2,3-ジアミノコハク酸エステル骨格を有する新規不斉源の開発と応用

取得学位：博士(工学)，学位授与番号：博甲第983号，学位授与年月日：平成20年3月22

Catalytic asymmetric dialkynylation reaction of α-dinitrone by utilizing tartaric acid ester as a chiral auxiliary

金沢大学理工研究域物質化学系The asymmetric addition of alkynylzinc reagents, prepared in situ from dimethylzinc and 1-alkynes, to α-dinitrones derived from glyoxal and N-(4-isopropylbenzyl)hydroxylamine was investigated by utilizing dicyclohexyl (R,R)-tartrate as a chiral auxiliary. The addition reaction of methyl(2-phenylethynyl)zinc afforded the corresponding optically active C2-symmetric (R,R)-bis(hydroxylamine) derivative with enantioselectivities of 90% and 81% ee by utilizing a stoichiometric and catalytic amount of the tartrate, respectively. Furthermore, the catalytic addition reaction of several alkynylzinc reagents also furnished the corresponding bis(hydroxylamine) with moderate to good enantioselectivities. © 2008 Elsevier Ltd. All rights reserved

Influence of friction stir welding conditions on joinability of oxide dispersion strengthened steel / F82H ferritic/martensitic steel joint

AbstractAs one of the joining methods for the reduced activation materials to realize the fusion reactors with high efficiency in the future, friction stir welding (FSW) is selected for fabricating the dissimilar butt joint between oxide-dispersion strengthened (ODS) alloy and F82H, and the effect of FSW conditions on joinability of this dissimilar joint was examined. The sound dissimilar joint can be produced under the condition that ODS plate is set on the advancing side and the FSW tool is plunged into F82H. As for the mild steel backside plate, the sound joint can be fabricated in the case of 150rpm rotational speed and 50mm/min traveling speed. On the other hand, by employing the silicon nitride backside plate, the total heat input should be decreased to obtain the sound joint, where the traveling speed is 100 or 150mm/min and rotational speed is 150rpm. In addition, the finite element heat conduction analyses indicate that the influence of traveling speed on the joinability with the mild steel backside plate seems to be smaller than that with the silicon nitride plate and the allowable range of the appropriate traveling speed for the joint becomes to be wider by employing the silicon nitride backside plate