4 research outputs found
Coupled spin models for magnetic variation of planets and stars
Geomagnetism is characterized by intermittent polarity reversals and rapid
fluctuations. We have recently proposed a coupled macro-spin model to describe
these dynamics based on the idea that the whole dynamo mechanism is described
by the coherent interactions of many small dynamo elements. In this paper, we
further develop this idea and construct a minimal model for magnetic
variations. This simple model naturally yields many of the observed features of
geomagnetism: its time evolution, the power spectrum, the frequency
distribution of stable polarity periods, etc. This model has coexistent two
phases; i.e. the cluster phase which determines the global dipole magnetic
moment and the expanded phase which gives random perpetual perturbations that
yield intermittent polarity flip of the dipole moment. This model can also
describe the synchronization of the spin oscillation. This corresponds to the
case of sun and the model well describes the quasi-regular cycles of the solar
magnetism. Furthermore, by analyzing the relevant terms of MHD equation based
on our model, we have obtained a scaling relation for the magnetism for
planets, satellites, sun, and stars. Comparing it with various observations, we
can estimate the scale of the macro-spins.Comment: 16 pages, 9 figure
Procrystalline Self-Assembly of Desymmetrized Pentaphenylcyclopentadiene
International audienceThe interplay between the molecular shape and the intermolecular interaction plays a decisive role in self-assembled structures. Recently, inherent randomness of low ordered assemblies, resulting from lack of short- and long-range periodicities, has attracted significant attention due to the unique structural, electronic, and mechanical properties. Here, we present procrystalline self-assemblies of pentaphenyl cyclopentadienyl derivatives on Ag(111) and Au(111) with scanning tunneling microscopy, operating at 4.3 K under ultrahigh vacuum conditions. Two examples, using 5-fold symmetric molecules substituted with methyl or fluorine groups, show that weak interactions, such as π–π stacking, CH−π interactions, and CH···F hydrogen bonding, play a pivotal role in formation of the procrystalline assembly. Our results may give insights into the intricate relationship between the molecular shape and the intermolecular interaction in the formation of non-crystalline assemblies