Corrosion behavior of commercially pure Mg and ZM21 Mg alloy in Ringer’s solution – Long term evaluation by EIS

Evaluation of the corrosion behavior of commercially pure magnesium (CP-Mg) and ZM21 Mg alloy immersed in Ringer’s solution for 92 h by electrochemical impedance spectroscopy (EIS) is addressed. The formation of a compact layer of well-developed rod-like aragonitic CaCO3 crystals and its subsequent thickening with increase in immersion time offers a higher corrosion protective ability for ZM21 Mg alloy. The formation of a mud-crack pattern and a large number of clusters of needle-like crystals offers a relatively lower corrosion resistance for CP-Mg. The study suggests that ZM21 Mg alloy is a promising candidate material for the development of degradable implants

Dezincification of Brass in Sulfide Polluted Sodium Chloride Medium: Evaluation of the Effectiveness of 2-Mercaptobenzothiazole

The present paper addresses the effectiveness of 2-mercaptobenzothiazole (MBT) in preventing the dezincification of brass in sulfide polluted 3.5% NaCl solution. The dezincification behaviour of brass in 3.5% NaCl solution containing 100-1000 ppm of sulfide ions and 1 x 10-6 to 1 x 10-3 M MBT was studied by potentiodynamic polarization, electrochemical impedance spectroscopy, current-time transient and accelerated leaching studies. The presence of sulfide ions in 3.5% NaCl solution has caused a significant increase in the extent of corrosion attack on brass. The inhibiting effect of MBT is markedly reduced in the presence of sulfide ions in the medium. The easy replacement of Cu-MBT complex by Cu2S film on the surface of brass is responsible for the inability of MBT to prevent corrosion attack in the presence of sulfide ions. The study concludes that the effectiveness of MBT in preventing the dezincification of brass is dependent on the concentration of the sulfide ions in the medium and the effectiveness is nullified at higher concentrations of sulfide ions

Effect of Sugar Promoters on Biomass Yield and Sugar Content of Napier Bajra Hybrids

In India deficiency of green fodder is estimated to the tune of 35.7% and this difference is likely to increase in coming period due to possible decrease in acreage under fodder crops as the cultivated land is being utilized for urbanization and other industrial uses. In tropical countries like India, crop residues from cultivated crops and grasses (mainly monsoon grasses) constitute the basal diet of livestock. But the nutritive value of these grasses is low (protein and digestibility) than the fodder crops and even in green stage is able only to meet the maintenance requirement of animals. A conservative estimate is that around 220 million tones of surplus green herbages is available during flush season of monsoon and can be conserved through ensiling. But due to the low DM (dry matter) and WSC (water soluble carbohydrate) content (2-4%) in such tropical grasses, they results in poor fermentation of freshly cut materials under anaerobic environment of ensiling. A minimum of 7-8% of water-soluble carbohydrate is needed to initiate the fermentation process. Hence, there is a need to improve in the quality of grasses even to conserve them as silage. The research efforts put forth by animal nutritionist to conserve these grasses as silage were not successful mainly due to their low water soluble carbohydrate contents. The use of chemicals to increase immature internodal sucrose levels in sugarcane has been made in some parts of the world. In forages, such efforts may solve the issue of conservation of monsoon grass as hay. Keeping in the view, an attempt has been made to explore the possibility of improving the sugar content of BN Hybrid grass

Rejuvenation of Wild Ber (\u3cem\u3eZizyphus\u3c/em\u3e Species) through Budding at Farmer’s Field

Ber is mainly cultivated for its fresh fruits, which are rich in vitamins C, A and B complex. Due to its nutritional qualities it is called poor man’s apple (Gajbhiya et al., 2003). A large number of wild ber shrubs (Zizyphus mauritiana, Z. rotundifolia and Z. nummularia) were seen growing on the neglected lands, uncultivated lands, roadsides and farm boundaries in Kadesara Kala Village in Lalitpur district of Uttar Pradesh (India). Production potential of this species is very low because of poor upkeep and inferior genetic makeup. But they have extensive root system which can withstand prolonged drought and has capability to regenerate even if the shoot system is damaged completely (Batahr, 1990). They are also responsibly resistant to common insect and pest. Therefore, these species offer an excellent production potential from the degraded lands of Bundelkhand region of India (Sharma and Tiwari, 1994; Tiwari and Sharma, 1993) after in-situ budding with improved cultivars. It also provides sufficient leaf biomass (pala) which can be utilized as fodder in lean period and also suitable for hay and silage for goat as it contains 11-13 percent crude protein (Tewatia and Khirwar, 2002). Pruned twigs/stems of ber also meet, to some extent, the fuel wood requirement in rural areas (Kumar et al., 2004)

Constraints for Grassland Development in Kadesara Kala Village, Lalitpur, Bundelkhand: A Case Study

