Vibrational branching ratios and hyperfine structure of 11^{11}BH and its suitability for laser cooling

The simple structure of the BH molecule makes it an excellent candidate for direct laser cooling. We measure the branching ratios for the decay of the ${\rm A}^{1}\Pi (v'=0)$ state to vibrational levels of the ground state, ${\rm X}^{1}\Sigma^{+}$, and find that they are exceedingly favourable for laser cooling. We verify that the branching ratio for the spin-forbidden transition to the intermediate ${\rm a}^{3}\Pi$ state is inconsequentially small. We measure the frequency of the lowest rotational transition of the X state, and the hyperfine structure in the relevant levels of both the X and A states, and determine the nuclear electric quadrupole and magnetic dipole coupling constants. Our results show that, with a relatively simple laser cooling scheme, a Zeeman slower and magneto-optical trap can be used to cool, slow and trap BH molecules.Comment: 7 pages, 5 figures. Updated analysis of A state hyperfine structure and other minor revision

Germinability Factors of Field-Grown Sorghum Seed

Germination of sorghum seed did not appear to be affected by spraying the plants with Maneb or with a chemical defoliant before harvest. Mechanical threshing greatly reduced germination of most but not all lots; this injury is thought to be related to the maturity and/ or moisture content of the seed when threshed, although other varietal differences may be important. At any given time there were large differences in moisture content between seeds of different hybrids, different plants of any one hybrid, and between different parts of the same panicle

Pulsed beams as field probes for precision measurement

We describe a technique for mapping the spatial variation of static electric, static magnetic, and rf magnetic fields using a pulsed atomic or molecular beam. The method is demonstrated using a beam designed to measure the electric dipole moment of the electron. We present maps of the interaction region, showing sensitivity to (i) electric field variation of 1.5 V/cm at 3.3 kV/cm with a spatial resolution of 15 mm; (ii) magnetic field variation of 5 nT with 25 mm resolution; (iii) radio-frequency magnetic field amplitude with 15 mm resolution. This new diagnostic technique is very powerful in the context of high-precision atomic and molecular physics experiments, where pulsed beams have not hitherto found widespread application.Comment: 6 pages, 12 figures. Figures heavily compressed to comply with arxiv's antediluvian file-size polic

A robust floating nanoammeter

A circuit capable of measuring nanoampere currents while floating at voltages up to at least 25kV is described. The circuit relays its output to ground potential via an optical fiber. We particularly emphasize the design and construction techniques which allow robust operation in the presence of high voltage spikes and discharges.Comment: 5 pages, 2 figure

A high quality, efficiently coupled microwave cavity for trapping cold molecules

We characterize a Fabry-Perot microwave cavity designed for trapping atoms and molecules at the antinode of a microwave field. The cavity is fed from a waveguide through a small coupling hole. Focussing on the compact resonant modes of the cavity, we measure how the electric field profile, the cavity quality factor, and the coupling efficiency, depend on the radius of the coupling hole. We measure how the quality factor depends on the temperature of the mirrors in the range from 77 to 293K. The presence of the coupling hole slightly changes the profile of the mode, leading to increased diffraction losses around the edges of the mirrors and a small reduction in quality factor. We find the hole size that maximizes the intra-cavity electric field. We develop an analytical theory of the aperture-coupled cavity that agrees well with our measurements, with small deviations due to enhanced diffraction losses. We find excellent agreement between our measurements and finite-difference time-domain simulations of the cavity.Comment: 16 pages, 8 figure

Measurement of the electron electric dipole moment using YbF molecules

The most sensitive measurements of the electron electric dipole moment d_e have previously been made using heavy atoms. Heavy polar molecules offer a greater sensitivity to d_e because the interaction energy to be measured is typically 10^3 times larger than in a heavy atom. We report the first measurement of this kind, for which we have used the molecule YbF. Together, the large interaction energy and the strong tensor polarizability of the molecule make our experiment essentially free of the systematic errors that currently limit d_e measurements in atoms. Our first result d_e = (- 0.2 \pm 3.2) x 10^-26 e.cm is less sensitive than the best atom measurement, but is limited only by counting statistics and demonstrates the power of the method.Comment: 4 pages, 4 figures. v2. Minor corrections and clarifications made in response to referee comment

Prospects for the measurement of the electron electric dipole moment using YbF

We discuss an experiment underway at Imperial College London to measure the permanent electric dipole moment (EDM) of the electron using a molecular beam of YbF. We describe the measurement method, which uses a combination of laser and radiofrequency resonance techniques to detect the spin precession of the YbF molecule in a strong electric field. We pay particular attention to the analysis scheme and explore some of the possible systematic effects which might mimic the EDM signal. Finally, we describe technical improvements which should increase the sensitivity by more than an order of magnitude over the current experimental limit.Comment: 6 pages, 2 figure

Improved alkaline extraction method for biogenic silica determination in volcanic soils

Here we present the first results obtained with an innovative technique aiming at measuring biogenic and lithogenic amorphous silica contents in soils developed on basaltic parent material. Biogenic silica (BSi) has become important to many research domains like soil science, biogeochemistry, aquatic sciences, palaeoecology, and agricultural sciences. In most soils, BSi is a small but highly reactive Si pool in comparison to lithogenic Si sources. This high reactivity makes it a key component of the soil-plant Si cycle. In the last decade, the continental cycle of Si has been increasingly studied, because of (1) the importance of Si as a nutrient for plants and diatoms (studies include e.g., impact of land-use change, export through harvest, influence on crops resistance to various kinds of stress) and (2) the major role of Si during chemical weathering. Constraining Si reservoirs in soils is, however, not an easy task due to the ubiquity of Si. Many methods have been developed to quantify BSi content in soils (mostly alkaline extraction techniques) and other Si pools in soils (e.g., mobile Si, adsorbed Si, … with the sequential Si extraction by Georgiadis et al. 2013 [1]). BSi extraction methods that are based only on solubility are, however, difficult to apply to environments where large amounts of lithogenic amorphous or poorly crystalline aluminosilicates are present, like e.g. in volcanic soils, as their solubility is close to that of BSi. In order to study the soil/plant Si cycle in such soils, leaching methods, quasi-continuously analysing both the dissolution kinetics and the chemistry of the dissolving phases, provide better control of the dissolving Si sources. Several authors successfully used methods similar to the one applied here on various materials. This is however the first study that applies such method with quasi-continuous monitoring of released elements on the challenging material that is volcanic soils

Permanent-magnet atom chips for the study of long, thin atom clouds

Atom-chip technology can be used to confine atoms tightly using permanently magnetised videotape along with external magnetic fields. The one-dimensional (1D) gas regime can be realised and studied by trapping the atoms in high-aspect-ratio traps in which the radial motion of the system is confined to zero-point oscillation

Doppler-free laser spectroscopy of buffer gas cooled molecular radicals

We demonstrate Doppler-free saturated absorption spectroscopy of cold molecular radicals formed by laser ablation inside a cryogenic buffer gas cell. By lowering the temperature, congested regions of the spectrum can be simplified, and by using different temperatures for different regions of the spectrum a wide range of rotational states can be studied optimally. We use the technique to study the optical spectrum of YbF radicals with a resolution of 30 MHz, measuring the magnetic hyperfine parameters of the electronic ground state. The method is suitable for high resolution spectroscopy of a great variety of molecules at controlled temperature and pressure, and is particularly well-suited to those that are difficult to produce in the gas phase.Comment: 11 pages, 4 figure