Polaron physics and crossover transition in magnetite probed by pressure-dependent infrared spectroscopy

The optical properties of magnetite at room temperature were studied by infrared reflectivity measurements as a function of pressure up to 8 GPa. The optical conductivity spectrum consists of a Drude term, two sharp phonon modes, a far-infrared band at around 600 cm$^{-1}$, and a pronounced mid-infrared absorption band. With increasing pressure both absorption bands shift to lower frequencies and the phonon modes harden in a linear fashion. Based on the shape of the MIR band, the temperature dependence of the dc transport data, and the occurrence of the far-infrared band in the optical conductivity spectrum the polaronic coupling strength in magnetite at room temperature should be classified as intermediate. For the lower-energy phonon mode an abrupt increase of the linear pressure coefficient occurs at around 6 GPa, which could be attributed to minor alterations of the charge distribution among the different Fe sites.Comment: 7 pages, 7 figure

Complex-Orbital Order in Fe_3O_4 and Mechanism of the Verwey Transition

Electronic state and the Verwey transition in magnetite (Fe_3O_4) are studied using a spinless three-band Hubbard model for 3d electrons on the B sites with the Hartree-Fock approximation and the exact diagonalisation method. Complex-orbital, e.g., 1/sqrt(2)[|zx> + i |yz>], ordered (COO) states having noncollinear orbital moments ~ 0.4 mu_B on the B sites are obtained with the cubic lattice structure of the high-temperature phase. The COO state is a novel form of magnetic ordering within the orbital degree of freedom. It arises from the formation of Hund's second rule states of spinless pseudo-d molecular orbitals in the Fe_4 tetrahedral units of the B sites and ferromagnetic alignment of their fictitious orbital moments. A COO state with longer periodicity is obtained with pseudo-orthorhombic Pmca and Pmc2_1 structures for the low-temperature phase. The state spontaneously lowers the crystal symmetry to the monoclinic and explains experimentally observed rhombohedral cell deformation and Jahn-Teller like distortion. From these findings, we consider that at the Verwey transition temperature, the COO state remaining to be short-range order impeded by dynamical lattice distortion in high temperature is developed into that with long-range order coupled with the monoclinic lattice distortion.Comment: 16 pages, 13 figures, 6 tables, accepted for publication in J. Phys. Soc. Jp

Influence of hunting on movements of female mule deer

Hunting is a fundamentally important tool for wildlife managers. We examined the null hypothesis that hunting does not influence deer movement and their use of habitat types. Seventeen radio-collared, adult, female Rocky Mountain mule deer (Odocoileus hemionus hemionus) were located 1 day before the 1983 first Colorado deer season, and during day 2 of the first and day 3 of the second deer seasons in the foothills west of Fort Collins, Colorado. Distance from the preseason location to each location during hunting seasons were calculated for each deer. There were no differences between mean distance from pre-hunting season location to hunting season location for 10 deer that had all 3 locations in the area closed to hunting, and 4 deer that had 3 locations in the area open to hunting (P = 0.34 and 0.52). All 17 deer had all 3 locations in the interior of their minimum convex polygon home ranges. Those home ranges had a mean size of 226 ha and range of 117 to 323 ha. However, deer in the section open to hunting generally moved to vegetation types with increasingly better escape cover as the hunting seasons progressed. We conclude that hunting pressure did not cause deer movement in terms of distance or cause them to leave their normal home ranges, but did cause deer to move into more adequate cover.This material was digitized as part of a cooperative project between the Society for Range Management and the University of Arizona Libraries.The Journal of Range Management archives are made available by the Society for Range Management and the University of Arizona Libraries. Contact [email protected] for further information.Migrated from OJS platform August 202

Habitat selection and activity patterns of female mule deer in the Front Range, Colorado

Twenty-two adult, female mule deer (Odocoileus hemionus hemionus) were radio-collared with activity sensors and monitored with ground triangulation from mid-November through March, for 3 years (1982-1985) in the foothills west of Fort Collins, Colorado, to test 4 general hypotheses about habitat selection and activity: (1) The proportion of time deer spend feeding and resting varies with time of day. (2) Deer alter their activity patterns in response to environmental influences. (3) Selection of specific vegetation types for feeding and resting varies with time of day. (4) Ecotones are preferred habitats. Deer were monitored during 6-hr sampling periods: sunrise, daytime, sunset, and night. Deer fed most during sunset, night, and sunrise periods and least during the day. Feeding occupied similar proportions of an average deer's time during sunset, night, and sunrise periods. They preferred the grassland type for feeding and resting at night and the mountain mahogany (Cercocarpus montanus) type for both activities during all other periods. Preference deer showed for the ponderosa pine (Pinus ponderosa) type for feeding activity was inversely related to canopy cover. Deer rested most during daytime and night periods. During periods of daylight, deer using the grassland type showed preference for ecotones with certain types offering escape cover. No such preference was observed at night. Deer fed less and rested more when snow depth exceeded 36 cm. No significant differences (P>0.05) in the proportion of time deer devoted to feeding were found in the following comparisons: clear versus cloudy full-moon nights (-50 vs. + 50% cloud cover), full-moon versus new-moon, low versus high wind speeds (0-32 vs. 32-56 km/hr), and warm versus cold temperatures (+18 to -15 vs. -15 to -23 degrees C). No significant relationships were found for the same comparisons in proportion of time devoted to resting.This material was digitized as part of a cooperative project between the Society for Range Management and the University of Arizona Libraries.The Journal of Range Management archives are made available by the Society for Range Management and the University of Arizona Libraries. Contact [email protected] for further information.Migrated from OJS platform August 202

Bedaquiline and Pyrazinamide Treatment Responses Are Affected by Pulmonary Lesion Heterogeneity in <i>Mycobacterium tuberculosis</i> Infected C3HeB/FeJ Mice

BALB/c and Swiss mice are routinely used to validate the effectiveness of tuberculosis drug regimens, although these mouse strains fail to develop human-like pulmonary granulomas exhibiting caseous necrosis. Microenvironmental conditions within human granulomas may negatively impact drug efficacy, and this may not be reflected in non-necrotizing lesions found within conventional mouse models. The C3HeB/FeJ mouse model has been increasingly utilized as it develops hypoxic, caseous necrotic granulomas which may more closely mimic the pathophysiological conditions found within human pulmonary granulomas. Here, we examined the treatment response of BALB/c and C3HeB/FeJ mice to bedaquiline (BDQ) and pyrazinamide (PZA) administered singly and in combination. BALB/c mice consistently displayed a highly uniform treatment response to both drugs, while C3HeB/FeJ mice displayed a bimodal response composed of responsive and less-responsive mice. Plasma pharmacokinetic analysis of dissected lesions from BALB/c and C3HeB/FeJ mice revealed that PZA penetrated lesion types from both mouse strains with similar efficiency. However, the pH of the necrotic caseum of C3HeB/FeJ granulomas was determined to be 7.5, which is in the range where PZA is essentially ineffective under standard laboratory in vitro growth conditions. BDQ preferentially accumulated within the highly cellular regions in the lungs of both mouse strains, although it was present at reduced but still biologically relevant concentrations within the central caseum when dosed at 25 mg/kg. The differential treatment response which resulted from the heterogeneous pulmonary pathology in the C3HeB/FeJ mouse model revealed several factors which may impact treatment efficacy, and could be further evaluated in clinical trials