Water vapor adsorption on Mars

Near-surface air moisture observations from Phoenix and Curiosity display diurnal adsorption, which appears insensitive to mineralogy of regolith. To study this, adsorptive column model simulations are made for midsummer at Phoenix, validated against recalibrated TECP water vapor pressures p. Two standard-form (= obeying the van't Hoff equilibrium law) adsorption isotherms with quite different specific surface areas A s do produce nearly identical and good matches with the observed p, whereas a widely used non-standard isotherm fails. When made standard, it also produces good results. Adsorbed amounts differ in the three good simulations but their surface fluxes and surface vapor concentrations are nevertheless nearly identical. Properties of regolith except enthalpy are shown to disappear in the model's adsorption term, explaining insensitivity to A(s). The van't Hoff plot of observed In p vs. model's 1/T-g during adsorption and desorption suggests enthalpy of about 22 kJ/mol. Enthalpies of the three standard-form isotherms are close to this, explaining their excellent match with each other and with observations. Hence the low-pressure water vapor adsorption to martian regolith appears essentially nonspecific and is associated with low enthalpy, as is typical for physisorption in general.Peer reviewe

Anti-heat island circulations and low-level jets on a sea gulf

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Annual and diurnal water vapor cycles at Curiosity from observations and column modeling

Local column precipitable water contents (PWC) for more than a martian year from 113 Curiosity ChemCam passive-mode sky scans were used to force a column model with subsurface adsorption. ChemCam volume mixing ratios (vmr) and T, RH and vmr from REMS-H were compared with model results. The REMS-H observations point to decrease of vmr (i.e. depletion of near-surface water vapor) during every evening and night throughout the year. The model's pre-dawn results are quite similar to the REMS-H observations, if adsorption is allowed. The indicated porosity is about 30% and the night depletion ratio about 0.25. If adsorption is not allowed, RH and vmr become excessive during every night at all seasons, leading to ground frost between Ls 82 degrees-146 degrees; frost has not been observed. As brine formation is unlikely along the Curiosity track, adsorption thus appears to be the depleting process. During daytime the ChemCam vmr is in general close to surface values from the Mars Climate Database (MCD) vmr profiles for the Curiosity site when those profiles are scaled to match the ChemCam PWC. Our simulated daytime surface-vmr is in turn close to the ChemCam vmr when moisture is assumed well-mixed to high altitudes, whereas a low moist layer (15 km) leads to overestimates, which are worse during the warm season. Increased TES-like regional PWC also leads to large overestimates of daytime surface-vmr. Hence the crater appears to be drier than the region surrounding Gale and the results support a seasonally varying vertical distribution of moisture with a dry lower atmosphere (by Hadley circulation), as suggested by MCD and other GCM experiments.Peer reviewe

The influence of synoptic scale flow on sea breeze induced surface winds and calm zones

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Surface energy budget at Curiosity through observations and column modeling

Diurnal ground surface temperatures (T-g) and the five major terms of the surface energy budget (SEB) are dis-played from hourly Mars Science Laboratory observations and from column model simulations in four contrasting cases along the Curiosity traverse. T(g )and the SEB terms are otherwise well simulated on regolith near the landing spot and on rocky Pahrump Hills, but the residual in observation-based SEB (-downwelling longwave radiation) shows unexplained peaks in the morning and evening and simultaneously model-T(g )is too cold. Enhanced or diurnally variable crater dust does not help but diurnally variable soil thermal inertia (suggested by Fourier analysis of observed T-g) reduces both defects at both sites. Sand on the steep Namib dune is instead homogeneous, defects here being reduced by taking into account slope effects. Regolith at the 2018 dust storm site appears inhomogeneous, with the SEB terms and T(g )relatively well simulated even in this case of extremely heavy dust load.Peer reviewe

The HIRLAM fast radiation scheme for mesoscale numerical weather prediction models

This paper provides an overview of the HLRADIA shortwave (SW) and longwave (LW) broadband radiation schemes used in the HIRLAM numerical weather prediction (NWP) model and available in the HARMONIE-AROME mesoscale NWP model. The advantage of broadband, over spectral, schemes is that they can be called more frequently within the model, without compromising on computational efficiency. In mesoscale models fast interactions between clouds and radiation and the surface and radiation can be of greater importance than accounting for the spectral details of clear-sky radiation; thus calling the routines more frequently can be of greater benefit than the deterioration due to loss of spectral details. Fast but physically based radiation parametrizations are expected to be valuable for high-resolution ensemble forecasting, because as well as the speed of their execution, they may provide realistic physical perturbations. Results from single-column diagnostic experiments based on CIRC benchmark cases and an evaluation of 10 years of radiation output from the FMI operational archive of HIRLAM forecasts indicate that HLRADIA performs sufficiently well with respect to the clear-sky downwelling SW and longwave LWfluxes at the surface. In general, HLRADIA tends to overestimate surface fluxes, with the exception of LW fluxes under cold and dry conditions. The most obvious overestimation of the surface SW flux was seen in the cloudy cases in the 10-year comparison; this bias may be related to using a cloud inhomogeneity correction, which was too large. According to the CIRC comparisons, the outgoing LW and SW fluxes at the top of atmosphere are mostly overestimated by HLRADIA and the net LW flux is underestimated above clouds. The absorption of SW radiation by the atmosphere seems to be underestimated and LW absorption seems to be overestimated. Despite these issues, the overall results are satisfying and work on the improvement of HLRADIA for the use in HARMONIE-AROME NWP system is ongoing. In a HARMONIE-AROME 3-D forecast experiment we have shown that the frequency of the call for the radiation parametrization and choice of the parametrization scheme makes a difference to the surface radiation fluxes and changes the spatial distribution of the vertically integrated cloud cover and precipitation.Peer reviewe

