6 research outputs found
Palladium-Catalyzed Direct C–H Carbonylation of Free Primary Benzylamines: A Synthesis of Benzolactams
A protocol for palladium-catalyzed
C–H carbonylation of
readily available free primary benzylamines using NH<sub>2</sub> as
the chelating group under an atmospheric pressure of CO has been achieved,
providing a general, atom- and step-economic approach to benzolactams,
an important structural motif found in many biologically active compounds.
Application of this new method is also exemplified in the concise
syntheses of two bioactive molecules
Visible-Light-Active Titanium Sulfonate Framework for Photocatalytic Organic Synthesis
In this work, the first visible-light-active titanium
sulfonate
metal–organic framework (denoted as FIR-138) with 2-fold interpenetrated
srs topology was synthesized by employing 2,5-dihydroxy-1,4-benzenedisulfonic
acid (H4DOBSC) as ligands. The strong chelating coordination
ability of the hydroxyl and sulfonate O atoms from H4DOBSC
endows the framework of FIR-138 with good stability, while the formation
of the Ti-phenolic motif ensures excellent visible light absorption
with a bandgap (Eg) of 1.74 eV. More importantly,
the extensive titanium active sites within the structure could trap
the photogenerated electrons and promote the charge separation effectively,
attributed to the excellent visible light photocatalytic performance
in organic reaction. FIR-138’s capability to harness visible
light for photocatalytic reactions presents a promising advancement
in the field of Ti-MOF photocatalysts. These results provide valuable
insights and open up new avenues for the rational design and synthesis
of visible-light-active Ti-MOF photocatalysts
Visible-Light-Active Titanium Sulfonate Framework for Photocatalytic Organic Synthesis
In this work, the first visible-light-active titanium
sulfonate
metal–organic framework (denoted as FIR-138) with 2-fold interpenetrated
srs topology was synthesized by employing 2,5-dihydroxy-1,4-benzenedisulfonic
acid (H4DOBSC) as ligands. The strong chelating coordination
ability of the hydroxyl and sulfonate O atoms from H4DOBSC
endows the framework of FIR-138 with good stability, while the formation
of the Ti-phenolic motif ensures excellent visible light absorption
with a bandgap (Eg) of 1.74 eV. More importantly,
the extensive titanium active sites within the structure could trap
the photogenerated electrons and promote the charge separation effectively,
attributed to the excellent visible light photocatalytic performance
in organic reaction. FIR-138’s capability to harness visible
light for photocatalytic reactions presents a promising advancement
in the field of Ti-MOF photocatalysts. These results provide valuable
insights and open up new avenues for the rational design and synthesis
of visible-light-active Ti-MOF photocatalysts
Visible-Light-Active Titanium Sulfonate Framework for Photocatalytic Organic Synthesis
In this work, the first visible-light-active titanium
sulfonate
metal–organic framework (denoted as FIR-138) with 2-fold interpenetrated
srs topology was synthesized by employing 2,5-dihydroxy-1,4-benzenedisulfonic
acid (H4DOBSC) as ligands. The strong chelating coordination
ability of the hydroxyl and sulfonate O atoms from H4DOBSC
endows the framework of FIR-138 with good stability, while the formation
of the Ti-phenolic motif ensures excellent visible light absorption
with a bandgap (Eg) of 1.74 eV. More importantly,
the extensive titanium active sites within the structure could trap
the photogenerated electrons and promote the charge separation effectively,
attributed to the excellent visible light photocatalytic performance
in organic reaction. FIR-138’s capability to harness visible
light for photocatalytic reactions presents a promising advancement
in the field of Ti-MOF photocatalysts. These results provide valuable
insights and open up new avenues for the rational design and synthesis
of visible-light-active Ti-MOF photocatalysts
Visible-Light-Active Titanium Sulfonate Framework for Photocatalytic Organic Synthesis
In this work, the first visible-light-active titanium
sulfonate
metal–organic framework (denoted as FIR-138) with 2-fold interpenetrated
srs topology was synthesized by employing 2,5-dihydroxy-1,4-benzenedisulfonic
acid (H4DOBSC) as ligands. The strong chelating coordination
ability of the hydroxyl and sulfonate O atoms from H4DOBSC
endows the framework of FIR-138 with good stability, while the formation
of the Ti-phenolic motif ensures excellent visible light absorption
with a bandgap (Eg) of 1.74 eV. More importantly,
the extensive titanium active sites within the structure could trap
the photogenerated electrons and promote the charge separation effectively,
attributed to the excellent visible light photocatalytic performance
in organic reaction. FIR-138’s capability to harness visible
light for photocatalytic reactions presents a promising advancement
in the field of Ti-MOF photocatalysts. These results provide valuable
insights and open up new avenues for the rational design and synthesis
of visible-light-active Ti-MOF photocatalysts