16,675 research outputs found
First-Principles Study of Electronic Structure in -(BEDT-TTF)I at Ambient Pressure and with Uniaxial Strain
Within the framework of the density functional theory, we calculate the
electronic structure of -(BEDT-TTF)I at 8K and room temperature
at ambient pressure and with uniaxial strain along the - and -axes. We
confirm the existence of anisotropic Dirac cone dispersion near the chemical
potential. We also extract the orthogonal tight-binding parameters to analyze
physical properties. An investigation of the electronic structure near the
chemical potential clarifies that effects of uniaxial strain along the a-axis
is different from that along the b-axis. The carrier densities show
dependence at low temperatures, which may explain the experimental findings not
only qualitatively but also quantitatively.Comment: 10 pages, 7 figure
Charge ordering in theta-(BEDT-TTF)_2 X materials
We investigate theoretically charge ordered states on the anisotropic
triangular lattice characteristic of the theta-(BEDT-TTF)_2 X materials. Using
exact diagonalization studies, we establish that the charge order (CO) pattern
corresponds to a ``horizontal'' stripe structure, with ...1100... CO along the
two directions with larger electron hopping (p-directions), and ...1010... CO
along the third direction (c-direction). The CO is accompanied by co-operative
bond dimerizations along all three directions in the highest spin state. In the
lowest spin state bonds along the p-directions are tetramerized. Our theory
explains the occurence of a charge-induced high temperature transition as well
as a spin gap transition at lower temperature.Comment: 4 pages, 4 eps figures, uses jpsj2.cl
Growth Dynamics of Photoinduced Domains in Two-Dimensional Charge-Ordered Conductors Depending on Stabilization Mechanisms
Photoinduced melting of horizontal-stripe charge orders in
quasi-two-dimensional organic conductors
\theta-(BEDT-TTF)2RbZn(SCN)4[BEDT-TTF=bis(ethylenedithio)tetrathiafulvalene]
and
\alpha-(BEDT-TTF)2I3 is investigated theoretically. By numerically solving
the time-dependent Schr\"odinger equation, we study the photoinduced dynamics
in extended Peierls-Hubbard models on anisotropic triangular lattices within
the
Hartree-Fock approximation. The melting of the charge order needs more energy
for \theta-(BEDT-TTF)2RbZn(SCN)4 than for \alpha-(BEDT-TTF)2I3, which is a
consequence of the larger stabilization energy in \theta-(BEDT-TTF)2RbZn(SCN)4.
After local photoexcitation in the charge ordered states, the growth of a
photoinduced domain shows anisotropy. In \theta-(BEDT-TTF)2RbZn(SCN)4, the
domain hardly expands to the direction perpendicular to the horizontal-stripes.
This is because all the molecules on the hole-rich stripe are rotated in one
direction and those on the hole-poor stripe in the other direction. They
modulate horizontally connected transfer integrals homogeneously, stabilizing
the charge order stripe by stripe. In \alpha-(BEDT-TTF)2I3, lattice distortions
locally stabilize the charge order so that it is easily weakened by local
photoexcitation. The photoinduced domain indeed expands in the plane. These
results are consistent with recent observation by femtosecond reflection
spectroscopy.Comment: 9 pages, 8 figures, to appear in J. Phys. Soc. Jpn. Vol. 79 (2010)
No.
Charge Ordering in Organic ET Compounds
The charge ordering phenomena in quasi two-dimensional 1/4-filled organic
compounds (ET)_2X (ET=BEDT-TTF) are investigated theoretically for the
and -type structures, based on the Hartree approximation for the
extended Hubbard models with both on-site and intersite Coulomb interactions.
It is found that charge ordered states of stripe-type are stabilized for the
relevant values of Coulomb energies, while the spatial pattern of the stripes
sensitively depends on the anisotropy of the models. By comparing the results
of calculations with the experimental facts, where the effects of quantum
fluctuation is incorporated by mapping the stripe-type charge ordered states to
the S=1/2 Heisenberg Hamiltonians, the actual charge patterns in the insulating
phases of -(ET)_2MM'(SCN)_4 and -(ET)_2I_3 are deduced.