Humidity observations and column simulations for a warm period at the Mars Phoenix lander site : Constraining the adsorptive properties of regolith

Two recalibrated sets of Phoenix (PHX) near-surface TECP air humidity measurements were compared with results from adsorptive single column model simulations during a warm clear-sky polar midsummer period, PHX sols 50-60. The model's 2 m temperatures were close to the observed values. Relative humidity (RH) is very low during the day but at night RH at 2 m reaches nearly 100% by the Zent et al. (2016) recalibration (Z), and 60-70% by the Fischer et al. (2019) recalibration (F). Model values of RH2m are close to Z and F at night and to F during the day. All three imply low water vapor pressures near the surface at night, 0.03-0.05 Pa, with a rapid increase each morning to 0.3-1 Pa and a decrease in the evening by both F and the model simulation. The model's daily adsorbed and desorbed water is in balance for regolith porosity of 16% (instead of 35% for lower latitudes). The depleted layer of nighttime air moisture extends to only about 200 m above the surface; hence the model's precipitable water content stays around the observed similar to 30 mu m throughout the sol. The model's moisture cycle is not sensitive to tortuosity of the regolith but the in-pore molecular diffusivity should be at least 5 cm(2)/s for fair agreement with the observations. In the adsorption experiments there is no fog and just a hint of ground frost, as observed during this period. Strong night frosts appear if adsorption is made weak or absent in the model.Peer reviewe

A user-orientated column modelling framework for efficient analyses of the Martian atmosphere

As spacecraft missions return ever more data from Mars, additional tools will be required to explore and analyse these datasets efficiently. To streamline research into the atmosphere of Mars, a user-orientated modelling capability is developed that enables automatic initialisation and running of a column model. As a demonstration we utilise the modelling framework to provide additional verification for the University of Helsinki and Finnish Meteorological Institute Mars column model temperature profiles above the height of typical lander meteorological measurements, i.e. above 2 m. We utilise the framework at landing site locations that are well characterised to understand the model's applicability and to identify future opportunities for modifications to the framework. We do this by using the framework to compare the column model to temperature soundings made by the Mars Reconnaissance Orbiter. We find that the column model, without any modification, is able to reproduce the observed lapse rates and average temperatures closely in most cases except for a 20-60 K increase over the northern hemisphere mid-winter. We can reproduce this discrepancy by incorporating an adiabatic heating term into the column model. Fitting of the modified column model to the observations results in estimated maximum downward vertical wind velocities of similar to 10 cm s(-1) at altitudes of 15-20 km over the winter solstice at the VL-1 and VL-2 sites. The approach developed here may possibly provide a way to independently estimate or observe the vertical motion in the Martian atmosphere. However, even though the magnitude of the vertical wind speed appears reasonable, it is not clear at this point how much the atmospheric heating is due to other mechanisms such as advection. We have introduced new application software that can quickly find and display the requested data and can be immediately analysed using the included tools. We have demonstrated the potential of this type of software application with a glimpse into the upper atmosphere of Mars.Peer reviewe

Meteorological predictions for Mars 2020 Perseverance rover landing site at Jezero crater

Correction to: Space Sci Rev (2020) 216:148 https://doi.org/10.1007/s11214-020-00763-xPeer reviewe

The Surface Energy Budget at Gale Crater During the First 2500 Sols of the Mars Science Laboratory Mission

We use in situ environmental measurements by the Mars Science Laboratory (MSL) mission to obtain the surface energy budget (SEB) across Curiosity's traverse during the first 2500 sols of the mission. This includes values of the downwelling shortwave solar radiation, the upwelling solar radiation reflected by the surface, the downwelling longwave radiation from the atmosphere, the upwelling longwave radiation emitted by the surface, the sensible heat flux associated with turbulent motions, and the latent heat flux associated with water phase changes. We then analyze their temporal variation on different timescales and relate this to the mechanisms causing these variations. Through its Rover Environmental Monitoring Station, MSL allows for a more accurate determination of the SEB than its predecessors on Mars. Moreover, the unprecedented duration, cadence, and frequency of MSL environmental observations allow for analyses of the SEB from diurnal to interannual timescales. The results presented in this article can be used to evaluate the consistency with predictions from atmospheric numerical models, to validate aerosol radiative properties under a range of dust conditions, to understand the energy available for solar-powered missions, and to enable comparisons with measurements of the SEB by the Perseverance rover at Jezero crater.Peer reviewe