(Table 1) Results of alkenone analyses of ODP Hole 165-1002C

We determined alkenone concentrations (µg/g dry sediment) and unsaturation indices (Uk'37) on 280 samples from Ocean Drilling Program Hole 1002C over the last full glacial cycle (marine oxygen isotope Stages [MIS] 1-6). Alkenone concentrations vary dramatically in relation to glacial-interglacial cycles, with high concentrations typical of interglacial stages, high sea level, inferred high surface productivity, and bottom-water anoxia. Our reconstruction of low productivity during the last glacial maximum is consistent with previous reports of a sharp decline in the foraminiferal species Neogloboquadrina dutertrei, an upwelling index. Alkenone paleotemperatures show little cooling at both the last glacial maximum and MIS 6. Variations of as much as 4°C occurred during the earlier part of MIS 3 and MIS 4 as well as the latter part of MIS 5. The absence of cooling during glacial maxima determined from alkenone paleothermometry is consistent with faunal reconstructions for the western Caribbean but requires that much of the oxygen isotopic record of the planktonic foraminifer Globigerinoides ruber be influenced by salinity variations rather than temperature

(Table 1) Alkenone concentration, UK'37 index and derived sea surface temperatures for ODP Site 167-1020

Uk'37 sea-surface temperature (SST) estimates obtained at ~2.5-k.y. resolution from Ocean Drilling Program Site 1020 show glacial-interglacial cyclicity with an amplitude of 7°-10°C over the last 780 k.y. This record shows a similar pattern of variability to another alkenone-based SST record obtained previously from the Santa Barbara Basin. Both records show that oxygen isotope Stage (OIS) 5.5 was warmer by ~3°C relative to the present and that glacial Uk'37 temperatures warm in advance of deglaciation, as inferred from benthic d18O records. The alkenone-based SST record at Site 1020 is longer than previously published work along the California margin. We show that warmer than present interglacial stages have occurred frequently during the last 800 k.y. Alkenone concentrations, a proxy for coccolithophorid productivity, indicate that sedimentary marine organic carbon content has also varied significantly over this interval, with higher contents during interglacial periods. A baseline shift to warmer SST and greater alkenone content occurs before OIS 13. We compare our results with those from previous multiproxy studies in this region and conclude that SST has increased by ~5°C since the last glacial period (21 ka). Our data show that maximum alkenone SSTs occur simultaneously with minimum ice volume at Site 1020, which is consistent with data from farther south along the margin. The presence of sea ice in the glacial northeast Pacific, the extent of which is inferred from locations of ice-rafted debris, provides further support for our notion of cold surface water within the northern California Current system, averaging 7°-8°C cooler during peak glacial conditions. The cooling of surface water during glacial stages most likely did not result from enhanced upwelling because alkenone concentrations and terrestrial redwood pollen assemblages are consistently lower during glacial periods

Alkenone production along the California Margin

Alkenone unsaturation indices (Uk'37) of marine sediment could prove particularly useful on organic-rich continental margins where carbonate dissolution hampers the use of other paleoclimatic proxies [McCaffrey et al., 1990, doi:10.1016/0016-7037(90)90399-6; Kennedy and Brassell, 1992, doi:10.1016/0146-6380(92)90040-5]. Forty core top samples of Recent sediment from a latitudinal transect (23°-40°N) along the California margin yield Uk'37 values that correlate linearly with modern mean annual sea surface temperatures (SSTs) in the range of 12°-23°C. Reproducibility of the unsaturation value in closely spaced cores is near analytical error. Uk'37 data define a relationship to temperature nearly identical to the Prahl et al. [1988, doi:10.1016/0016-7037(88)90132-9] laboratory cultures of Emiliania huxleyi. The close agreement is particularly significant in light of the nannofossil composition of the sediments, where the abundance of the coccolith taxon Gephyrocapsa oceanica (known to synthesize alkenones) equals or exceeds that of E. huxleyi. Comparison with seasonal temperature variations at different depths indicates that little if any alkenone production occurs at depths >30 m along the continental margin (water depths <2 km). Sediments in more pelagic locations exhibit small but consistent biases toward winter and/or subsurface production similar to previously reported sediment trap and core top data from the Oregon margin [Prahl et al., 1993, doi:10.1016/0967-0637(93)90045-5; Doose et al., 1997, doi:10.1029/97PA00821]