296 research outputs found
1′′-Benzyl-1′-methyl-4′-(naphthalen-1-yl)naphthalene-2-spiro-3′-pyrrolidine-2′-spiro-3′′-indoline-1,2′′-dione
In the title compound, C38H32N2O2, the pyrrolidine ring adopts an envelope conformation, whereas the cyclohexanone ring in the tetrahydronaphthalene fused-ring system adopts a half-chair conformation. The benzyl ring is oriented at an angle of 67.1 (1)° with respect to the naphthyl ring system. Four intramolecular C—H⋯O close contacts and C—H⋯π interaction are observed. In the crystal, molecules associate via C—H⋯O hydrogen bonds, forming a C(12) chain motif along the ac plane
Methyl 4-(4-chlorophenyl)-3,3a,4,4a,5,12c-hexahydro-2-thianaphtho[1′,2′:3,2]furo[5,4-b]pyrrolizine-4a-carboxylate
In the title compound, C25H22ClNO3S, both the pyrrolidinyl and thiazolyl rings adopt envelope conformations whereas the dihydropyran ring adopts a half-chair conformation. The chlorophenyl and naphthalenyl ring systems are oriented at a dihedral angle of 59.7 (1)°. The crystal packing is stabilized by an intramolecular C—H⋯N hydrogen bond and weak intermolecular C—H⋯π interactions
1′,1′′-Dimethyl-4′-(naphthalen-1-yl)-1,2,3,4-tetrahydronaphthalene-2-spiro-3′-pyrrolidine-2′-spiro-3′′-indoline-1,2′′-dione
In the title compound, C32H28N2O2, the pyrrolidine ring adopts an envelope conformation, whereas the cyclohexanone ring in the tetrahydronaphthalene fused-ring system adopts a half-chair conformation. The oxindole ring system is oriented at an angle of 48.2 (1)° with respect to the naphthyl ring system. An intramolecular C—H⋯O close contact is observed. In the crystal, molecules associate via two C—H⋯O hydrogen bonds, forming R
2
2(14) and R
2
2(10) dimers
Methyl 3-[(1H-benzimidazol-1-yl)methyl]-1-methyl-4-(4-methylphenyl)-2′-oxopyrrolidine-2-spiro-3′-1-benzimidazole-3-carboxylate
In the title compound, C29H28N4O3, the pyrrolidine ring adopts a twist conformation whereas the oxindole and benzimidazole residues are approximately planar with maximum deviations of 0.159 (1) and 0.011 (1) Å, respectively. The oxindole residue is almost perpendicular to the benzimidazole residue, making a dihedral angle of 89.2 (1)°. The methyl-substituted benzene ring is oriented at angles of 47.7 (1) and 71.0 (1)°, respectively, with respect to the oxindole and benzimidazole residues. An intramolecular C—H⋯O hydrogen bond is observed. In the crystal, molecules associate via N—H⋯N hydrogen bonds, forming R
2
2(9) dimers
1′-Methyl-4′-(1-naphthyl)-1′′,2′′,3′′,4′′-tetrahydroindane-2-spiro-2′-pyrrolidine-3′-spiro-2′′-naphthalene-1,3,1′′-trione
In the title compound, C32H25NO3, the pyrrolidine ring adopts an envelope conformation, whereas the cyclohexanone ring in the tetrahydronaphthalene fused-ring system adopts a half-chair conformation. The indanedione unit is oriented at an angle of 58.9 (1)° with respect to the naphthyl ring system. Three intramolecular C—H⋯O close contacts and an intramolecular C—H⋯π interaction are observed. In the crystal, molecules associate via C—H⋯O hydrogen bonds, forming a helical chain with a C(10) motif along the b axis
Methyl 2-(2,2,4-trimethyl-6-tosylperhydro-1,3-dioxino[5,4-c]pyridin-5-yl)acetate
The title compound, C20H29NO6S, crystallizes with two molecules in the asymmetric unit, with similar conformations. The dioxane and pyridine rings adopt twist conformations in both molecules. The packing is stabilized by intermolecular C—H⋯O hydrogen bonds
1-Vinyl-1H-indole-3-carbaldehyde
