Synthetic Testing of Load Current Interruption in Medium Voltage Load Break Switches

To conduct the mainly active load current test duty according to IEC 62271-103, a directly powered test circuit and therefore a medium voltage connection or a power generator is needed. A newly developed synthetic test circuit allows to replicate the current as well as the full transient recovery voltage (TRV) and the power frequent recovery voltage (RV) of the direct test circuit up to its crest value. It is dimensioned for voltage classes up to 52 kV and can be adapted to test currents between 630 A and 1250 A. The test circuit allows a detailed investigation of load break switches without costly high power sources and loads. Many parameters, like current and voltage steepness at current zero, as well as different parameters defining the TRV steepness can be varied individually

Hole Doping Effects on Spin-gapped Na2Cu2TeO6 via Topochemical Na Deficiency

We report the magnetic susceptibility and NMR studies of a spin-gapped layered compound Na2Cu2TeO6 (the spin gap $\Delta\sim$ 250 K), the hole doping effect on the Cu2TeO6 plane via a topochemical Na deficiency by soft chemical treatment, and the static spin vacancy effect by nonmagnetic impurity Zn substitution for Cu. A finite Knight shift at the $^{125}$Te site was observed for pure Na2Cu2TeO6. The negative hyperfine coupling constant $^{125}A_{tr}$ is an evidence for the existence of a superexchange pathway of the Cu-O-Te-O-Cu bond. It turned out that both the Na deficiency and Zn impurities induce a Curie-type magnetism in the uniform spin susceptibility in an external magnetic field of 1 T, but only the Zn impurities enhance the low-temperature $^{23}$Na nuclear spin-lattice relaxation rate whereas the Na deficiency suppresses it. A spin glass behavior was observed for the Na-deficient samples but not for the Zn-substituted samples. The dynamics of the unpaired moments of the doped holes are different from that of the spin vacancy in the spin-gapped Cu2TeO6 planes.Comment: 4 pages, 7 figures, to be published in J. Phys. Soc. Jpn. Vol. 75, No. 8 (2006

Influence of Oxygen-containing Filling Gas Mixtures on the Interruption Capability of MV Load Break Switches

Nowadays SF6 is commonly used as filling gas for medium voltage load break switches due to its outstanding insulating and arc-quenching properties. However, due to its high global warming potential the interrupting performance of alternative eco-friendly gases are investigated for such devices. This contribution investigates the thermal interruption capability of a medium voltage load break switch using two different oxygen-containing gas mixtures: dry air and a mixture of nitrogen, oxygen and carbon dioxide. The findings indicate an improved performance in comparison to pure nitrogen when considering an admixture of oxygen. In gas mixtures containing 80\% nitrogen, the addition of oxygen results in an enhanced thermal interruption capability compared to an equivalent proportion of carbon dioxide

59Co Nuclear Quadrupole Resonance Studies of Superconducting and Non-superconducting Bilayer Water Intercalated Sodium Cobalt Oxides NaxCoO2.yH2O

We report 59Co nuclear quadrupole resonance (NQR) studies of bilayer water intercalated sodium cobalt oxides NaxCoO2.yH2O (BLH) with the superconducting transition temperatures, 2 K < T_c <= 4.6 K, as well as a magnetic BLH sample without superconductivity. We obtained a magnetic phase diagram of T_c and the magnetic ordering temperature T_M against the peak frequency nu_3 59Co NQR transition I_z = +- 5/2 +-7/2 and found a dome shape superconducting phase. The 59Co NQR spectrum of the non-superconducting BLH shows a broadening below T_M without the critical divergence of 1/T_1 and 1/T_2, suggesting an unconventional magnetic ordering. The degree of the enhancement of 1/T_1T at low temperatures increases with the increase of nu_3 though the optimal nu_3~12.30 MHz. In the NaxCoO2.yH2O system, the optimal-T_c superconductivity emerges close to the magnetic instability. T_c is suppressed near the phase boundary at nu_3~12.50 MHz, which is not a conventional magnetic quantum critical point.Comment: 4 pages, 5 figure

Correlation between Superconducting Transition Temperature TcT_c and Increase of Nuclear Spin-Lattice Relaxation Rate Devided by Temperature 1/T1T1/T_1T at TcT_c in the Hydrate Cobaltate Nax_{x}CoO2⋅y_{2}\cdot yH2_{2}O

We have performed Co-nuclear quadrupole resonance (NQR) studies on Na$_{x}$CoO$_{2}\cdot y$H$_{2}$O compounds with different Na ($x$) and hydrate ($y$) contents. Two samples with different Na contents but nearly the same $T_c$ values ($x$ = 0.348, $T_c$ = 4.7 K ; $x$ = 0.339, $T_c$ = 4.6 K) were investigated. The spin-lattice relaxation rate $1/T_1$ in the superconducting (SC) and normal states is almost the same for the two samples except just above $T_c$. NQR measurements were also performed on different-hydrate-content samples with different $T_c$ values, which were prepared from the same Na-content ($x$ = 0.348) sample. From measurements of $1/T_1$ using the different-hydrate-content samples, it was found that a low-$T_c$ sample with $T_c = 3.9$ K has a larger residual density of states (DOS) in the SC state and a smaller increase of $1/T_1T$ just above $T_c$ than a high-$T_c$ sample with $T_c$ = 4.7 K. The former behavior is consistent with that observed in unconventional superconductors, and the latter suggests the relationship between $T_c$ and the increase in DOS just above $T_c$. This increase, which is seemingly associated with the two-dimensionality of the CoO$_2$ plane, is considered to be one of the most important factors for the occurrence of superconductivity.Comment: 5 pages, 5 figures, To be published in J. Phys. Soc. Jp

