263 research outputs found
Cappuccino and specific heat versus heat of vaporization
A cappuccino is prepared by adding about 50 mL frothing, foaming milk to a cup of espresso. Whole milk is best for foaming and the ideal milk temperature when adding it to the espresso is 65 °C. The espresso itself may be warmer than that. During the heating the milk should not burn, as that would spoil the taste. The best way is to heat the milk slowly while stirring to froth the milk and create foam. But modern cappuccino machines in restaurants do not have time for slow heating. Could we heat the milk by just adding hot water? That’s the question we pose to our high school students first. How many mL of 90 °C hot water would be needed to heat 50 mL of milk from a refrigerator temperature (say 4 °C) to 65 °C? Assume that the specific heat of milk is the same as that of water. Students answer the question on a worksheet and practice their computation skills. The answer: 122 g. This would mean an unacceptable dilution of the milk, 2.5 mL of water for every mL of milk. What would the answer be if we use boiling hot water of 100 °C? Students calculate again, then the answer is 87 g, still an unacceptable dilution. What then? What if we use steam
Cappuccino and specific heat versus heat of vaporization
A cappuccino is prepared by adding about 50 mL frothing, foaming milk to a cup of espresso. Whole milk is best for foaming and the ideal milk temperature when adding it to the espresso is 65 °C. The espresso itself may be warmer than that. During the heating the milk should not burn, as that would spoil the taste. The best way is to heat the milk slowly while stirring to froth the milk and create foam. But modern cappuccino machines in restaurants do not have time for slow heating. Could we heat the milk by just adding hot water?
Neutrophils amplify the formation of DNA adducts by benzo[a]pyrene in lung target cells.
Inflammatory cells and their reactive oxygen metabolites can cause mutagenic effects in lung cells. The purpose of this study was to investigate the ability of activated neutrophils to modulate DNA binding of benzo[a]pyrene (B[a]P), a known carcinogen, in lung target cells. Equivalent numbers of rat lung epithelial cells (RLE-6TN cell line) and freshly isolated human blood neutrophils (PMN) were coincubated in vitro for 2 hr after addition of benzo[a]pyrene (0.5 microM) or two of its trans-diol metabolites, with or without stimulation with phorbol myristate acetate (PMA). DNA adducts of B[a]P-metabolites were determined in target cells using 32P-postlabeling; oxidative DNA damage (7-hydro-8-oxo-2'-deoxyguanosine [8-oxodG]) was evaluated by high performance liquid chromatography with electrochemical detection. Increased DNA adducts were observed in lung cells coincubated with polymorphonuclear leukocytes (PMN). Activation of PMN with PMA, or addition of more activated PMN in relation to the number of lung cells, further increased the number of adducts, the latter in a dose-response manner. Incubation with B[a]P-4,5-diol did not result in any adduct formation, while B[a]P-7,8-diol led to a significant number of adducts. Moreover, PMA-activated PMN strongly enhanced adduct formation by B[a]P-7,8-diol, but not 8-oxodG, in lung cells. The addition of antioxidants to the coincubations significantly reduced the number of adducts. Results suggest that an inflammatory response in the lung may increase the biologically effective dose of polycyclic aromatic hydrocarbons (PAHs), and may be relevant to data interpretation and risk assessment of PAH-containing particulates
Ultrafast charge generation in a semiconducting polymer studied with THz emission spectroscopy
Euan Hendry, Mattijs Koeberg, Juleon M. Schins, L. D. A. Siebbeles, and Mischa Bonn, Physical Review B, Vol. 70, article 033202 (2004). "Copyright © 2004 by the American Physical Society."We study the ultrafast charge generation in a semiconducting polymer (MEH-PPV) by measuring the radiated THz field after photoexciting the biased polymer with a femtosecond visible pulse. The subpicosecond temporal characteristics of the emitted wave reflects the ultrafast photoconductivity dynamics and sets an upper limit for charge generation of 200 fs following photoexcitation, and reveals the dispersive nature of charge transport in MEH-PPV. A comparison of the fields radiated from MEH-PPV and the well-characterized model semiconductor system (GaAs) allows for an accurate estimate of the quantum efficiency for charge generation in the polymer, found to be less than 1% . Both observations are consistent with ultrafast charge generation in semiconducting polymers through hot exciton dissociation
Aging and memory effects in beta-hydrochinone-clathrate
The out-of-equilibrium low-frequency complex susceptibility of the
orientational glass methanol(73%)-beta-hydrochinone-clathrate is studied using
temperature-stop protocols in aging experiments . Although the material does