In the title compound, C11H9NO, the C and O atoms of the attached carbaldehyde group deviate by just 0.052 (2) and 0.076 (1) Å, respectively, from the mean plane of the indole ring system. In addition to van der Waals forces, the molecular packing is stabilized by C—H⋯O hydrogen bonds, which form a C(7) chain motif, and π–π interactions (centroid–centroid distance 3.637 Å) between the pyrrole and benzene rings of the indole ring system
A High Speed Networked Signal Processing Platform for Multi-element Radio Telescopes
A new architecture is presented for a Networked Signal Processing System
(NSPS) suitable for handling the real-time signal processing of multi-element
radio telescopes. In this system, a multi-element radio telescope is viewed as
an application of a multi-sensor, data fusion problem which can be decomposed
into a general set of computing and network components for which a practical
and scalable architecture is enabled by current technology. The need for such a
system arose in the context of an ongoing program for reconfiguring the Ooty
Radio Telescope (ORT) as a programmable 264-element array, which will enable
several new observing capabilities for large scale surveys on this mature
telescope. For this application, it is necessary to manage, route and combine
large volumes of data whose real-time collation requires large I/O bandwidths
to be sustained. Since these are general requirements of many multi-sensor
fusion applications, we first describe the basic architecture of the NSPS in
terms of a Fusion Tree before elaborating on its application for the ORT. The
paper addresses issues relating to high speed distributed data acquisition,
Field Programmable Gate Array (FPGA) based peer-to-peer networks supporting
significant on-the fly processing while routing, and providing a last mile
interface to a typical commodity network like Gigabit Ethernet. The system is
fundamentally a pair of two co-operative networks, among which one is part of a
commodity high performance computer cluster and the other is based on
Commercial-Off The-Shelf (COTS) technology with support from software/firmware
components in the public domain.Comment: 19 pages, 4 eps figures, To be published in Experimental Astronomy
(Springer
3′-[Hydroxy(4-oxo-4H-chromen-3-yl)methyl]-2-oxospiro[indoline-3,2′-pyrrolidine]-3′-carbonitrile
In the title compound, C23H19N3O4, the pyran ring adopts a half-chair conformation, while the pyrrolidine (with a C atom as the flap atom) and the five-membered ring in the indoline (with a C atom as the flap atom) ring system adopt slight envelope conformations. The pyrrolidine ring makes dihedral angles of 83.3 (1) and 60.4 (1)° with the mean plane through all non-H atoms of the indoline and chromene ring systems, respectively. In the crystal, molecules are connected by two unique N—H⋯O and O—H⋯O hydrogen-bonding interactions, which form centrosymmetric patterns described by graph-set motifs R
2
2(18) and R
2
2(14). These two motifs combine to form a hydrogen-bonded chain which propagates in the a-axis direction. The crystal structure is also stablized by C—H⋯O interactions and by aromatic π–π stacking interactions between the pyran and benzene rings of neighbouring molecules [centroid–centroid distance = 3.755 (1) Å and slippage = 1.371 (2) Å]
Methyl 4-phenyl-1,2,3,3a,4,4a,5,12c-octahydronaphtho[1′,2′:3,2]furo[5,4-b]pyrrolizine-4a-carboxylate
In the title compound, C26H25NO3, both pyrrolidine rings adopt envelope conformations, whereas the dihydropyran ring adopts a half-chair conformation. The phenyl ring is oriented at an angle of 27.9 (1)° with respect to the naphthalene ring system. An intramolecular C—H⋯O hydrogen bond is observed. The crystal packing is stabilized by weak intermolecular C—H⋯π interactions
- …