An Efficient Ultrasound-Assisted Synthesis of Cu/Zn Hybrid MOF Nanostructures With High Microbial Strain Performance

Metal organic frameworks (MOFs) are a promising choice for antibacterial and antifungal activity due to their composition, unique architecture, and larger surface area. Herein, the ultrasonic method was used to synthesize the Cu/Zn-MOF material as an effective hybrid nanostructure with ideal properties. SEM images were used to investigate the product’s morphology and particle size distribution. The XRD pattern revealed that the Cu/Zn hybrid MOF nanostructures had a smaller crystalline size distribution than pure Cu and Zn-MOF samples. Furthermore, the BET technique determined that the hybrid MOF nanostructures had a high specific surface area. TG analysis revealed that the hybrid MOF structures were more thermally stable than pure samples. The final product, with remarkable properties, was used as a new option in the field of antibacterial studies. Antibacterial activity was assessed using MIC and MBC against Gram negative and Gram positive strains, as well as antifungal activity using MIC and MFC. The antimicrobial properties of the synthesized Cu/Zn hybrid MOF nanostructures revealed that they were more effective than commercial drugs in some cases. This study’s protocol could be a new strategy for introducing new hybrid nanostructures with specific applications

Enhanced removal of tetrabromobisphenolA (TBBPA) from e-waste by Fe–S nanoparticles and Fe–S/CuS nanocomposite with response surface methodology (RSM)

Abstract TetrabromobisphenolA is a well-known member of the brominated flame retardant group and is widely used as a highly effective fire-retardant additive in electronic and electrical equipment. TBBPA is commonly found in various environmental sources and can be harmful to human health. This study presents a simple approach to preparing a magnetic nanocomposite, offering a straightforward method that results in consistent quality and low resource consumption. The nanocomposite has a high surface-to-volume ratio for the removal of tetrabromobisphenolA. Various characterization techniques, including XRD, FTIR, EDX, FESEM, VSM, TEM, and BET analyses were used to characterize the Fe–S nanoparticles and Fe–S/CuS. The results showed that Fe–S/CuS nanocomposite successfully removed over 97% of the initial TBBPA (15 mg L−1) under optimized conditions determined by RSM, such as a contact time of 15 min, pH of 7, Fe–S/CuS nanocomposite dosage of 0.69 g L−1, and salt concentration of 0.10%. The RSM analysis provided a second-order polynomial model with a confidence level of 93% (F = 29.58; p < 0.0001) to predict the TBBPA removal efficiency at various concentrations. In the adsorption kinetic studies, the second-order kinetic model provided the best fit for the experimental data. Additionally, Fe–S/CuS nanocomposite shows great potential for practical applications and environmental remediation efforts, making it a valuable asset for real-sample use in environmental settings

Evaluation of Vali Asr (aj) hospital effluent for irrigation of the green

Background and Aim: Recycling of sewage in our country can be one of the ways to overcome the problem of water shortage. The aim of this paper is Evaluation of Valli-e-asr hospital effluent for irrigation of the green. Materials and Methods: During the 12 months of the project since January 2009, twelve samples of the hospital water were selected. 35 samples were taken both from raw sewage and refined effluent with the average frequency of two samples every month. Various physical, chemical, and biological factors were measured on the basis of the standard method book (AWWA). The gathered data was statistically analyzed using SPSS software (version 15) and paired T test at the significant level . Results: The percentages of separating some parameters such as BOD, TSS, COD, and MPS in the exiting effluent were 63.56%, 44.9%, 42.9%, and 89.97% respectively and those of the parameters PH, Mg, SO4, and SAR were 7.52mg/l, 66.82 mg/l, 382.14 mg/l, and 0.54 mg/l respectively. The amount of parameters BOD, COD, TSS, MPN, EC, CL, TDS, and NA% were 165.14mg/l, 887.657mg/l, 784.4286mg/l, 1856857 MPN, 4137.97&micro;s/cm, 999mg/l, 2866.57mg/l, and 75.11% respectively. Conclusion: The sewage refinery of Valli-e-asr hospital does not produce a favorable outcome and some of the parameters of the effluent such as PH, Mg, SO4, and SAR are in accord with the standards of reusing in agriculture and irrigation but many of the necessary parameters do not correspond with the necessary standards for this task

Green construction of magnetic MnFe2O4/ZIF-8 nanocomposite utilizing extract of Melissa officinalis plant for the photo-degradation of tetracycline under UV illumination

The current work explores the photocatalytic degradation of tetracycline utilizing ZIF-8 grafted with MnFe2O4 through a facile green approach. The complete degradation was achieved at optimized circumstances (pH = 9, catalyst concentration = 0.5 g/L, contact time = 180 min, and 20 mg/L of tetracycline dose). The photocatalytic decontamination reaction of the as-made catalyst was more adherence to the pseudo-first-order model. Recycling experiments demonstrated the excellent stability of the MnFe2O4/ZIF-8 composite after six regeneration runs. Furthermore, the as-constructed composite can simultaneously eliminate tetracycline, COD, and TOC from real wastewater by 84%, 65%, and 50%, respectively, revealing its robust potential in addressing water contamination concerns

Bacterial contamination of salads and vegetables offered in restaurants and fast food in Birjand city in 2015

Background and Aim: Given the ever-increasing population in the world, people's need for fruits and vegetables is increasing day by day. Fruit and vegetable are an important part of human diet. So, this study was conducted to determine the level of microbial contamination in the salads and vegetables supplied in restaurants and fast food in Birjand. Materials and Methods: In this descriptive study, after identifing restaurants and fast food that were the supplier of salads and vegetables in Birjand, 2015, was removed 100 samples under sterile conditions randomly from all restaurants and fast food. The samples were transferred to the laboratory in good condition. The microbial contamination was compared with the current standard according to standard laboratory procedures of Standard and Industrial Research of Iran. Results: Results showed that maximum pollution vegetables and salads were in yeast (28%) and Staphylococcus aureus (13%) and Eshershia.Coli (9% and Enterococcus infection and parasite eggs were not found in the samples. Samples were taken, 69% in accordance with the standard and 31% were not in accordance with the standard. Conclusion: According to the results, about 31% of the samples were contaminated. Shows that washing the vegetables are done, but probably do not be disinfected. Therefore, education in the field of disinfection of vegetables and salad ingredients and continuous sampling of salads and vegetables seems necessary