Fortissat minewater geothermal district heating project: case study

This study summarises the findings of a feasibility assessment for a potential minewater geothermal energy system in the vicinity of the James Hutton Institute’s Hartwood Home Farm, North Lanarkshire in Scotland’s Central Belt. This study aimed to assess the potential for Scotland’s first minewater geothermal scheme in a rural area with social deprivation. While focused on the specifics of the location, the project is conceived as a readily replicable and fully operational minewater geothermal district heating system demonstrator project that would act as proof of concept for duplication elsewhere. This study concluded that, with current support mechanisms, the scheme is technically and financially viable, breaking even or better with a network scenario covering the ‘representative’ communities of Allanton and Hartwood. As might be expected, there are considerable economies of scale, with the scheme becoming commercially viable when the network is extended to the town of Shotts

Probing intermetallic coupling in dinuclear N-heterocyclic carbene ruthenium(II) complexes

A series of bimetallic N-heterocyclic carbene (NHC) ruthenium(II) complexes were synthesized, which comprise two [RuCl₂(cymene)(NHC)] units that are interlinked via the NHC nitrogens by alkyl chains of different length. Electrochemical characterization revealed two mutually dependent oxidation processes for the complex with a methylene linker, indicating moderate intramolecular electronic coupling of the two metal centers (class II system). The degree of coupling decreases rapidly upon increasing the number of CH₂ units in the linker and provides essentially decoupled class I species when propylene or butylene linkers are used. Electrochemical analyses combined with structural investigations suggest a through-bond electronic coupling. Replacement of the alkyl linker with a p-phenylene group afforded cyclometalated complexes, which were considerably less stable. The electronic coupling in the methylene-linked complex and the relatively robust NHC–ruthenium bond may provide access to species that are switchable on the molecular scale