Furthermore, to obtain a unified view among the , and
-(ET)_2X families, the stability of the charge ordered state in
competition with the dimeric antiferromagnetic state viewed as the Mott
insulating state, which is typically realized in -type compounds, and
with the paramagnetic metallic state, is also pursued by extracting essential
parameters.Comment: 35 pages, 27 figures, submitted to J. Phys. Soc. Jp
Finite-temperature phase transitions in quasi-one-dimensional molecular conductors
Phase transitions in 1/4-filled quasi-one-dimensional molecular conductors
are studied theoretically on the basis of extended Hubbard chains including
electron-lattice interactions coupled by interchain Coulomb repulsion. We apply
the numerical quantum transfer-matrix method to an effective one-dimensional
model, treating the interchain term within mean-field approximation.
Finite-temperature properties are investigated for the charge ordering, the
"dimer Mott" transition (bond dimerization), and the spin-Peierls transition
(bond tetramerization). A coexistent state of charge order and bond
dimerization exhibiting dielectricity is predicted in a certain parameter
range, even when intrinsic dimerization is absent.Comment: to be published in J. Phys. Soc. Jpn., Vol. 76 (2007) No. 1 (5 pages,
4 figures); typo correcte
Imaging Hepatocellular Carcinoma With 68Ga-Citrate PET: First Clinical Experience.
While cross-sectional imaging with computed tomography (CT) and magnetic resonance imaging is the primary method for diagnosing hepatocellular carcinoma (HCC), they provide little biological insight into this molecularly heterogeneous disease. Nuclear imaging tools that can detect molecular subsets of tumors could greatly improve diagnosis and management of HCC. To this end, we conducted a patient study to determine whether HCC can be resolved using 68Ga-citrate positron emission tomography (PET). One patient with recurrent HCC was injected with 300 MBq of 68Ga-citrate and imaged with PET/CT 249 minutes post injection. Four (28%) of 14 hepatic lesions were avid for 68Ga-citrate. One extrahepatic lesion was not PET avid. The average maximum standardized uptake value (SUVmax) for the lesions was 7.2 (range: 6.2-8.4), while the SUVmax of the normal liver parenchyma was 4.7 and blood pool was 5.7. The avid lesions were not significantly larger than the quiescent lesions, and a prior contrast CT showed uniform enhancement among the lesions, suggesting that tumor signals are due to specific binding of the radiotracer to the transferrin receptor, rather than enhanced vascularity in the tumor microenvironment. Further studies are required in a larger patient cohort to verify the molecular basis of radiotracer uptake and the clinical utility of this tool
Finite-Temperature Properties across the Charge Ordering Transition -- Combined Bosonization, Renormalization Group, and Numerical Methods
We theoretically describe the charge ordering (CO) metal-insulator transition
based on a quasi-one-dimensional extended Hubbard model, and investigate the
finite temperature () properties across the transition temperature, . In order to calculate dependence of physical quantities such as the
spin susceptibility and the electrical resistivity, both above and below
, a theoretical scheme is developed which combines analytical
methods with numerical calculations. We take advantage of the renormalization
group equations derived from the effective bosonized Hamiltonian, where Lanczos
exact diagonalization data are chosen as initial parameters, while the CO order
parameter at finite- is determined by quantum Monte Carlo simulations. The
results show that the spin susceptibility does not show a steep singularity at
, and it slightly increases compared to the case without CO because
of the suppression of the spin velocity. In contrast, the resistivity exhibits
a sudden increase at , below which a characteristic dependence
is observed. We also compare our results with experiments on molecular
conductors as well as transition metal oxides showing CO.Comment: 9 pages, 8 figure
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