64 research outputs found
Topological nanophotonics for photoluminescence control
Rare-earth doped nanocrystals are emerging light sources used for many
applications in nanotechnology enabled by human ability to control their
various optical properties with chemistry and material science. However, one
important optical problem -- polarisation of photoluminescence -- remains
largely out of control by chemistry methods. Control over photoluminescence
polarisation can be gained via coupling of emitters to resonant nanostructures
such as optical antennas and metasurfaces. However, the resulting polarization
is typically sensitive to position disorder of emitters, which is difficult to
mitigate. Recently, new classes of disorder-immune optical systems have been
explored within the framework of topological photonics. Here we explore
disorder-robust topological arrays of Mie-resonant nanoparticles for
polarisation control of photoluminescence of nanocrystals. We demonstrate
polarized emission from rare-earth-doped nanocrystals governed by photonic
topological edge states supported by zigzag arrays of dielectric resonators. We
verify the topological origin of polarised photoluminescence by comparing
emission from nanoparticles coupled to topologically trivial and nontrivial
arrays of nanoresonators
Experimental observation of highly anisotropic elastic properties of two-dimensional black arsenic
Anisotropic two-dimensional layered materials with low-symmetric lattices
have attracted increasing attention due to their unique orientation-dependent
mechanical properties. Black arsenic (b-As), with the puckered structure,
exhibits extreme in-plane anisotropy in optical, electrical and thermal
properties. However, experimental research on mechanical properties of b-As is
very rare, although theoretical calculations predicted the exotic elastic
properties of b-As, such as anisotropic Young's modulus and negative Poisson's
ratio. Herein, experimental observations on highly anisotropic elastic
properties of b-As were demonstrated using our developed in situ tensile
straining setup based on the effective microelectromechanical system. The
cyclic and repeatable load-displacement curves proved that Young's modulus
along zigzag direction was ~1.6 times greater than that along armchair
direction, while the anisotropic ratio of ultimate strain reached ~2.5,
attributed to hinge structure in armchair direction. This study could provide
significant insights to design novel anisotropic materials and explore their
potential applications in nanomechanics and nanodevices.Comment: 19 pages, 5 figure
Highly Anisotropic Elastic Properties of Suspended Black Arsenic Nanoribbons
Anisotropy, as an exotic degree of freedom, enables us to discover the
emergent two-dimensional (2D) layered nanomaterials with low in-plane symmetry
and to explore their outstanding properties and promising applications. 2D
black arsenic (b-As) with puckered structure has garnered increasing attention
these years owing to its extreme anisotropy with respect to the electrical,
thermal, and optical properties. However, the investigation on mechanical
properties of 2D b-As is still lacking, despite much effort on theoretical
simulations. Herein, we report the highly anisotropic elastic properties of
suspended b-As nanoribbons via atomic force microscope-based nanoindentation.
It was found that the extracted Young's modulus of b-As nanoribbons exhibits
remarkable anisotropy, which approximates to 72.2 +- 5.4 and 44.3 +- 1.4 GPa
along zigzag and armchair directions, respectively. The anisotropic ratio
reaches up to ~ 1.6. We expect that these results could lay a solid foundation
for the potential applications of 2D anisotropic nanomaterials in the
next-generation nanomechanics and optoelectronics.Comment: 17 pages, 5 figure
Energy and spectrum efficient blind equalization with unknown constellation for air-to-ground multipath UAV communications
In unmanned aerial vehicle (UAV) communications, frequency-selective fading can severely deteriorate the quality of transmitted signal by generating undesired and disordered constellation diagrams due to scatters in the air-to-ground (ATG) mutipath channels. In this paper, we propose a low-overhead blind equalization method to combat frequency-selective fading in air-ground multipath UAV channels. Specifically, a pre-equalization method is proposed based on a constant modulus algorithm to restore the contour of the constellation diagram. Moreover, the similarity measure function and the difference measure function are derived using template matching to identify the constellation of M-ary quadrature amplitude modulation. Furthermore, we propose a weighted constant cross algorithm (WXA) to reduce the residual mean square error and construct a cross-shaped modulus value, by utilizing the statistical information of the identified normalized standard constellation diagrams and the equalizer output decision symbols’ weighting value. The proposed method requires less information and no training sequences and pilots, therefore, if achieves energy and spectrum efficient ATG multipath UAV communications. Simulation results show that the proposed WXA algorithm can reduce the residual mean square error convergence value between -22dB and -25dB, making it very useful for the equalization of the frequency-selective fading channel in typical UAV communication scenarios
