Synthesis, structure and magnetic properties of Ti doped La2MnNiO6 double perovskite

Received: 20.08.2019. Accepted: 11.09.2019. Published: 15.10.2019.We report sol-gel synthesis, structural characterization and magnetic properties of La2Mn1–xTixNiO6 (0 ≤ x ≤ 1.0). Ti doping removed the biphasic structure of La2MnNiO6 by suppression of rhombohedral structure and all the Ti containing samples crystallized in monoclinic P21 / n symmetry. La2MnNiO6 exhibits multiple magnetic transitions. The high temperature ferromagnetic transition of La2MnNiO6 gradually shifted to lower temperatures with increase in Ti doping. La2TiNiO6 (x = 1.0) does not show any long-range magnetic ordering. The suppression of magnetic transition by Ti doping is ascribed to the destruction of Mn4+ – O – Ni2+ superexchange interaction. However, the signature of ferromagnetic phase persists up to 70 % Ti doping, indicating the robustness of magnetic ordering in La2MnNiO6. These results suggest that the addition of Ti4+ truncates the ferromagnetic Mn4+ – O – Ni2+ superexchange path and it likely promotes ferromagnetic cluster formation. The robustness of ferromagnetic state towards Ti substitution compared to the simple perovskite or spinel structure can be attributed to cationic ordering in double perovskite structure. Both the pure and Ti-doped samples exhibit magnetic frustration at lower temperatures due to partial cationic disordering. The absence of long-range ordering in La2TiNiO6, unlike La2TiCoO6 or Pr2TiCoO6, could be related to cationic disordering.The authors acknowledge the financial support from Indo-Russian project (INT / RUS / RFBR / P-239), Department of Science and Technology (DST), Government of India

Brillouin Scattering Studies of La_{0.77}Ca_{0.23}MnO_3 Across Metal-Insulator Transition

Temperature-dependent Brillouin scattering studies have been carried out on La_{0.77}Ca_{0.23}MnO_3 across the paramagnetic insulator - ferromagnetic metal (I-M) transition. The spectra show a surface Rayleigh wave (SRW) and a high velocity pseudo surface acoustic wave (HVPSAW) besides bulk acoustic waves (BAW). The Brillouin shifts associated with SRW and HVPSAW show blue-shifts, where as the frequencies of the BAW decrease below the I-M transition temperature (T_C) of 230 K. These results can be understood based on the temperature dependence of the elastic constants. We also observe a central peak whose width is maximum at T_C.Comment: 7 pages, 8 figure

Incoherent Effect of Fe and Ni Substitutions in the Ferromagnetic-Insulator La0.6Bi0.4MnO3+d

A comparative study of the effect of Fe and Ni doping on the bismuth based perovskite La0.6Bi0.4MnO3.1, a projected spintronics magnetic semiconductor has been carried out. The doped systems show an expressive change in magnetic ordering temperature. However, the shifts in ferromagnetic transition (TC) of these doped phases are in opposite direction with respect to the parent phase TC of 115 K. The Ni-doped phase shows an increase in TC ~200 K, whereas the Fe-doped phase exhibits a downward shift to TC~95 K. Moreover, the Fe-doped is hard-type whereas the Ni-doped compound is soft-type ferromagnet. It is observed that the materials are semiconducting in the ferromagnetic phase with activation energies of 77 & 82 meV for Fe & Ni-doped phases respectively. In the presence of external magnetic field of 7 Tesla, they exhibit minor changes in the resistivity behaviours and the maximum isothermal magnetoresistance is around -20 % at 125 K for the Ni-phase. The results are explained on the basis of electronic phase separation and competing ferromagnetic and antiferromagnetic interactions between the various mixed valence cations.Comment: 18 pages including figure

Effect of substrate roughness on growth of diamond by hot filament CVD

Polycrystalline diamond coatings are grown on Si (100) substrate by hot filament CVD technique. We investigate here the effect of substrate roughening on the substrate temperature and methane concentration required to maintain high quality, high growth rate and faceted morphology of the diamond coatings. It has been shown that as we increase the substrate roughness from 0.05 μm to 0.91 μm (Centre Line Average or CLA) there is enhancement in deposited film quality (Raman peak intensity ratio of sp 3 to non-sp 3 content increases from 1.65 to 7.13) and the substrate temperature can be brought down to 640°C without any additional substrate heating. The coatings grown at adverse conditions for sp 3 deposition has cauliflower morphology with nanocrystalline grains and coatings grown under favourable sp 3 condition gives clear faceted grains

Brillouin scattering studies in Fe3_3O4_4 across the Verwey transition

Brillouin scattering studies have been carried out on high quality single crystals of Fe$_3$O$_4$ with [100] and [110] faces in the temperature range of 300 to 30 K. The room temperature spectrum shows a surface Rayleigh wave (SRW) mode at 8 GHz and a longitudinal acoustic (LA) mode at 60 GHz. The SRW mode frequency shows a minimum at the Verwey transition temperature $T_V$ of 123 K. The softening of the SRW mode frequency from about 250 K to $T_V$ can be quantitatively understood as a result of a decrease in the shear elastic constant C$_{44}$, arising from the coupling of shear strain to charge fluctuations. On the other hand, the LA mode frequency does not show any significant change around $T_V$, but shows a large change in its intensity. The latter shows a maximum at around 120 K in the cooling run and at 165 K in the heating run, exhibiting a large hysteresis of 45 K. This significant change in intensity may be related to the presence of stress-induced ordering of Fe$^{3+}$ and Fe$^{2+}$ at the octahedral sites, as well as to stress-induced domain wall motion.Comment: 14 pages, 3 figures, accepted in Physical Review B 200

Magneticproperties of La0.5−xLnxSr0.5MnO3La_{0.5-x}Ln_xSr_{0.5}MnO_3 (Ln=Pr, Nd, Gd and Y)

Magnetic and electron transport properties of four series of manganates of the composition $La_{0.5-x}Ln_xSr_{0.5}MnO_3$ (Ln=Pr, Nd, Gd and Y) have been investigated to examine how the ferromagnetic metallic nature of the parent La compound changes over to antiferromagneticinsulating behavior, with change in Ln and x due to the associated changes in the A-site cation radius as well as the size disorder. When Ln=Pr and Nd, there is a transition from the tetragonal I4/mcm structure to the orthorhombic Immm and Imma structures at x = 0.2 and 0.35, respectively. There is a gradual evolution of the properties from those of $La_{0.5}Sr_{0.5}MnO_3$ to those of $Pr_{0.5}Sr_{0.5}MnO_3$ or $Nd_{0.5}Sr_{0.5}MnO_3$ with increase in x. Thus, when x>0.2 and >0.35 respectively, the Pr- and Nd-substituted manganates show ferromagnetic transitions followed by antiferromagnetictransitions at low temperatures, with the ferromagnetic $T_C$ decreasing with increasing x. The Gd and Y series of compounds are all orthorhombic and show a decrease in $T_C$ with the increase in x, the ferromagnetism disappearing at high x. At a value of x corresponding to the A-site cation radius of $Pr_{0.5}Sr_{0.5}MnO_3$ the Gd and Y series of compounds exhibit ferromagnetism in the 250­-300K region and undergo an antiferromagnetictransition on cooling. The $T_C-T_N$ gap is sensitive to the disorder arising from the size mismatch