Novel phase diagram of superconductor NaxCoO2-yH2O in a 75 % relative humidity

We succeeded in synthesizing the powder samples of bilayer-hydrate sodium cobalt oxide superconductors NaxCoO2-yH2O with Tc = 0 ~ 4.6 K by systematically changing the keeping duration in a 75 % relative humidity atmosphere after intercalation of water molecules. From the magnetic measurements, we found that the one-day duration sample does not show any superconductivity down to 1.8 K, and that the samples kept for 2 ~ 7 days show superconductivity, in which Tc increases up to 4.6 K with increasing the duration. Tc and the superconducting volume fraction are almost invariant between 7 days and 1month duration. The 59Co NQR spectra indicate a systematic change in the local charge distribution on the CoO2 plane with change in duration.Comment: 4 pages, 5 figures, submitted to Journal of the Physical Society of Japa

Structure and Dynamics of Superconducting NaxCoO(2) Hydrate and Its Unhydrated Analog

Neutron scattering has been used to investigate the crystal structure and lattice dynamics of superconducting Na0.3CoO2 1.4(H/D)2O, and the parent Na0.3CoO2 material. The structure of Na0.3CoO2 consists of alternate layers of CoO2 and Na and is the same as the structure at higher Na concentrations. For the superconductor, the water forms two additional layers between the Na and CoO2, increasing the c-axis lattice parameter of the hexagonal P63/mmc space group from 11.16 A to 19.5 A. The Na ions are found to occupy a different configuration from the parent compound, while the water forms a structure that replicates the structure of ice. Both types of sites are only partially occupied. The CoO2 layer in these structures is robust, on the other hand, and we find a strong inverse correlation between the CoO2 layer thickness and the superconducting transition temperature (TC increases with decreasing thickness). The phonon density-of-states for Na0.3CoO2 exhibits distinct acoustic and optic bands, with a high-energy cutoff of ~100 meV. The lattice dynamical scattering for the superconductor is dominated by the hydrogen modes, with librational and bending modes that are quite similar to ice, supporting the structural model that the water intercalates and forms ice-like layers in the superconductor.Comment: 14 pages, 7 figures, Phys. Rev. B (in press). Minor changes + two figures removed as requested by refere

Unconventional Superconductivity and Nearly Ferromagnetic Spin Fluctuations in Nax_xCoO2_2⋅y\cdot yH2_2O

Co NQR studies were performed in recently discovered superconductor Na$_x$CoO$_2$$\cdot y$H$_2$O to investigate physical properties in the superconducting (SC) and normal states. Two samples from the same Na$_x$CoO$_2$ were examined, SC bilayer-hydrate sample with $T_c \sim 4.7$ K and non-SC monolayer-hydrate sample. From the measurement of nuclear-spin lattice relaxation rate $1/T_1$ in the SC sample, it was found that the coherence peak is absent just below $T_c$ and that $1/T_1$ is proportional to temperature far below $T_c$. These results, which are in qualitatively agreement with the previous result by Fujimoto {\it et al.}, suggest strongly that unconventional superconductivity is realized in this compound. In the normal state, $1/T_1T$ of the SC sample shows gradual increase below 100K down to $T_c$, whereas $1/T_1T$ of the non-SC sample shows the Korringa behavior in this temperature range. From the comparison between $1/T_1T$ and $\chi_{\rm bulk}$ in the SC sample, the increase of $1/T_1T$ is attributed to nearly ferromagnetic fluctuations. These remarkable findings suggest that the SC sample possesses nearly ferromagnetic fluctuations, which are possibly related with the unconventional superconductivity in this compound. The implication of this finding is discussed.Comment: 4 pages, 5 figures. submitted to J. Phys. Soc. Jp

Adhesion of HVOF-sprayed WC-Co coatings on 316L substrates processed by SLM

Different studies have been demonstrated that the surface integrity of substrate bulk materials to be coated has a significant impact on the adhesion of thermally sprayed coatings. It is known that the surface integrity of parts processed by selective laser melting (SLM) differs from those obtained from bulk materials. Although 316L stainless steel is among the most investigated material for SLM, the adhesion of thermally sprayed coatings on 316L stainless steel substrates processed by SLM has not been studied yet. This study aims at evaluating the effect of various mechanical pre-treatments onto 316L stainless steel substrates processed by SLM and their effect on the adhesion of high velocity oxy-fuel (HVOF)-sprayed WC-Co coatings. To differentiate between topographical effects and residual stress-related phenomena, a stress-relief heat treatment of the SLM substrates served as a reference throughout the investigations. The differently pre-treated SLM substrates were investigated with regard to the surface roughness and residual stresses. For the HVOF-sprayed SLM composites, Vickers interfacial indentation tests were conducted to assess the resulting coating adhesion. The findings demonstrated that the HVOF-sprayed WC-Co coatings predominantly exhibit good adhesion to the SLM 316L substrates. However, it was found that the stress state in the SLM 316L substrate surface is more likely to affect the adhesion of the WC-Co coating, while the substrate surface roughness showed a marginal effect

International Courts and the Crime of Genocide

En este trabajo realizo un análisis jurídico de los elementos constitutivos (tanto subjetivos como objetivos) del crimen de genocidio, tal y como han sido interpretados y aplicados por la jurisprudencia internacional. En concreto, se estudia la jurisprudencia de la Corte Internacional de Justicia, del Tribunal Internacional Penal para la antigua Yugoslavia y del Tribunal Internacional Penal para Ruanda sobre el crimen de genocidio