Observation of blue-shifted ultralong-range Cs2_{2} Rydberg molecules

We observe ultralong-range blue-shifted Cs$_{2}$ molecular states near $ns_{1/2}$ Rydberg states in an optical dipole trap, where $31\leq n\leq34$. The accidental near degeneracy of $(n-4)l$ and $ns$ Rydberg states for $l>2$ in Cs, due to the small fractional $ns$ quantum defect, leads to non-adiabatic coupling among these states, producing potential wells above the $ns$ thresholds. Two important consequences of admixing high angular momentum states with $ns$ states are the formation of large permanent dipole moments, $\sim 15-100\,$Debye, and accessibility of these states via two-photon association. The observed states are in excellent agreement with theory. Both projections of the total angular momentum on the internuclear axis are visible in the experiment

Photoionization Rates of Cs Rydberg Atoms in a 1064 nm Far Off-Resonance Trap

Experimental measurements of photoionization rates of $nD_{5/2}$ Rydberg states of Cs ($50 \leq n \leq 75$) in a 1064 nm far off-resonance dipole trap are presented. The photoionization rates are obtained by measuring the lifetimes of Rydberg atoms produced inside of a 1064 nm far off-resonance trap and comparing the lifetimes to corresponding control experiments in a magneto-optical trap. Experimental results for the control experiments agree with recent theoretical predictions for Rydberg state lifetimes and measured photoionization rates are in agreement with transition rates calculated from a model potential.Comment: 12 pages, 4 figure

Unilateral and Exclusionary/Strategic Effects of Common Agency: Price Impacts in a Repeated Common Value English Auction

The business justification for multiple principals to hire a common agent is efficiency. Our empirical study demonstrates that the creation of the common agent unilaterally depresses winning bids. Additionally, the common agent was not only observed to be the dominant bidder but also paid significantly lower prices than fringe competitors (price/quantity differential). The observed price/quantity differential is consistent with the almost common value English auction theory developed by Rose and Kagel (2008) in which a cost advantaged bidder is able to reduce competition by credibly raising the costs of disadvantaged rivals associated with the winner’s curse.Common Value Auctions, Common Agency, Antitrust, Industrial Organization, D44, K21, K23,

Safety, the Preface Paradox and Possible Worlds Semantics

This paper contains an argument to the effect that possible worlds semantics renders semantic knowledge impossible, no matter what ontological interpretation is given to possible worlds. The essential contention made is that possible worlds semantic knowledge is unsafe and this is shown by a parallel with the preface paradox

Rydberg trimers and excited dimers bound by internal quantum reflection

Quantum reflection is a pure wave phenomena that predicts reflection of a particle at a changing potential for cases where complete transmission occurs classically. For a chemical bond, we find that this effect can lead to non-classical vibrational turning points and bound states at extremely large interatomic distances. Only recently has the existence of such ultralong-range Rydberg molecules been demonstrated experimentally. Here, we identify a broad range of molecular lines, most of which are shown to originate from two different novel sources: a single-photon associated triatomic molecule formed by a Rydberg atom and two ground state atoms and a series of excited dimer states that are bound by a so far unexplored mechanism based on internal quantum reflection at a steep potential drop. The properties of the Rydberg molecules identified in this work qualify them as prototypes for a new type of chemistry at ultracold temperatures.Comment: 6 pages, 3 figures, 1 tabl

Modelización de datos de supervivencia en nidos: estudio comparativo de varios métodos desarrollados recientemente que pueden implementarse en MARK y SAS

