5,667 research outputs found

    Solidification processing of alloys using an applied electric field

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    A method is provided for obtaining an alloy having an ordered microstructure which comprises the steps of heating the central portion of the alloy under uniform temperature so that it enters a liquid phase while the outer portions remain solid, applying a constant electric current through the alloy during the heating step, and solidifying the liquid central portion of the alloy by subjecting it to a temperature-gradient zone so that cooling occurs in a directional manner and at a given rate of speed while maintaining the application of the constant electric current through the alloy. The method of the present invention produces an alloy having superior characteristics such as reduced segregation. After subsequent precipitation by heat-treatment, the alloys produced by the present invention will have excellent strength and high-temperature resistance

    Dynamics of confined water reconstructed from inelastic x-ray scattering measurements of bulk response functions

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    Nanoconfined water and surface-structured water impacts a broad range of fields. For water confined between hydrophilic surfaces, measurements and simulations have shown conflicting results ranging from “liquidlike” to “solidlike” behavior, from bulklike water viscosity to viscosity orders of magnitude higher. Here, we investigate how a homogeneous fluid behaves under nanoconfinement using its bulk response function: The Green's function of water extracted from a library of S(q,ω) inelastic x-ray scattering data is used to make femtosecond movies of nanoconfined water. Between two confining surfaces, the structure undergoes drastic changes as a function of surface separation. For surface separations of ≈9 Å, although the surface-associated hydration layers are highly deformed, they are separated by a layer of bulklike water. For separations of ≈6 Å, the two surface-associated hydration layers are forced to reconstruct into a single layer that modulates between localized “frozen’ and delocalized “melted” structures due to interference of density fields. These results potentially reconcile recent conflicting experiments. Importantly, we find a different delocalized wetting regime for nanoconfined water between surfaces with high spatial frequency charge densities, where water is organized into delocalized hydration layers instead of localized hydration shells, and are strongly resistant to `freezing' down to molecular distances (<6 Å)

    Cosmology and Astrophysics from Relaxed Galaxy Clusters I: Sample Selection

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    This is the first in a series of papers studying the astrophysics and cosmology of massive, dynamically relaxed galaxy clusters. Here we present a new, automated method for identifying relaxed clusters based on their morphologies in X-ray imaging data. While broadly similar to others in the literature, the morphological quantities that we measure are specifically designed to provide a fair basis for comparison across a range of data quality and cluster redshifts, to be robust against missing data due to point-source masks and gaps between detectors, and to avoid strong assumptions about the cosmological background and cluster masses. Based on three morphological indicators - Symmetry, Peakiness and Alignment - we develop the SPA criterion for relaxation. This analysis was applied to a large sample of cluster observations from the Chandra and ROSAT archives. Of the 361 clusters which received the SPA treatment, 57 (16 per cent) were subsequently found to be relaxed according to our criterion. We compare our measurements to similar estimators in the literature, as well as projected ellipticity and other image measures, and comment on trends in the relaxed cluster fraction with redshift, temperature, and survey selection method. Code implementing our morphological analysis will be made available on the web.Comment: MNRAS, in press. 43 pages in total, of which 17 are tables (please think twice before printing). 18 figures, 4 tables. Machine-readable tables will be available from the journal and at the url below; code will be posted at http://www.slac.stanford.edu/~amantz/work/morph14

    A Theoretical Investigation of the Geometries, Vibrational Frequencies, and Binding Energies of Several Mixed Alkali Halide Dimers

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    Results are presented from ab initio calculations on several mixed alkali halide dimers made up of Li, Na, F, and Cl. All of the dimers are investigated at the restricted Hartree–Fock level to provide ab initio estimates of geometries, vibrational frequencies, and binding energies. The dimer LiNaF2 is then treated using a variety of basis sets at the Hartree–Fock level, as well as at correlated levels (second‐order Møller–Plesset and coupled‐cluster singles and doubles) to examine the sensitivity of the calculations to use of higher levels of theory. The results are then compared to the experimental data available for the LiNaF2 molecule, previous theoretical results for the monomers, and recent semiempirical calculations on the mixed dimers