not have a sharp glass transition aging effects including rejuvenation and
memory are found at low temperatures. However, they turn out to be much weaker,
however, than in conventional magnetic spin glasses.Comment: 5 pages RevTeX, 6 eps-figures include
Interchain effects in the ultrafast photophysics of a semiconducting polymer: THz time-domain spectroscopy of thin films and isolated chains in solution
Euan Hendry, Mattijs Koeberg, Juleon M. Schins, H. K. Nienhuys, V. Sundström, L. D. A. Siebbeles, and Mischa Bonn, Physical Review B, Vol. 71, article 125201 (2005). "Copyright © 2005 by the American Physical Society."We compare the generation and decay dynamics of charges and excitons in a model polymer semiconductor (MEH-PPV) in solution and drop-cast thin films, by recording the sub-ps transient complex conductivity using THz time-domain spectroscopy. The results show that the quantum efficiency of charge generation is two orders of magnitude smaller in solution (~10–5) than in the solid film (~10–3). The proximity of neighboring chains in the films apparently facilitates (hot) exciton dissociation, presumably by allowing the electron and hole to separate on different polymer strands. For both samples, photoexcitation leads to the predominant formation of bound charge pairs (excitons) that can be detected through their polarizability. Surprisingly, the polarizability per absorbed photon is a factor of 3 larger in solution than in the film, suggesting that interchain interactions in the film do not result in a substantial delocalization of the exciton wave function
Universality, frustration and conformal invariance in two-dimensional random Ising magnets
We consider long, finite-width strips of Ising spins with randomly
distributed couplings. Frustration is introduced by allowing both ferro- and
antiferromagnetic interactions. Free energy and spin-spin correlation functions
are calculated by transfer-matrix methods. Numerical derivatives and
finite-size scaling concepts allow estimates of the usual critical exponents
, and to be obtained, whenever a second-order
transition is present. Low-temperature ordering persists for suitably small
concentrations of frustrated bonds, with a transition governed by pure--Ising
exponents. Contrary to the unfrustrated case, subdominant terms do not fit a
simple, logarithmic-enhancement form. Our analysis also suggests a vertical
critical line at and below the Nishimori point. Approaching this point along
either the temperature axis or the Nishimori line, one finds non-diverging
specific heats. A percolation-like ratio is found upon analysis of
the uniform susceptibility at the Nishimori point. Our data are also consistent
with frustration inducing a breakdown of the relationship between
correlation-length amplitude and critical exponents, predicted by conformal
invariance for pure systems.Comment: RevTeX code for 10 pages, 9 eps figures, to appear in Physical Review
B (September 1999
Numerical Study on Aging Dynamics in the 3D Ising Spin-Glass Model. II. Quasi-Equilibrium Regime of Spin Auto-Correlation Function
Using Monte Carlo simulations, we have studied isothermal aging of
three-dimensional Ising spin-glass model focusing on quasi-equilibrium behavior
of the spin auto-correlation function. Weak violation of the time translational
invariance in the quasi-equilibrium regime is analyzed in terms of {\it
effective stiffness} for droplet excitations in the presence of domain walls.
Within the range of computational time window, we have confirmed that the
effective stiffness follows the expected scaling behavior with respect to the
characteristic length scales associated with droplet excitations and domain
walls, whose growth law has been extracted from our simulated data. Implication
of the results are discussed in relation to experimental works on ac
susceptibilities.Comment: 18 pages, 6 figure
Domain growth by isothermal aging in 3d Ising and Heisenberg spin glasses
Non-equilibrium dynamics of three dimensional model spin glasses - the Ising
system FeMnTiO and the Heisenberg like system Ag(11 at%
Mn) - has been investigated by measurements of the isothermal time decay of the
low frequency ac-susceptibility after a quench from the paramagnetic to the
spin glass phase. It is found that the relaxation data measured at different
temperatures can be scaled according to predictions from the droplet scaling
model, provided that critical fluctuations are accounted for in the analyzes.Comment: 5 pages, 3 figure
Scaling properties in off equilibrium dynamical processes
In the present paper, we analyze the consequences of scaling hypotheses on
dynamic functions, as two times correlations . We show, under general
conditions, that must obey the following scaling behavior , where the scaling variable is
and , two
undetermined functions. The presence of a non constant exponent
signals the appearance of multiscaling properties in the dynamics.Comment: 6 pages, no figure
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