Estimating nest success and evaluating factors potentially related to the survival rates of nests are key aspects of many studies of avian populations. A strong interest in nest success has led to a rich literature detailing a variety of estimation methods for this vital rate. In recent years, modeling approaches have undergone especially rapid development. Despite these advances, most researchers still employ Mayfield’s ad–hoc method (Mayfield, 1961) or, in some cases, the maximum–likelihood estimator of Johnson (1979) and Bart & Robson (1982). Such methods permit analyses of stratified data but do not allow for more complex and realistic models of nest survival rate that include covariates that vary by individual, nest age, time, etc. and that may be continuous or categorical. Methods that allow researchers to rigorously assess the importance of a variety of biological factors that might affect nest survival rates can now be readily implemented in Program MARK and in SAS’s Proc GENMOD and Proc NLMIXED. Accordingly, use of Mayfield’s estimator without first evaluating the need for more complex models of nest survival rate cannot be justified. With the goal of increasing the use of more flexible methods, we first describe the likelihood used for these models and then consider the question of what the effective sample size is for computation of AICc. Next, we consider the advantages and disadvantages of these different programs in terms of ease of data input and model construction; utility/flexibility of generated estimates and predictions; ease of model selection; and ability to estimate variance components. An example data set is then analyzed using both MARK and SAS to demonstrate implementation of the methods with various models that contain nest–, group– (or block–), and time–specific covariates. Finally, we discuss improvements that would, if they became available, promote a better general understanding of nest survival rates.La estimación del éxito de nidificación y la evaluación de los factores potencialmente relacionados con las tasas de supervivencia de los mismos son aspectos clave de numerosos estudios sobre poblaciones de aves. El gran interés por el éxito de nidificación se ha traducido en una rica literatura que detalla varios métodos de estimación de esta tasa vital. En los últimos años, los enfoques de modelización han experimentado un rápido desarrollo. No obstante, pese a estos avances, la mayoría de los investigadores siguen empleando el método ad–hoc de Mayfield (Mayfield, 1961) o, en algunos casos, el estimador de probabilidad máxima de Johnson (1979) y Bart & Robson (1982). Tales métodos permiten el análisis de datos estratificados, pero, en cambio, no permiten modelos más complejos y realistas de la tasa de supervivencia en nidos cuando se incluyen covariantes que cambian según el individuo, la edad del nido, el tiempo, etc., y que pueden ser continuas o categóricas. Actualmente, con la ayuda de Program MARK, así como de Proc GENMOD y Proc NLMIXED de SAS, es posible implementar métodos que permiten a los investigadores evaluar rigurosamente la importancia de varios factores biológicos susceptibles de incidir en las tasas de supervivencia en nidos. Por consiguiente, no está justificada la utilización del estimador de Mayfield sin antes evaluar la necesidad de emplear modelos más complejos para determinar la tasa de supervivencia en nidos. Con objeto de incrementar el empleo de métodos más flexibles, primero describimos la probabilidad empleada para estos modelos, para posteriormente tomar en consideración cuál es el tamaño de muestra eficaz para el cálculo de AICc. Seguidamente, tomamos en consideración las ventajas y desventajas de estos programas por lo que respecta a la facilidad de introducción de datos y de construcción de modelos, la utilidad/flexibilidad de las estimaciones y predicciones generadas, la facilidad de la selección de modelos y la capacidad para estimar los componentes de la varianza. A continuación, analizamos un conjunto de datos de ejemplo utilizando los programas MARK y SAS con objeto de demostrar la implementación de los métodos con varios modelos que contienen nido–, grupo– (o bloque–), y covariantes específicas al tiempo. Por último, comentamos varias mejoras que, si estuvieran disponibles, fomentarían una mejor comprensión general de las tasas de supervivencia en nidos

Irreversibility and Polymer Adsorption

Physisorption or chemisorption from dilute polymer solutions often entails irreversible polymer-surface bonding. We present a theory of the non-equilibrium layers which result. While the density profile and loop distribution are the same as for equilibrium layers, the final layer comprises a tightly bound inner part plus an outer part whose chains make only fN surface contacts where N is chain length. The contact fractions f follow a broad distribution, P(f) ~ f^{-4/5}, in rather close agreement with strong physisorption experiments [H. M. Schneider et al, Langmuir v.12, p.994 (1996)].Comment: 4 pages, submitted to Phys. Rev. Let