High-Mobility Semiconducting Polymers With Different Spin Ground States
Organic semiconductors with high-spin ground states are fascinating because they could enable fundamental understanding on the spin-related phenomenon in light element and provide opportunities for organic magnetic and quantum materials. Although high-spin ground states have been observed in some quinoidal type small molecules or doped organic semiconductors, semiconducting polymers with high-spin at their neutral ground state are rarely reported. Here we report three high-mobility semiconducting polymers with different spin ground states. We show that polymer building blocks with small singlet-triplet energy gap (ΔES-T) could enable small ΔES-T gap and increase the diradical character in copolymers. We demonstrate that the electronic structure, spin density, and solid-state interchain interactions in the high-spin polymers are crucial for their ground states. Polymers with a triplet ground state (S = 1) could exhibit doublet (S = 1/2) behavior due to different spin distributions and solid-state interchain spin-spin interactions. Besides, these polymers showed outstanding charge transport properties with high hole/electron mobilities and can be both n- and p-doped with superior conductivities. Our results demonstrate a rational approach to obtain high-mobility semiconducting polymers with different spin ground states
Xiaoqinglong granules as add-on therapy for asthma: latent class analysis of symptom predictors of response.
Xiaoqinglong granules (XQLG) has been shown to be an effective therapy in asthma animal models. We reviewed the literature and conducted this study to assess the impact of XQLG as an add-on therapy to treatment with fluticasone/salmeterol (seretide) in adult patients with mild-to-moderate, persistent asthma. A total of 178 patients were randomly assigned to receive XQLG and seretide or seretide plus placebo for 90 days. Asthma control was assessed by asthma control test (ACT), symptoms scores, FEV(1), and PEF. Baseline patient-reported Chinese medicine (CM)-specific symptoms were analyzed to determine whether the symptoms may be possible indicators of treatment response by conducting latent class analysis (LCA). There was no statistically significant difference in ACT score between two groups. In the subset of 70 patients with symptoms defined by CM criteria, XQLG add-on therapy was found to significantly increase the levels of asthma control according to global initiative for asthma (GINA) guidelines (P = 0.0329). There was no significant difference in another subset of 100 patients with relatively low levels of the above-mentioned symptoms (P = 0.1291). Results of LCA suggest that patients with the six typical symptoms defined in CM may benefit from XQLG
Immune cell early activation, apoptotic kinetic, and T-cell functional impairment in domestic pigs after ASFV CADC_HN09 strain infection
African swine fever (ASF) caused by the African swine fever virus (ASFV) is a fatal and highly contagious disease of domestic pigs characterized by rapid disease progression and death within 2 weeks. How the immune cells respond to acute ASFV infection and contribute to the immunopathogenesis of ASFV has not been completely understood. In this study, we examined the activation, apoptosis, and functional changes of distinct immune cells in domestic pigs following acute infection with the ASFV CADC_HN09 strain using multicolor flow cytometry. We found that ASFV infection induced broad apoptosis of DCs, monocytes, neutrophils, and lymphocytes in the peripheral blood of pigs over time. The expression of MHC class II molecule (SLA-DR/DQ) on monocytes and conventional DCs as well as CD21 expression on B cells were downregulated after ASFV infection, implying a potential impairment of antigen presentation and humoral response. Further examination of CD69 and ex vivo expression of IFN-γ on immune cells showed that T cells were transiently activated and expressed IFN-γ as early as 5 days post-infection. However, the capability of T cells to produce cytokines was significantly impaired in the infected pigs when stimulated with mitogen. These results suggest that the adaptive cellular immunity to ASFV might be initiated but later overridden by ASFV-induced immunosuppression. Our study clarified the cell types that were affected by ASFV infection and contributed to lymphopenia, improving our understanding of the immunopathogenesis of ASFV
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