Calculation of the Phase Behavior of Lipids

The self-assembly of monoacyl lipids in solution is studied employing a model in which the lipid's hydrocarbon tail is described within the Rotational Isomeric State framework and is attached to a simple hydrophilic head. Mean-field theory is employed, and the necessary partition function of a single lipid is obtained via a partial enumeration over a large sample of molecular conformations. The influence of the lipid architecture on the transition between the lamellar and inverted-hexagonal phases is calculated, and qualitative agreement with experiment is found.Comment: to appear in Phys.Rev.

Photonically-driven Schottky diode based 0.3 THz heterodyne receiver

Photonics-based technologies are key players in a number of emerging applications in the terahertz (THz) field. These solutions exploit the well-known advantages of optical devices, such as ultra-wide tuneability and direct integration with fiber networks. However, THz receivers are mainly implemented by fully electronic solutions, where Schottky barrier diodes (SBD) are the preferred option as detectors and mixers due to their excellent response within the THz range at room temperature, and technological maturity. Here, we demonstrate an SBD-based subharmonic mixer (SHM) at 300 GHz pumped with a photonic local oscillator. The Schottky mixer is a prototype designed and manufactured by ACST GmbH, operating at 270-320 GHz. The local oscillator is generated by photomixing on a high-frequency and high-power uni-travelling-carrier photodiode (UTC-PD), providing enough power to saturate conversion loss. Minimum single-side-band conversion loss of 14.4 dB and a peak dynamic range of 130 dB have been measured. Finally, as a proof of concept we realize an all-photonics-based 5 Gbps wireless bridge, utilizing the optically-pumped SBD mixer. With this work, we prove the feasibility of high-performance hybrid Schottky-photonic THz receivers, incorporating the best of both worlds

On the making and taking of professionalism in the further education workplace

This paper examines the changing nature of professional practice in English further education. At a time when neo-liberal reform has significantly impacted on this under-researched and over-market-tested sector, little is known about who its practitioners are and how they construct meaning in their work. Sociological interest in the field has tended to focus on further education practitioners as either the subjects of market and managerial reform or as creative agents operating within the contradictions of audit and inspection cultures. In challenging such dualism, which is reflective of wider sociological thinking, the paper examines the ways in which agency and structure combine to produce a more transformative conception of the further education professional. The approach contrasts with a prevailing policy discourse that seeks to re-professionalise and modernise further education practice without interrogating either the terms of its professionalism or the neo-liberal practices in which it resides

The conservation status of the world’s freshwater molluscs

With the biodiversity crisis continuing unchecked, we need to establish levels and drivers of extinction risk, and reassessments over time, to effectively allocate conservation resources and track progress towards global conservation targets. Given that threat appears particularly high in freshwaters, we assessed the extinction risk of 1428 randomly selected freshwater molluscs using the IUCN Red List Categories and Criteria, as part of the Sampled Red List Index project. We show that close to one-third of species in our sample are estimated to be threatened with extinction, with highest levels of threat in the Nearctic, Palearctic and Australasia and among gastropods. Threat levels were higher in lotic than lentic systems. Pollution (chemical and physical) and the modification of natural systems (e.g. through damming and water abstraction) were the most frequently reported threats to freshwater molluscs, with some regional variation. Given that we found little spatial congruence between species richness patterns of freshwater molluscs and other freshwater taxa, apart from crayfish, new additional conservation priority areas emerged from our study. We discuss the implications of our findings for freshwater mollusc conservation, the adequacy of a sampled approach and important next steps to estimate trends in freshwater mollusc extinction risk over time

Dialectic tensions in the financial markets: a longitudinal study of pre- and post-crisis regulatory technology

This article presents the findings from a longitudinal research study on regulatory technology in the UK financial services industry. The financial crisis with serious corporate and mutual fund scandals raised the profile of compliance as governmental bodies, institutional and private investors introduced a ‘tsunami’ of financial regulations. Adopting a multi-level analysis, this study examines how regulatory technology was used by financial firms to meet their compliance obligations, pre- and post-crisis. Empirical data collected over 12 years examine the deployment of an investment management system in eight financial firms. Interviews with public regulatory bodies, financial institutions and technology providers reveal a culture of compliance with increased transparency, surveillance and accountability. Findings show that dialectic tensions arise as the pursuit of transparency, surveillance and accountability in compliance mandates is simultaneously rationalized, facilitated and obscured by regulatory technology. Responding to these challenges, regulatory bodies continue to impose revised compliance mandates on financial firms to force them to adapt their financial technologies in an ever-changing multi-jurisdictional regulatory landscape

Past and future dynamics of the Brunt Ice Shelf from seabed bathymetry and ice shelf geometry

