4 + adsorption capacity increased with increasing the initial NH4 + concentration from 1 mg/l to 200 mg/l. Adsorption data followed the Langmuir isotherm at 34.48mg/g maximum adsorption capacity and it shows that the surface of NZ01 is homogeneous. The adsorption process obeys pseudo-second order kinetic models. The thermodynamic properties (?G, ?S, and ?H) were also studied at different temperatures (30, 40, 50, 70°C). The negative value of ?H for NH4 + adsorption confirmed the process is exothermic in nature. The adsorptive coagulation-flocculation (ACF) results revealed that the NH4 + removal increased with adsorbent dosage, ranging from 0.2 to 2.0 mg/ml at 5 hours contact time. The percentage removal of NH4 + in ACF for the effect of initial NH4 + concentrations (i.e. 1 mg/l, 20 mg/l, 50 mg/l and 100 mg/l) showed the increasing value up to 20% efficiency compared to adsorption. The NH4 + adsorption isotherm data for ACF followed the Temkin isotherm model and the kinetic adsorption data was observed to obey a pseudo-second order. All these results demonstrate that the natural zeolites can be potentially used for the removal of NH4 + in drinking water treatment process

Characterization of natural zeolite for adsorptive removal of antibiotics from aqueous solution

The persistent existence of antibiotics in sewage wastewater treatment plants in recent years has emerged as a serious concern. In this study, natural zeolite (NZ02) obtained from China was employed as an adsorbent to remove tetracycline (TC) from aqueous solution. The characterization results show that the NZ02 consists of quartz, clinoptilolite-Na and heulandite having the CEC of 62.18cmol/kg and the surface area of 36.646m2/g. Adsorption results show that the maximum adsorption capacity of TC on NZ02 was 19.30mg/g and the equilibrium data followed theLangmuir adsorption isotherm model

Natural zeolite characterization for adsorptive coagulation flocculation (ACF) removal of ammonium in drinking water treatment process

The naturally occurring zeolite (N Z01) was characterized and used as an adsorbent for the removal of ammonium (N-NH4+) from water. The characterization results show that the NZ01 is mainly composed of clinoptilolite, quartz and plagioclase and has the cation-exchange capacity (CEC) of 64 cmol/kg. Batch adsorption results show that the best ammonia removal was at pH close to that of the natural water (= pH 7). The increase in initial ammonium nitrogen concentration from 5 to 50 ppm resulted in an increase of the adsorption capacity from 0.64 to 15.1 mg NH4+-N/g. The Jar test experiments indicate the introduction of the NZ01 enhanced the ammonium removal efficiency. All these results demonstrate that the NZ01 is potential to be used for the removal of ammonium in drinking water treatm ent process