Detecting independence of random vectors: generalized distance covariance and Gaussian covariance

Distance covariance is a quantity to measure the dependence of two random vectors. We show that the original concept introduced and developed by Sz\'{e}kely, Rizzo and Bakirov can be embedded into a more general framework based on symmetric L\'{e}vy measures and the corresponding real-valued continuous negative definite functions. The L\'{e}vy measures replace the weight functions used in the original definition of distance covariance. All essential properties of distance covariance are preserved in this new framework. From a practical point of view this allows less restrictive moment conditions on the underlying random variables and one can use other distance functions than Euclidean distance, e.g. Minkowski distance. Most importantly, it serves as the basic building block for distance multivariance, a quantity to measure and estimate dependence of multiple random vectors, which is introduced in a follow-up paper [Distance Multivariance: New dependence measures for random vectors (submitted). Revised version of arXiv: 1711.07775v1] to the present article.Comment: Published at https://doi.org/10.15559/18-VMSTA116 in the Modern Stochastics: Theory and Applications (https://www.i-journals.org/vtxpp/VMSTA) by VTeX (http://www.vtex.lt/

Strong Effect of Weak Charging in Suspensions of Anisotropic Colloids

Suspensions of hard colloidal particles frequently serve as model systems in studies on fundamental aspects of phase transitions. But often colloidal particles that are considered as ``hard'' are in fact weakly charged. If the colloids are spherical, weak charging has a only a weak effect on the structural properties of the suspension, which can be easily corrected for. However, this does not hold for anisotropic particles. We introduce a model for the interaction potential between charged ellipsoids of revolution (spheroids) based on the Derjaguin approximation of Debye--H\"uckel Theory and present a computer simulation study on aspects of the system's structural properties and phase behaviour. In line with previous experimental observations, we find that even a weak surface charge has a strong impact on the correlation functions. A likewise strong impact is seen on the phase behaviour, in particular, we find stable cubatic order in suspensions of oblate ellipsoids

Solid phase properties and crystallization in simple model systems

We review theoretical and simulational approaches to the description of equilibrium bulk crystal and interface properties as well as to the nonequilibrium processes of homogeneous and heterogeneous crystal nucleation for the simple model systems of hard spheres and Lennard-Jones particles. For the equilibrium properties of bulk and interfaces, density functional theories employing fundamental measure functionals prove to be a precise and versatile tool, as exemplified with a closer analysis of the hard sphere crystalliquid interface. A detailed understanding of the dynamic process of nucleation in these model systems nevertheless still relies on simulational approaches. We review bulk nucleation and nucleation at structured walls and examine in closer detail the influence of walls with variable strength on nucleation in the Lennard-Jones fluid. We find that a planar crystalline substrate induces the growth of a crystalline film for a large range of lattice spacings and interaction potentials. Only a strongly incommensurate substrate and a very weakly attractive substrate potential lead to crystal growth with a non-zero contact angle