2,315 research outputs found
Polarization-dependence of palladium deposition on ferroelectric lithium niobate (0001) surfaces
We investigate the effect of ferroelectric polarization direction on the
geometric properties of Pd deposited on the positive and negative surfaces of
LiNbO (0001). We predict preferred geometries and diffusion properties of
small Pd clusters using density functional theory, and use these calculations
as the basis for kinetic Monte Carlo simulations of Pd deposition on a larger
scale. Our results show that on the positive surface, Pd atoms favor a
clustered configuration, while on the negative surface, Pd atoms are adsorbed
in a more dispersed pattern due to suppression of diffusion and agglomeration.
This suggests that the effect of LiNbO polarization direction on the
catalytic activity of Pd [J. Phys. Chem. \textbf{88}, 1148 (1984)] is due, at
least in part, to differences in adsorption geometry. Further investigations
using these methods can aid the search for catalysts whose activities switch
reversibly with the polarization of their ferroelectric substrates
On Ptolemaic metric simplicial complexes
We show that under certain mild conditions, a metric simplicial complex which
satisfies the Ptolemy inequality is a CAT(0) space. Ptolemy's inequality is
closely related to inversions of metric spaces. For a large class of metric
simplicial complexes, we characterize those which are isometric to Euclidean
space in terms of metric inversions.Comment: 13 page
Superfluid Helium Orbital Resupply Coupling
The resupply of superfluid helium to satellites and other space-based experiment packages can increase the useful longevity of these devices far beyond their present life expectancies which are many times determined by the supply of helium coolant. The transfer of superfluid helium to spacecraft in space will require a reusable coupling that functions at 1.8 Kelvin with little heat leak and low pressure drop. Moog has designed the Helium Resupply Coupling to meet these operational requirements. Initially, the coupling manual mode operation will be demonstrated on orbit by an EVA crew member during the Space Shuttle borne Superfluid Helium On-Orbit Transfer (SHOOT) experiment. The ultimate application will use robotic (automatic) coupling operation to which the present design readily adapts. The utilization of Moog's exclusive Rotary Shut-Off (RSO) technology in the development of the Superfluid Helium Resupply Coupling is described. The coupling not only performs the function of a flow control valve and disconnect but also provides adequate safety features for a shuttle launched man-rated payload. In addition, the coupling incorporates the necessary features to provide the high thermal isolation of the internal flow path from the external environment
Oscillatory angular dependence of the magnetoresistance in a topological insulator Bi_{1-x}Sb_{x}
The angular-dependent magnetoresistance and the Shubnikov-de Haas
oscillations are studied in a topological insulator Bi_{0.91}Sb_{0.09}, where
the two-dimensional (2D) surface states coexist with a three-dimensional (3D)
bulk Fermi surface (FS). Two distinct types of oscillatory phenomena are
discovered in the angular-dependence: The one observed at lower fields is shown
to originate from the surface state, which resides on the (2\bar{1}\bar{1})
plane, giving a new way to distinguish the 2D surface state from the 3D FS. The
other one, which becomes prominent at higher fields, probably comes from the
(111) plane and is obviously of unknown origin, pointing to new physics in
transport properties of topological insulators.Comment: 4 pages, 5 figures, revised version with improved data and analysi
Coexistence of two- and three-dimensional Shubnikov-de Haas oscillations in Ar^+ -irradiated KTaO_3
We report the electron doping in the surface vicinity of KTaO_3 by inducing
oxygen-vacancies via Ar^+ -irradiation. The doped electrons have high mobility
(> 10^4 cm^2/Vs) at low temperatures, and exhibit Shubnikov-de Haas
oscillations with both two- and three-dimensional components. A disparity of
the extracted in-plane effective mass, compared to the bulk values, suggests
mixing of the orbital characters. Our observations demonstrate that Ar^+
-irradiation serves as a flexible tool to study low dimensional quantum
transport in 5d semiconducting oxides
Combination quantum oscillations in canonical single-band Fermi liquids
Chemical potential oscillations mix individual-band frequencies of the de
Haas-van Alphen (dHvA) and Shubnikov-de Haas (SdH) magneto-oscillations in
canonical low-dimensional multi-band Fermi liquids. We predict a similar mixing
in canonical single-band Fermi liquids, which Fermi-surfaces have two or more
extremal cross-sections. Combination harmonics are analysed using a single-band
almost two-dimensional energy spectrum. We outline some experimental conditions
allowing for resolution of combination harmonics
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