281 research outputs found
The symmetry of the spin Hamiltonian in herbertsmithite, a spin-1/2 kagom\'{e} lattice
We present magnetization measurements on oriented powder of
ZnCu(OH)Cl along and perpendicular to the orienting field. We
find a dramatic difference in the magnetization between the two directions. It
is biggest at low measurement fields or high temperatures. We show that the
difference at high temperatures must emerge from Ising-like exchange
anisotropy. This allows us to explain muon spin rotation data at in
terms of an exotic ferromagnetic ground state.Comment: 5 pages, 5 figure
Ni3TeO6 - a collinear antiferromagnet with ferromagnetic honeycomb planes
We report a comprehensive study of magnetic properties of Ni3TeO6. The system
crystallizes in a noncentrosymmetric rhombohedral lattice, space group R3.
There are three differently coordinated Ni atoms in the unit cell. Two of them
form an almost planar honeycomb lattice, while the third one is placed between
the layers. Magnetization and specific heat measurements revealed a single
magnetic ordering at TN = 52 K. Below TN the susceptibility with the magnetic
field parallel to the c-axis drops towards zero while the perpendicular
susceptibility remains constant, a characteristic of antiferromagnetic
materials. Neutron diffraction confirmed that the system is antiferromagnet
below TN with ferromagnetic ab-planes stacked antiferromagnetically along the
c-axis. All Ni moments are in the S = 1 spin state and point along the c-axis.Comment: accepted for publication in Journal of Physics Condensed Matte
Magnetic and thermal properties of the S = 1/2 zig-zag spin-chain compound In2VO5
Static magnetic susceptibility \chi, ac susceptibility \chi_{ac} and specific
heat C versus temperature T measurements on polycrystalline samples of In2VO5
and \chi and C versus T measurements on the isostructural, nonmagnetic compound
In2TiO5 are reported. A Curie-Wiess fit to the \chi(T) data above 175 K for
In2VO5 indicates ferromagnetic exchange between V^{4+} (S = 1/2) moments. Below
150 K the \chi(T) data deviate from the Curie-Weiss behavior but there is no
signature of any long range magnetic order down to 1.8 K. There is a cusp at
2.8 K in the zero field cooled (ZFC) \chi(T) data measured in a magnetic field
of 100 Oe and the ZFC and field cooled (FC) data show a bifurcation below this
temperature. The frequency dependence of the \chi_{ac}(T) data indicate that
below 3 K the system is in a spin-glass state. The difference \Delta C between
the heat capacity of In2VO5 and In2TiO5 shows a broad anomaly peaked at 130 K.
The entropy upto 300 K is more than what is expected for S = 1/2 moments. The
anomaly in \Delta C and the extra entropy suggests that there may be a
structural change below 130 K in In2VO5.Comment: 6 pages, 7 figures, 1 tabl
Experimental investigation of the origin of the cross-over temperature in the cuprates
We investigate the cross-over temperature T* as a function of doping in
(Ca_{x}La_{1-x})(Ba_{1.75-x}La_{0.25+x})Cu_3O_{y}, where the maximum Tc
(Tc^max) varies continuously by 30% between families (x) with minimal
structural changes. T* is determined by DC-susceptibility measurements. We find
that T* scales with the maximum Neel temperature TN^max of each family. This
result strongly supports a magnetic origin of T*, and indicates that three
dimensional interactions play a role in its magnitude.Comment: 4 pages, 4 figure
The Impact of Nike Project 40/Generation Adidas Players on Major League Soccer
Created in 1997, the Nike Project40/Generation Adidas program encourages soccer players to leave college early to sign professional contracts with Major League Soccer teams, guaranteeing them a 3-year salary with two one-year options. In theory, if the best players are being chosen to this program each year, they should be outperforming those who are drafted to MLS teams but are not a part of the program. By comparing the top draft picks within and outside the program, researchers hoped to determine whether Nike/Adidas players were having a different impact on the league than their counterparts. Results showed that, of 15 statistical categories analyzed, only three resulted in a statistically significant difference between groups. Though Nike/Adidas players were outperforming players who were not a part of the program, they were not doing so at a rate to justify the claim that they have a greater impact on the league
Spin-gap behaviour in the 2-leg spin-ladder BiCu2PO6
We present magnetic suscceptibility and heat capacity data on a new S=1/2
two-leg spin ladder compound BiCu2PO6. From our susceptibility analysis, we
find that the leg coupling J1/k_B is ~ 80 K and the ratio of the rung to leg
coupling J2/J1 ~ 0.9. We present the magnetic contribution to the heat capacity
of a two-leg ladder. The spin-gap Delta/k_B =3 4 K obtained from the heat
capacity agrees very well with that obtained from the magnetic susceptibility.
Significant inter-ladder coupling is suggested from the susceptibility
analysis. The hopping integrals determined using Nth order muffin tin orbital
(NMTO) based downfolding method lead to ratios of various exchange couplings in
agreement with our experimental data. Based on our band structure analysis, we
find the inter-ladder coupling in the bc-plane J2 to be about 0.75J1 placing
the compound presumably close to the quantum critical limit.Comment: 8 pages, 5 figure
31P NMR study of Na2CuP2O7: a S=1/2 two-dimensional Heisenberg antiferromagnetic system
The magnetic properties of Na2CuP2O7 were investigated by means of 31P
nuclear magnetic resonance (NMR), magnetic susceptibility, and heat capacity
measurements. We report the 31P NMR shift, the spin-lattice 1/T1, and spin-spin
1/T2 relaxation-rate data as a function of temperature T.
