Macromixing study for various designs of impellers in a stirred vessel

The effect of the impeller designs and impeller clearance level (C/T) on power consumption, mixing time and air entrainment point in a single liquid phase under turbulent conditions (Re > 104) were investigated. Different impeller designs including conventional and new designs, were used to consider both axial and radial flow impellers. The electric conductivity method, suspended motor system and observation method were employed to determine the mixing time, the power consumption and the air entrainment point, respectively. The reduction in the impeller clearance level form T/3 to T/6 resulted in a decrease in power number values for up-flow pumping impellers while it was increased for down-flow pumping. The same trend was observed for the mixing time results. Moreover, axial flow impellers and specially HE3 are preferable for higher agitation speeds due to the less air entrainment. The results verified that the axial flow impellers and specifically down-flow impellers are more efficient than the radial flow impellers. ANFIS-Fuzzy C–means (ANFIS–FcM) and nonlinear regression were used to develop models to predict the mixing time based on the energy dissipation rate and clearance. The results verified that the model predictions successfully fit the experimental mixing time data

Activated carbon-supported CuO nanoparticles: a hybrid material for carbon dioxide adsorption

Activated carbon-supported copper(II) oxide (CuO) nanoparticles were synthesized by simple impregnation method to improve carbon dioxide (CO2) adsorption capacity of the support. The structural and chemical properties of the hybrid material were characterized by scanning electron microscopy (SEM), energy dispersive X-ray (EDX), X-ray diffraction (XRD), Xray photoelectron spectroscopy (XPS), atomic absorption spectroscopy (AAS), and Brunauer-Emmett-Teller (BET) analyses. The analyses showed that CuO nanoparticles are well-distributed on the activated carbon surface. The CO2 adsorption behavior of the activated carbon-supported CuO nanoparticles was observed by thermogravimetric analysis (TGA), temperature programmed desorption (TPD), Fourier transform infrared (FTIR), and BETanalyses. The results showed that CuO nanoparticle loading on activated carbon led to about 70 % increase in CO2 adsorption capacity of activated carbon under standard conditions (1 atm and 298 K). The main contributor to the observed increase is an improvement in chemical adsorption of CO2 due to the presence of CuO nanoparticles on activated carbon