4 research outputs found

    Superoleophilic and Flexible Thermoplastic Polymer Nanofiber Aerogels for Removal of Oils and Organic Solvents

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    Chemical cross-linked poly­(vinyl alcohol-<i>co</i>-ethylene) (EVOH) nanofiber aerogels (NFAs) were fabricated employing an economical and facile freeze-drying process. The manufactured chemical cross-linking nanofiber aerogel was successfully confirmed by scanning electron microscopy, attenuated total reflection-Fourier transform infrared spectrometer, and X-ray diffraction. The resulting aerogels showed high porosity (>99%), superior elasticity, elastic durability, high hydrophobicity, and superoleophilicity without any other hydrophobic modification. The cross-linked EVOH NFAs exhibited excellent absorption capacity (ranging from 45 to 102 times their own weight) when exposed to various oils and organic solvents, which was observed to be higher than that for most sorbents reported in the literature. Consequently, it is envisaged that the cross-linked EVOH NFA would play an important role in many fields of pollution removal

    Surface Enhanced Raman Scattering Detection of Cancer Biomarkers with Bifunctional Nanocomposite Probes

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    This report describes new findings of an investigation of a bifunctional nanocomposite probe for the detection of cancer biomarkers, demonstrating the viability of magnetic focusing and SERS detection in a microfluidic platform. The nanocomposite probe consists of a magnetic nickel–iron core and a gold shell. Upon bioconjugation, the nanoprobes are magnetically focused on a specific spot in a microfluidic channel, enabling an enrichment of “hot spots” for surface enhanced Raman scattering detection of the targeted carcinoembryonic antigen. The detection sensitivity, with a limit of detection of ∌0.1 pM, is shown to scale with the magnetic focusing time and the nanoparticle size. The latter is also shown to exhibit an excellent agreement between the experimental data and the theoretical simulation. Implications of the findings to the development of rapid and sensitive microfluidic detection of cancer biomarkers are also discussed
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