The temperature dependence of the NMR shift K(T) is well described by the
S=1/2 square lattice Heisenberg antiferromagnetic (HAF) model with an
intraplanar exchange of J/k_B \simeq 18\pm2 K and a hyperfine coupling A =
(3533\pm185) Oe/mu_B. The 31P NMR spectrum was found to broaden abruptly below
T \sim 10 K signifying some kind of transition. However, no anomaly was noticed
in the bulk susceptibility data down to 1.8 K. The heat capacity appears to
have a weak maximum around 10 K. With decrease in temperatures, the
spin-lattice relaxation rate 1/T1 decreases monotonically and appears to agree
well with the high temperature series expansion expression for a S = 1/2 2D
square lattice.Comment: 12 pages, 8 figures, submitted to J. Phys.: Cond. Ma
Synthesis, Structure and Properties of Tetragonal Sr2M3As2O2 (M3 = Mn3, Mn2Cu and MnZn2) Compounds Containing Alternating CuO2-Type and FeAs-Type Layers
Polycrystalline samples of Sr2Mn2CuAs2O2, Sr2Mn3As2O2, and Sr2Zn2MnAs2O2 were
synthesized. Their temperature- and applied magnetic field-dependent
structural, transport, thermal, and magnetic properties were characterized by
means of x-ray and neutron diffraction, electrical resistivity rho, heat
capacity, magnetization and magnetic susceptibility measurements. These
compounds have a body-centered-tetragonal crystal structure (space group
I4/mmm) that consists of MO2 (M = Zn and/or Mn) oxide layers similar to the
CuO2 layers in high superconducting transition temperature Tc cuprate
superconductors, and intermetallic MAs (M = Cu and/or Mn) layers similar to the
FeAs layers in high-Tc pnictides. These two types of layers alternate along the
crystallographic c-axis and are separated by Sr atoms. The site occupancies of
Mn, Cu and Zn were studied using Rietveld refinements of x-ray and neutron
powder diffraction data. The temperature dependences of rho suggest metallic
character for Sr2Mn2CuAs2O2 and semiconducting character for Sr2Mn3As2O2 and
Sr2Zn2MnAs2O2. Sr2Mn2CuAs2O2 is inferred to be a ferrimagnet with a Curie
temperature TC = 95(1) K. Remarkably, we find that the magnetic ground state
structure changes from a G-type antiferromagnetic structure in Sr2Mn3As2O2 to
an A-type ferrimagnetic structure in Sr2Mn2CuAs2O2 in which the Mn ions in each
layer are ferromagnetically aligned, but are antiferromagnetically aligned
between layers.Comment: 18 pages, 16 figures, 6 tables; submitted to Phys. Rev.
Helicoidal magnetic order in a clean copper oxide spin chain compound
We report susceptibility, specific heat, and neutron diffraction measurements
on NaCuO, a spin-1/2 chain compound isostructural to LiCuO,
which has been extensively investigated. Below 13 K, we find a long-range
ordered, incommensurate magnetic helix state with a propagation vector similar
to that of LiCuO. In contrast to the Li analogue, substitutional
disorder is negligible in NaCuO. We can thus rule out that the helix is
induced by impurities, as was claimed on the basis of prior work on
LiCuO. A spin Hamiltonian with frustrated longer-range exchange
interactions provides a good description of both the ordered state and the
paramagnetic susceptibility.Comment: 4 pages, 4 figures Improved Fig.1 and 4. Minor rephrasing. Reference
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Electronic correlations in FeGa3 and the effect of hole doping on its magnetic properties
We investigate signatures of electronic correlations in the narrow-gap semiconductor FeGa 3 by means of electrical resistivity and thermodynamic measurements performed on single crystals of FeGa 3 , Fe 1−x Mn x Ga 3 , and FeGa 3−y Zn y , complemented by a study of the 4d analog material RuGa 3 . We find that the inclusion of sizable amounts of Mn and Zn dopants into FeGa 3 does not induce an insulator-to-metal transition. Our study indicates that both substitution of Zn onto the Ga site and replacement of Fe by Mn introduces states into the semiconducting gap that remain localized even at highest doping levels. Most importantly, using neutron powder diffraction measurements, we establish that FeGa 3 orders magnetically above room temperature in a complex structure, which is almost unaffected by the doping with Mn and Zn. Using realistic many-body calculations within the framework of dynamical mean field theory (DMFT), we argue that while the iron atoms in FeGa 3 are dominantly in an S=1 state, there are strong charge and spin fluctuations on short-time scales, which are independent of temperature. Further, the low magnitude of local contributions to the spin susceptibility advocates an itinerant mechanism for the spin response in FeGa 3 . Our joint experimental and theoretical investigations classify FeGa 3 as a correlated band insulator with only small dynamical correlation effects, in which nonlocal exchange interactions are responsible for the spin gap of 0.4 eV and the antiferromagnetic order. We show that hole doping of FeGa 3 leads, within DMFT, to a notable strengthening of many-body renormalizations
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