The recent rapid growth of rifts in the Brunt Ice Shelf appears to signal the onset of its largest calving event since records began in 1915. The aim of this study is to determine whether this calving event will lead to a new steady state in which the Brunt Ice Shelf remains in contact with the bed, or an unpinning from the bed, which could predispose it to accelerated flow or possible break-up. We use a range of geophysical data to reconstruct the sea-floor bathymetry and ice shelf geometry, to examine past ice sheet configurations in the Brunt Basin, and to define the present-day geometry of the contact between the Brunt Ice Shelf and the bed. Results show that during past ice advances grounded ice streams likely converged in the Brunt Basin from the south and east. As the ice retreated, it was likely pinned on at least three former grounding lines marked by topographic highs, and transverse ridges on the flanks of the basin. These may have subsequently formed pinning points for developing ice shelves. The ice shelf geometry and bathymetry measurements show that the base of the Brunt Ice Shelf now only makes contact with one of these topographic highs. This contact is limited to an area of less than 1.3 to 3&thinsp;km2 and results in a compressive regime that helps to maintain the ice shelf's integrity. The maximum overlap between ice shelf draft and the bathymetric high is 2–25&thinsp;m and is contingent on the presence of incorporated iceberg keels, which protrude beneath the base of the ice shelf. The future of the ice shelf depends on whether the expected calving event causes full or partial loss of contact with the bed and whether the subsequent response causes re-grounding within a predictable period or a loss of structural integrity resulting from properties inherited at the grounding line.</p

Past and future dynamics of the Brunt Ice Shelf from seabed bathymetry and ice shelf geometry

The recent rapid growth of rifts in the Brunt Ice Shelf appears to signal the onset of its largest calving event since records began in 1915. The aim of this study is to determine whether this calving event will lead to a new steady state in which the Brunt Ice Shelf remains in contact with the bed, or an unpinning from the bed, which could predispose it to accelerated flow or possible break-up. We use a range of geophysical data to reconstruct the sea-floor bathymetry and ice shelf geometry, to examine past ice sheet configurations in the Brunt Basin, and to define the present-day geometry of the contact between the Brunt Ice Shelf and the bed. Results show that during past ice advances grounded ice streams likely converged in the Brunt Basin from the south and east. As the ice retreated, it was likely pinned on at least three former grounding lines marked by topographic highs, and transverse ridges on the flanks of the basin. These may have subsequently formed pinning points for developing ice shelves. The ice shelf geometry and bathymetry measurements show that the base of the Brunt Ice Shelf now only makes contact with one of these topographic highs. This contact is limited to an area of less than 1.3 to 3 km2 and results in a compressive regime that helps to maintain the ice shelf's integrity. The maximum overlap between ice shelf draft and the bathymetric high is 2–25 m and is contingent on the presence of incorporated iceberg keels, which protrude beneath the base of the ice shelf. The future of the ice shelf depends on whether the expected calving event causes full or partial loss of contact with the bed and whether the subsequent response causes re-grounding within a predictable period or a loss of structural integrity resulting from properties inherited at the grounding line

Tradeoffs in jet inlet design: a historical perspective

The design of the inlet(s) is one of the most demanding tasks of the development process of any gas turbine-powered aircraft. This is mainly due to the multi-objective and multidisciplinary nature of the exercise. The solution is generally a compromise between a number of conflicting goals and these conflicts are the subject of the present paper. We look into how these design tradeoffs have been reflected in the actual inlet designs over the years and how the emphasis has shifted from one driver to another. We also review some of the relevant developments of the jet age in aerodynamics and design and manufacturing technology and we examine how they have influenced and informed inlet design decision

Governing the governors : a case study of college governance in English further education

This paper addresses the nature of governors in the governance of further education colleges in an English context (1). It explores the complex relationship between governors (people/agency), government (policy/structure) and governance (practice), in a college environment. While recent research has focused on the governance of schooling and higher education there has been little attention paid to the role of governors in the lifelong learning sector. The objective of the paper is to contribute to the debate about the purpose of college governance at a time when the Learning and Skills Council (LSC) commissioning era ends, and new government bodies responsible for further education and training, including local authorities, arrive. The paper analyses the nature of FE governance through the perspectives and experiences of governors, as colleges respond to calls from government for greater improvement and accountability in the sector (LSIS, 2009a). What constitutes creative governance is complex and controversial in the wider framework of regulation and public policy reform (Stoker, 1997; Seddon, 2008). As with other tricky concepts such as leadership, professionalism and learning, college governance is best defined in the contexts, cultures and situations in which it is located. College governance does not operate in a vacuum. It involves governors, chairs, principals, professionals, senior managers, clerks, community, business and wider agencies, including external audit and inspection regimes. Governance also acts as a prism through which national education and training reforms are mediated, at local level. While governing bodies are traditionally associated with the business of FE - steering, setting the tone and style, dealing with finance, funding, audit and procedural matters – they are increasingly being challenged to be more creative and responsive to the wider society. Drawing on a recent case study of six colleges, involving governors and key policy stakeholders, this paper explores FE governance in a fast changing policy environment