Constructed wetlands: Treatment of concentrated storm water runoff (part A)

The aim of this research was to assess the treatment efficiencies for gully pot liquor of experimental vertical- flow constructed wetland filters containing Phragmites australis (Cav.) Trin. ex Steud. (common reed) and filter media of different adsorption capacities. Six out of 12 filters received inflow water spiked with metals. For 2 years, hydrated nickel and copper nitrate were added to sieved gully pot liquor to simulate contaminated primary treated storm runoff. For those six constructed wetland filters receiving heavy metals, an obvious breakthrough of dissolved nickel was recorded after road salting during the first winter. However, a breakthrough of nickel was not observed, since the inflow pH was raised to eight after the first year of operation. High pH facilitated the formation of particulate metal compounds such as nickel hydroxide. During the second year, reduction efficiencies of heavy metal, 5-days at 20°C N-Allylthiourea biochemical oxygen demand (BOD) and suspended solids (SS) improved considerably. Concentrations of BOD were frequently �20 mg/L. However, concentrations for SS were frequently �30 mg/L. These are the two international thresholds for secondary wastewater treatment. The BOD removal increased over time due to biomass maturation, and the increase of pH. An analysis of the findings with case-based reasoning can be found in the corresponding follow-up paper (Part B)

Comparison of planted soil infiltration systems for treatment of log yard runoff

Treatment of log yard runoff is required to avoid contamination of receiving watercourses. The research aim was to assess if infiltration of log yard runoff through planted soil systems is successful and if different plant species affect the treatment performance at a fieldscale experimental site in Sweden (2005 to 2007). Contaminated runoff from the log yard of a sawmill was infiltrated through soil planted with Alnus glutinosa (L.) Ga¨rtner (common alder), Salix schwerinii3viminalis (willow variety ‘‘Gudrun’’), Lolium perenne (L.) (rye grass), and Phalaris arundinacea (L.) (reed canary grass). The study concluded that there were no treatment differences when comparing the four different plants with each other, and there also were no differences between the tree and the grass species. Furthermore, the infiltration treatment was effective in reducing total organic carbon (55%) and total phosphorus (45%) concentrations in the runoff, even when the loads on the infiltration system increased from year to year

Core hole-electron correlation in coherently coupled molecules

We study the core hole-electron correlation in coherently coupled molecules by energy dispersive near edge X-ray absorption fine-structure spectroscopy. In a transient phase, which exists during the transition between two bulk arrangements, 1,4,5,8-naphthalene-tetracarboxylicacid-dianhydride multilayer films exhibit peculiar changes of the line shape and energy position of the X-ray absorption signal at the C K-edge with respect to the bulk and gas phase spectra. By a comparison to a theoretical model based on a coupling of transition dipoles, which is established for optical absorption, we demonstrate that the observed spectroscopic differences can be explained by an intermolecular delocalized core hole-electron pair. By applying this model we can furthermore quantify the coherence length of the delocalized core-exciton.Comment: 5 pages, 3 figures, Accepted Version, PRL, minor wording change

New insights into the dust formation of oxygen-rich AGB stars

We observed the AGB stars S Ori, GX Mon and R Cnc with the MIDI instrument at the VLTI. We compared the data to radiative transfer models of the dust shells, where the central stellar intensity profiles were described by dust-free dynamic model atmospheres. We used Al2O3 and warm silicate grains. Our S Ori and R Cnc data could be well described by an Al2O3 dust shell alone, and our GX Mon data by a mix of an Al2O3 and a silicate shell. The best-fit parameters for S Ori and R Cnc included photospheric angular diameters Theta(Phot) of 9.7+/-1.0mas and 12.3+/-1.0mas, optical depths tau(V)(Al2O3) of 1.5+/-0.5 and 1.35+/-0.2, and inner radii R(in) of 1.9+/-0.3R(Phot) and 2.2+/-0.3R(Phot), respectively. Best-fit parameters for GX Mon were Theta(Phot)=8.7+/-1.3mas, tau(V)(Al2O3)=1.9+/-0.6, R(in)(Al2O3)=2.1+/-0.3R(Phot), tau(V)(silicate)=3.2+/-0.5, and R(in)(silicate)=4.6+/-0.2R(Phot). Our model fits constrain the chemical composition and the inner boundary radii of the dust shells, as well as the photospheric angular diameters. Our interferometric results are consistent with Al2O3 grains condensing close to the stellar surface at about 2 stellar radii, co-located with the extended atmosphere and SiO maser emission, and warm silicate grains at larger distances of about 4--5 stellar radii. We verified that the number densities of aluminum can match that of the best-fit Al2O3 dust shell near the inner dust radius in sufficiently extended atmospheres, confirming that Al2O3 grains can be seed particles for the further dust condensation. Together with literature data of the mass-loss rates, our sample is consistent with a hypothesis that stars with low mass-loss rates form primarily dust that preserves the spectral properties of Al2O3, and stars with higher mass-loss rate form dust with properties of warm silicates.Comment: 20 pages, 10 figure

Treatment of artificial wastewater containing two azo textile dyes by vertical-flow constructed wetlands

The release of untreated dye textile wastewater into receiving streams is unacceptable not only for aesthetic reasons and its negative impacts on aquatic life but also because numerous dyes are toxic and carcinogenic to humans. Strategies, as of now, used for treating textile wastewaters have technical and economical restrictions. The greater part of the physico-chemical methods, which are used to treat this kind of wastewater, are costly, produce large amounts of sludge and are wasteful concerning some soluble dyes. In contrast, biological treatments such as constructed wetlands are cheaper than the traditional methods, environmental friendly and do not produce large amounts of sludge. Synthetic wastewater containing Acid Blue 113 (AB113) and Basic Red 46 (BR46) has been added to laboratory-scale vertical-flow construction wetland systems, which have been planted with Phragmites australis (Cav.) Trin. ex Steud. (common reed). The concentrations 7 and 208 mg/l were applied for each dye at the hydraulic contact times of 48 and 96 h. Concerning the low concentrations of BR46 and AB113, the unplanted wetlands are associated with significant (ρ < 0.05) reduction performances, if compared with planted wetlands concerning the removal of dyes. For the high concentrations of AB113, BR46 and a mixture of both of them, wetlands with long contact times were significantly (ρ < 0.05) better than wetlands that had short contact times in terms of dye, colour and chemical oxygen demand reductions. Regarding nitrate nitrogen (NO3-N), the reduction percentage rates of AB113, BR46 and a mixture dye of both of them were between 85 and 100%. For low and high inflow dye concentrations, best removals were generally recorded for spring and summer, respectively

Shuttle Ground Operations Efficiencies/Technologies Study (SGOE/T). Volume 5: Technical Information Sheets (TIS)

The Technology Information Sheet was assembled in database format during Phase I. This document was designed to provide a repository for information pertaining to 144 Operations and Maintenance Instructions (OMI) controlled operations in the Orbiter Processing Facility (OPF), Vehicle Assembly Building (VAB), and PAD. It provides a way to accumulate information about required crew sizes, operations task time duration (serial and/or parallel), special Ground Support Equipment (GSE). required, and identification of a potential application of existing technology or the need for the development of a new technolgoy item