Real-time setup to measure radon emission during rock deformation. Implications for geochemical surveillance

Laboratory experiments can represent a valid approach to unravel the complex interplay between the geochemical behaviour of radon and rock deformation mechanisms. In light of this, we present a new real-time experimental setup for analysing in continuum the alpha-emitting 222Rn and 220Rn daughters over variable stress–strain regimes. The most innovative segment of this setup consists of the radon accumulation chamber obtained from a tough and durable material that can host large cylindrical rock samples. The accumulation chamber is connected, in a closed-loop configuration, to a gas-drying unit and to a RAD7 radon monitor. A recirculating pump moves the gas from the rock sample to a solid-state detector for alpha counting of radon and thoron progeny. The measured radon signal is enhanced by surrounding the accumulation chamber with a digitally controlled heating belt. As the temperature is increased, the number of effective collisions of radon atoms increases favouring the diffusion of radon through the material and reducing the analytical uncertainty. The accumulation chamber containing the sample is then placed into a uniaxial testing apparatus where the axial deformation is measured throughout a linear variable displacement transducer. A dedicated software allows obtaining a variety of stress–strain regimes from fast deformation rates to long-term creep tests. Experiments conducted with this new real-time setup have important ramifications for the interpretation of geochemical anomalies recorded prior to volcanic eruptions or earthquakes

International cooperation during volcanic crisis: an example from the Italy-El Salvador monitoring system installed at Chaparrastique volcano, El Salvador

On December 29th, 2013, after 12 years of inactivity, a new explosive eruption occurred at Chaparrastique volcano (San Miguel, el Salvador) prompting the evacuation of more than 5000 people. The new eruption that occurred at the volcano has so far been an isolated single explosion of vulcanian type, and was the first eruption since 2002, when the volcano produced a small VEI 1 eruption. The explosion produced an ash plume of considerable (5-10 km) height, generating heavy ash fall in nearby areas downwind, such as in the towns of Chinameca and San Jorge. Pyroclastic density currents also affected the flanks, damaging the coffee plantations and small inhabited areas around the volcano. On January 2014, following a request of support by the government of El Salvador, INGV (Istituto Nazionale di Geofisica e Vulcanologia), organized a task force, V-Emer (Volcano Emergency) to improve the existing monitoring network at Chaparrastque volcano. During a 10 days campaign in El Salvador a temporary network was successfully installed, and it is now run by the volcanologists of MARN (Ministerio de Medio Ambiente y Recursos Naturales, El Salvador). The network is composed of five broadband seismic stations, 3 infrasonic microphones, 2 radiometers, 10 GPS stations, 1 thermal camera, 1 DOAS and 1 multi-gas geochemical station for measurement of SO2 and CO2 fluxes, respectively. Since 27 January, significant collaborative efforts are being done between MARN and INGV for the processing and interpretation of the data collected during monitoring. For facilitating communication and exchange between the members of the cooperation, a mailing list has been created, and weekly meetings are attended by the members for the discussion on a number of scientific and technical aspects. This initiative seeks to make significant advance into volcano monitoring network and data analysis, as well as improving international cooperation during volcanic crisis management. V-EMER group: A. Bonforte, G. Giuffrida,A. La Spina, F. Montalvo, M. Liuzzo, S. Rapisarda, G. Salerno, D. Andronico, E. Biale, A. Cannata, T. Caltabiano, E. Del Bello, M. La Rocca, D. Granieri, L. Lodato, G. Giudice, F. Murè, E. Pecora, M. Prestifilippo, L. Scuderi, L. Zuccarello, G. De Natale, R. Favara, E. Privitera. MARN group: M. Diaz, D. Escobar, E. Gutierrez, D. Hernandez, G. Marroquin, C. Bolaños, L. Handal, C. Polío, B. Palacios, N. Galvez, R. Torres, E. Escobar

