6,422 research outputs found

    Possible indicators for low dimensional superconductivity in the quasi-1D carbide Sc3CoC4

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    The transition metal carbide Sc3CoC4 consists of a quasi-one-dimensional (1D) structure with [CoC4]_{\inft} polyanionic chains embedded in a scandium matrix. At ambient temperatures Sc3CoC4 displays metallic behavior. At lower temperatures, however, charge density wave formation has been observed around 143K which is followed by a structural phase transition at 72K. Below T^onset_c = 4.5K the polycrystalline sample becomes superconductive. From Hc1(0) and Hc2(0) values we could estimate the London penetration depth ({\lambda}_L ~= 9750 Angstroem) and the Ginsburg-Landau (GL) coherence length ({\xi}_GL ~= 187 Angstroem). The resulting GL-parameter ({\kappa} ~= 52) classifies Sc3CoC4 as a type II superconductor. Here we compare the puzzling superconducting features of Sc3CoC4, such as the unusual temperature dependence i) of the specific heat anomaly and ii) of the upper critical field H_c2(T) at T_c, and iii) the magnetic hysteresis curve, with various related low dimensional superconductors: e.g., the quasi-1D superconductor (SN)_x or the 2D transition-metal dichalcogenides. Our results identify Sc3CoC4 as a new candidate for a quasi-1D superconductor.Comment: 4 pages, 5 figure

    Direct picosecond time resolution of unimolecular reactions initiated by local mode excitation

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    The concept of local mode (LM) states [1] in large molecules raises the possibilty of inducing chemical reactions from a well-defined initial state (bond-selective chemistry). The results of linewidth and energy measurements in gases, [2(a)] and low temperature solids, [2(b)] however, indicate that the relaxation times for such high energy (> 15000 cm^-1) states can be extremely short, < 1ps. Because of the lack of direct time-resolved measurements, the following fundamental questions have not been unequivocally answered: What are the homogeneous linewidths of LM states and what are the rates of energy relaxation or reaction out of these states? Over the past five years we have made several attempts to observe the picosecond dynamics of LM states. Due to the inherent difficulties associated with making these measurements, such as the very small oscillator strength (σ < 10^-23 cm^2), an extremely sensitive probing technique becomes imperative

    An Experiment on Innovation and Collusion

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    This paper examines the relationship between product innovation and the success of price collusion using novel laboratory experiments. Average market prices in low innovation (LO) experiments are significantly higher than those in high innovation, but otherwise identical experiments. This price difference is attributed to LO experimental subjects\u27 greater common market experience. The data illustrate how collusion can be perceived as the only way to make it in LO markets where product innovation is not a viable strategy for increasing profits. They suggest that product homogeneity can be a proximate cause, and product innovation an ultimate cause, of collusion

    Unusual Non-Fermi Liquid Behavior of Ce1x_{1-x}Lax_{x}Ni9_{9}Ge4_4 Analyzed in a Single Impurity Anderson Model with Crystal Field Effects

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    CeNi9_{9}Ge4_4 exhibits unusual non-Fermi liquid behavior with the largest ever recorded value of the electronic specific heat ΔC/T5.5\Delta C/T \cong 5.5 JK2^{-2}mol1^{-1} without showing any evidence of magnetic order. Specific heat measurements show that the logarithmic increase of the Sommerfeld coefficient flattens off below 200 mK. In marked contrast, the local susceptibility Δχ\Delta\chi levels off well above 200 mK and already becomes constant below 1 K. Furthermore, the entropy reaches 2RRln2 below 20 K corresponding to a four level system. An analysis of CC and χ\chi was performed in terms of an SU(N=4)SU(N=4) single impurity Anderson model with additional crystal electric field (CEF) splitting. Numerical renormalization group calculations point to a possible consistent description of the different low temperature scales in Δc\Delta c and Δχ\Delta \chi stemming from the interplay of Kondo effect and crystal field splitting.Comment: 2 pages, 2 figure

    Gauge symmetric delta(1232) couplings and the radiative muon capture in hydrogen

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    Using the difference between the gauge symmetric and standard pi-N-delta couplings, a contact pi-pi-N-N term, quadratic in the pi-N-delta coupling, is explicitly constructed. Besides, a contribution from the delta excitation mechanism to the photon spectrum for the radiative muon capture in hydrogen is derived from the gauge symmetric pi-N-delta and gamma-N-delta couplings. It is shown for the photon spectrum, studied recently experimentally, that the new spectrum is for the photon momentums k > 60 MeV by 4-10 % smaller than the one obtained from standardly used couplings with the on-shell deltas.Comment: 9 pages, 3 figure

    The munich LSTM-RNN approach to the MediaEval 2014 "Emotion in Music" Task

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    In this paper we describe TUM's approach for the MediaEval's \Emotion in Music" task. The goal of this task is to automatically estimate the emotions expressed by music (in terms of Arousal and Valence) in a time-continuous fashion. Our system consists of Long-Short Term Memory Recurrent Neural Networks (LSTM-RNN) for dynamic Arousal and Valence regression. We used two di erent sets of acoustic and psychoacoustic features that have been previously proven as e ective for emotion prediction in music and speech. The best model yielded an average Pearson's correlation coe-cient of 0.354 (Arousal) and 0.198 (Valence), and an average Root Mean Squared Error of 0.102 (Arousal) and 0.079 (Valence)

    Phospholipases and the Network of Auxin Signal Transduction with ABP1 and TIR1 as Two Receptors: A Comprehensive and Provocative Model

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    Three types of phospholipases, phospholipase D, secreted phospholipase A2, and patatin-related phospholipase A (pPLA) have functions in auxin signal transduction. Potential linkage to auxin receptors ABP1 or TIR1, their rapid activation or post-translational activation mechanisms, and downstream functions regulated by these phospholipases is reviewed and discussed. Only for pPLA all aspects are known at least to some detail. Evidence is gathered that all these signal reactions are located in the cytosol and seem to merge on regulation of PIN-catalyzed auxin efflux transport proteins. As a consequence, auxin concentration in the nucleus is also affected and this regulates the E3 activity of this auxin receptor. We showed that ABP1, PIN2, and pPLA, all outside the nucleus, have an impact on regulation of auxin-induced genes within 30 min. We propose that regulation of PIN protein activities and of auxin efflux transport are the means to coordinate ABP1 and TIR1 activity and that no physical contact between components of the ABP1-triggered cytosolic pathways and TIR1-triggered nuclear pathways of signaling is necessary to perform this

    Coupled Ito equations of continuous quantum state measurement, and estimation

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    We discuss a non-linear stochastic master equation that governs the time-evolution of the estimated quantum state. Its differential evolution corresponds to the infinitesimal updates that depend on the time-continuous measurement of the true quantum state. The new stochastic master equation couples to the two standard stochastic differential equations of time-continuous quantum measurement. For the first time, we can prove that the calculated estimate almost always converges to the true state, also at low-efficiency measurements. We show that our single-state theory can be adapted to weak continuous ensemble measurements as well.Comment: 5 pages, RevTeX4. In version v2 some minor revisions and clarifications have been incorporated. Moreover, a new reference has been included. Accepted for publication in Journal of Physics A: Mathematical and Genera
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