2 research outputs found
Estimation of speed of sound in binary mixtures of cyclohexane with benzene, benzaldehyde or cyclohexylamine, and, cyclohexylamine with benzene in the temperature range (293.15–323.15) K employing empirical and theoretical models
492-497Speed of sound in
the binary mixtures of cyclohexane with benzene, benzaldehyde or
cyclohexylamine, and, that of cyclohexylamine with benzene over the entire
composition range and at (293.15, 303.15, 313.15 and 323.15) K has been
estimated employing several models, viz., Nomoto model (NM), Van Dael model
(VM), Junjie
model (JM), Ernst et al.
model (EM), Impedance model (IM), Collision factor theory (CFT), Intermolecular
free length theory (FLT), and, Prigogine-Flory-Patterson
theory (PFPT). <span style="font-size:9.0pt;
mso-bidi-font-size:11.0pt" lang="EN-US">The maximum deviations between estimated and
experimental speed of sound by different models NM, VDM, JM, EM, IM, CFT, FLT,
and PFPT are –24.5, –23.0, 20.2, –48.3, –22.1, –24.9, 25.0, and 24.4 m s-1,
respectively.
The values of standard percentage deviations for NM, VDM, JM, EM, IM, CFT, FLT,
and PFPT models are in the range of 0.3–1.4,
0.3–1.4, 0.3–1.1, 0.3–2.7, 0.5–1.2, 0.2–1.4, 0.4–1.2, and
0.4–1.2%, respectively. Considering the overall results, the FLT model predicts
the most accurate values for speed of sound while the EM model gives the least
accurate values.
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