Effect of glass on the frictional behavior of basalts at seismic slip rates

We performed 31 friction experiments on glassy basalts (GB) and glass-free basalts (GFB) at slip rates up to 6.5 m s−1 and normal stress up to 40 MPa (seismic conditions). Frictional weakening was associated to bulk frictional melting and lubrication. The weakening distance (Dw) was about 3 times shorter in GB than in GFB, but the steady state friction was systematically higher in GB than in GFB. The shorter Dw in GB may be explained by the thermal softening occurring at the glass transition temperature (Tg ~500°C), which is lower than the bulk melting temperature (Tm ~1250°C) of GFB. Postexperiment microanalyses suggest that the larger crystal fraction measured in GB melts results in the higher steady state friction value compared to the GFB melts. The effect of interstitial glass is to facilitate frictional instability and rupture propagation in GB with respect to GFB

Decarbonation and thermal microcracking under magmatic P-T-fCO2 conditions: the role of skarn substrata in promoting volcanic instability

We present a systematic study on the influence of pressure (0.1-600 MPa), temperature (750- 1200oC), carbon dioxide fugacity (logfCO2 = -4.41 to 3.60) and time (2-12 hr) on the chemical and physical properties of carbonate rock. Our experiments aim to reproduce the conditions at the periphery of magma chamber where carbonate host rock is influenced by, but not readily assimilated by, magma. This permits the investigation of the natural conditions at which circulating fluids/gases promote infiltration reactions typical of metasomatic skarns that can involve large volumes of subvolcanic carbonate basements. Results show that, providing that carbon dioxide is retained in the pore space, decarbonation does not proceed at any magmatic pressure and temperature. However, when the carbon dioxide is free to escape, decarbonation can occur rapidly and is not hindered by a low initial porosity or permeability. Together with carbon dioxide and lime, portlandite, a mineral commonly found in voluminous metasomatic skarns, readily forms during carbonate decomposition. Post-experimental analyses highlight that thermal microcracking, a result of the highly anisotropic thermal expansion of calcite, exerts a greater influence on rock physical properties (porosity, ultrasonic wave velocities and elastic moduli) than decarbonation. Our data suggest that this will be especially true at the margins of dykes or magma bodies, where temperatures can reach up to 1200oC. However, rock compressive strength is significantly reduced by both thermal cracking and decarbonation, explained by the relative weakness of lime + portlandite compared to calcite, and an increase in grain size with increasing temperature. Metasomatic skarns, whose petrogenetic reactions may involve a few tens of cubic kilometres, could therefore represent an important source of volcanic instability. © The Authors 2013 Published by Oxford University Press on behalf of The Royal Astronomical Society

The application of ecologically intensive principles to the systemic redesign of livestock farms on native grasslands: A case of co-innovation in Rocha, Uruguay