    Collisional Properties of Cold Spin-Polarized Metastable Neon Atoms

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    We measure the rates of elastic and inelastic two-body collisions of cold spin-polarized neon atoms in the metastable 3P2 state for 20^Ne and 22^Ne in a magnetic trap. From particle loss, we determine the loss parameter of inelastic collisions beta=6.5(18)x10^{-12} cm^3s^{-1} for 20^Ne and beta=1.2(3)x10^{-11}cm^3{s}^{-1} for 22^Ne. These losses are caused by ionizing (i.e. Penning) collisions %to more than and occur less frequently than for unpolarized atoms. This proves the suppression of Penning ionization due to spin-polarization. From cross-dimensional relaxation measurements, we obtain elastic scattering lengths of a=-180(40) a_0 for 20^Ne and a=+150(+80/-50) a_0 for 22^Ne, where a_0=0.0529 nm.Comment: 4 pages, 3 figure

    Cosmology and Astrophysics from Relaxed Galaxy Clusters II: Cosmological Constraints

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    We present cosmological constraints from measurements of the gas mass fraction, fgasf_{gas}, for massive, dynamically relaxed galaxy clusters. Our data set consists of Chandra observations of 40 such clusters, identified in a comprehensive search of the Chandra archive, as well as high-quality weak gravitational lensing data for a subset of these clusters. Incorporating a robust gravitational lensing calibration of the X-ray mass estimates, and restricting our measurements to the most self-similar and accurately measured regions of clusters, significantly reduces systematic uncertainties compared to previous work. Our data for the first time constrain the intrinsic scatter in fgasf_{gas}, (7.4±2.3)(7.4\pm2.3)% in a spherical shell at radii 0.8-1.2 r2500r_{2500}, consistent with the expected variation in gas depletion and non-thermal pressure for relaxed clusters. From the lowest-redshift data in our sample we obtain a constraint on a combination of the Hubble parameter and cosmic baryon fraction, h3/2Ωb/Ωm=0.089±0.012h^{3/2}\Omega_b/\Omega_m=0.089\pm0.012, that is insensitive to the nature of dark energy. Combined with standard priors on hh and Ωbh2\Omega_b h^2, this provides a tight constraint on the cosmic matter density, Ωm=0.27±0.04\Omega_m=0.27\pm0.04, which is similarly insensitive to dark energy. Using the entire cluster sample, extending to z>1z>1, we obtain consistent results for Ωm\Omega_m and interesting constraints on dark energy: ΩΛ=0.650.22+0.17\Omega_\Lambda=0.65^{+0.17}_{-0.22} for non-flat Λ\LambdaCDM models, and w=0.98±0.26w=-0.98\pm0.26 for flat constant-ww models. Our results are both competitive and consistent with those from recent CMB, SNIa and BAO data. We present constraints on models of evolving dark energy from the combination of fgasf_{gas} data with these external data sets, and comment on the possibilities for improved fgasf_{gas} constraints using current and next-generation X-ray observatories and lensing data. (Abridged)Comment: 25 pages, 14 figures, 8 tables. Accepted by MNRAS. Code and data can be downloaded from http://www.slac.stanford.edu/~amantz/work/fgas14/ . v2: minor fix to table 1, updated bibliograph

    Directional solidification processing of alloys using an applied electric field

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    A method is provided for obtaining an alloy having an ordered microstructure which comprises the steps of heating the central portion of the alloy under uniform temperature so that it enters a liquid phase while the outer portions remain solid, applying a constant electric current through the alloy during the heating step, and solidifying the liquid central portion of the alloy by subjecting it to a temperature-gradient zone so that cooling occurs in a directional manner and at a given rate of speed while maintaining the application of the constant electric current through the alloy. The method is particularly suitable for use with nickel-based superalloys. The method of the present invention produces an alloy having superior characteristics such as reduced segregation. After subsequent precipitation by heat-treatment, the alloys produced by the present invention will have excellent strength and high-temperature resistance
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