CONTEXT: Family-run cow-calf farms based on native grasslands exhibit low economic and social sustainability, as reflected in low family incomes and high workloads. Experimental results have shown that pasture–herd interaction management could improve native grasslands and animal productivity OBJECTIVE: This paper analyzes the extent to which the sustainability of family-run livestock farms based on native grasslands could be enhanced by a systemic redesign informed by ecological intensification practices. The research questions address the initial state of farm sustainability, key bottlenecks to improving farm sustainability, and changes in sustainability criteria achieved over three years of farm redesign. METHODS: The study was executed as part of a multi-level co-innovation project in Uruguay in which a team of scientist-practitioners and seven farm families participated in farm characterization, diagnosis, and redesign. The farm characterization took the form of indicators to describe the farms’ management and bio-physical subsystems. Redesign plans were negotiated between the research team and the farmers. Frequent monitoring and evaluation cycles enabled finetuning across the years of implementation. RESULTS AND CONCLUSION: Improvements were observed in the economic indicators gross margin (+55%), return to labor (+71%), and family income (+53%) and in the social indicator workload ( 22%), and the environmental indicators bird diversity and ecosystem integrity index were maintained or increased slightly. These changes were explained by the uptake of coherent sets of ecological intensification practices causing changes in forage height (+30%), forage allowance (+69%), pregnancy (+22), weight of weaning calf per mating cow (+32%), and presence of tussocks (+65%). Ecological intensification principles resulted in synergistic positive effects between productivity–biodiversity tradeoffs and the scope for enhanced farm resilience and stability. SIGNIFICANCE: Cow-calf family-run farms can be transformed to produce positive environmental and social effects and viable economic results. The implementation of projects in a co-innovation context may be taken as a guide to scaling up and scaling out the ecological intensification of livestock production on native grasslands, contributing to an extension system at the national level with the aim of improving cow-calf systems sustainability.Estación Experimental Agropecuaria BarilocheFil: Ruggia, Andrea. Instituto Nacional de Investigacion Agropecuaria (INIA). Programa Nacional de Investigacion en Produccion Familiar. Estacion Experimental INIA Las Brujas; UruguayFil: Dogliotti, Santiago. Universidad de la República. Facultad de Agronomía. Departamento de Produccion Vegetal; UruguayFil: Aguerre, Maria Veronica. Instituto Nacional de Investigacion Agropecuaria (INIA). Programa Nacional de Investigacion en Produccion Familiar. Estacion Experimental INIA Las Brujas; UruguayFil: Albicette, Maria Marta. Instituto Nacional de Investigacion Agropecuaria (INIA). Programa Nacional de Investigacion en Produccion Familiar. Estacion Experimental INIA Las Brujas; UruguayFil: Blumetto, Oscar. Instituto Nacional de Investigacion Agropecuaria (INIA). Programa Nacional de Investigacion en Produccion Familiar. Estacion Experimental INIA Las Brujas; UruguayFil: Cardozo, Geronimo. Instituto Nacional de Investigacion Agropecuaria (INIA). Programa Nacional de Investigacion en Pasturas y Forrajes. Estacion Experimental INIA Treinta y Tres; UruguayFil: Leoni, Carolina. Instituto Nacional de Investigacion Agropecuaria (INIA). Programa Nacional de Investigacion en Produccion Familiar. Estacion Experimental INIA Las Brujas; UruguayFil: Quintans, Graciela. Instituto Nacional de Investigacion Agropecuaria (INIA). Programa Nacional de Investigacion en Carne y Lana. Estacion Experimental INIA Treinta y Tres; UruguayFil: Scarlato, Santiago. nstituto Nacional de Investigacion Agropecuaria (INIA). Programa Nacional de Investigacion en Produccion Familiar. Estacion Experimental INIA Las Brujas; UruguayFil: Tittonell, Pablo Adrian. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Bariloche; ArgentinaFil: Tittonell, Pablo Adrian. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Instituto de Investigaciones Forestales y Agropecuarias Bariloche; ArgentinaFil: Rossing, Walter A.H. Wageningen University and Research. Farming Systems Ecology, Plant Sciences Group; Holand

ISPD mutations account for a small proportion of Italian Limb Girdle Muscular Dystrophy cases

Background: Limb Girdle Muscular Dystrophy (LGMD), caused by defective a\u3b1-dystroglycan (a\u3b1-DG) glycosylation, was recently associated with mutations in Isoprenoid synthase domain-containing (ISPD) and GDP-mannose pyrophosphorylase B (GMPPB) genes. The frequency of ISPD and GMPPB gene mutations in the LGMD population is unknown. Methods: We investigated the contributions of ISPD and GMPPB genes in a cohort of 174 Italian patients with LGMD, including 140 independent probands. Forty-one patients (39 probands) from this cohort had not been genetically diagnosed. The contributions of ISPD and GMPPB were estimated by sequential a\u3b1-DG immunohistochemistry (IHC) and mutation screening in patients with documented a\u3b1-DG defect, or by direct DNA sequencing of both genes when muscle tissue was unavailable. Results: We performed a\u3b1-DG IHC in 27/39 undiagnosed probands: 24 subjects had normal a\u3b1-DG expression, two had a partial deficiency, and one exhibited a complete absence of signal. Direct sequencing of ISPD and GMPPB revealed two heterozygous ISPD mutations in the individual who lacked a\u3b1-DG IHC signal: c.836-5 T > G (which led to the deletion of exon 6 and the production of an out-of-frame transcript) and c.676 T > C (p.Tyr226His). This patient presented with sural hypertrophy and tip-toed walking at 5 years, developed moderate proximal weakness, and was fully ambulant at 42 years. The remaining 12/39 probands did not exhibit pathogenic sequence variation in either gene. Conclusion:ISPD mutations are a rare cause of LGMD in the Italian population, accounting for less than 1 % of the entire cohort studied (FKRP mutations represent 10 %), while GMPPB mutations are notably absent in this patient sample. These data suggest that the genetic heterogeneity of LGMD with and without a\u3b1-DG defects is greater than previously realized