India is maintaining a livestock population of over 500 million and has a grim situation of forage and feed deficit to the tune of 35.6% green fodder, 10.95% crop residues and 44% concentrate. In term of nutrients, the deficit is expected to the tune of 24.6 and 19.9% respectively by the year 2020. The gap is to be bridged up through development as well as extension of appropriate fodder production technologies suitable for different farming situation strategies. Fifty-eight % of the available fodder comes from grazing land and 42% from stall feeding with crop residues (30%) and leaf fodder (12%). Grasses constitute the majority (88%) of fodder available in Uttar Pradesh (GOUP, 1994). However, the role of grasslands cannot be under judged, as the large animal populations owned by small, marginal and landless farm family strive upon these. The livestock sector achieved an average growth rate of 4.8 per cent during the Eleventh Five Year Plan (Economic Survey, 2012-13) and it contributed 3.6 percent of national GDP during the Eleventh Plan. In the same tune, the contribution from this sector is expected to improve because increasing purchasing power is favoring the proportion of protein from animal source in the human diets. Further, The Indian livestock sector is becoming more competitive participant in the world market. All this largely depends, however, on improvement and sufficiency in the production of feeds and forages. Notwithstanding the above, the grasslands and pastureland in the country are continuously shrinking. The paper addresses important issues limiting the development of new grasslands in semiarid Bundelkhand region of Uttar Pradesh particularly the Lalitpur district

Economics of BN Hybrid Grass Production Bundelkhand Region of India: A Case Study

Napier grass is also called as Elephant Grass due to its tallness and vigorous vegetative growth. The plants tiller freely and a single clump may produce more than 60 tillers under favorable climatic and soil conditions. Unfortunately, the grass coarse-textured, the leaf blade sheaths as well as sharply serrated, leaf margins. Therefore, cross was made between Bajra which is more succulent, leafy, fine-textured, palatable, fast growing and drought resistant and Napier to combine these qualities with its high yielding potential. The outcome Hybrid Napier is a perennial grass which can be retained on field for 2-3 years. Hybrid napier grass are mostly grown under assured water supply but cultivating under varying agroclimatic condition is also possible. Low grass production in dry land area is mainly due to the limited availability of soil moisture and plant nutrients. Agrawal et al., (2001) reported NB hybrid is superior to guinea grass or setaria grass. However the economy of production plays an important role in introduction/ adoption of a crop in an area, village or farm. Many earlier studies have been conducted on economics of BN Hybrid production at research farm, or other government farms. But the information on economics of BN hybrid production at farmer’s field and its integration livestock feeding as well rooted slips are limited. Therefore, the present study was conducted with the object to study the economics of BN hybrid at farmer’s field in Bundelkhand

Nutrient Intake and Utilization in Jalauni Lambs Fed \u3cem\u3e Azolla \u3c/em\u3e Meal Supplemented Diet

Azolla is an important aquatic fungi due to the occurrence of both photosynthesis and nitrogen fixation in the leaves and also because of its profuse growth habbit, it appears as a potential source of protein, minerals and vitamins for livestock feeding. Keeping in view of the increasing cost and heavy deficit of concentrate ingredients in the country, an attempt was made to replace mustard cake protein @ 25% and 50% levels with Azolla (Microphylla) meal protein in the ration of sheep to investigate the effect of supplementation of azolla meal on nutrient intake and utilization in growing Jalauni lambs fed green chaffed MP Chari based rations

Frequency of \u3b2-thalassemia trait and other hemoglobinopathies in northern and western India

Introduction : India is an ethnically diverse country with an approximate population of 1.2 billion. The frequency of beta-thalassemia trait (\u3b2TT) has variously been reported from < 1% to 17% and an average of 3.3%. Most of these studies have been carried out on small population groups and some have been based on hospital-based patients. There is also a variation in the prevalence of hemoglobinopathies in different regions and population groups in the country. A high frequency of Hb D has been reported from the North in the Punjabi population, Hb E in the eastern region of India and Hb S is mainly reported from populations of tribal origin from different parts of the country. Objectives: To study the gene frequency of \u3b2TT and other hemoglobinopathies in three regions East (Kolkata), West (Mumbai) and North (Delhi) in larghe population group (schoolchildren) for a more accurate assessment of gene frequency for planning of control programmes for haemoglobinopathies. Materials and Methods: This study included 5408 children from 11 schools in Delhi, 5682 from 75 schools in Mumbai and 957 schoolchildren from Kolkata who were screened for \u3b2TT and haemoglobinopathies. These included 5684 children from 75 schools in Mumbai and 5408 children from 11 schools in Delhi. Children were 11-18 years of age of both sexes. The final report is, however, only on 11090 schoolchildren from Mumbai and Delhi as data from Kolkata was restricted both in numbers and objectives and could not be included for comparison. Results: The overall gene frequency of \u3b2TT in Mumbai and Delhi was 4.05% being 2.68% and 5.47% in children of the two cities respectively. In Mumbai, the gene frequency was evenly distributed. Majority of the children with \u3b2TT from Mumbai were from Marathi (38.9%) and Gujarati (25%) speaking groups. Gene frequency was> 5% in Bhatias, Khatris, Lohanas and Schedule Castes. In Delhi, a higher incidence was observed in schoolchildren of North and West Delhi (5.8-9.2%). The schoolchildren of North and West Delhi comprised predominantly of Punjabi origin compared to children in the South of the city (2.2%, 2.3%). When analyzed state-wise, the highest incidence was observed in children of Punjabi origin (7.6%) and was> 4% from several other states. Majority of the traits from Mumbai were anemic (95.1% male and 85.6% in female). The prevalence of anemia was lower (62.7% male and 58.4% female) children with \u3b2TT from Delhi. This was a reflection of the higher prevalence of anemia in children without hemoglobinopathy in Mumbai than in Delhi. Nutritional deficiency was probably more severe and rampant in children Mumbai. Gene frequency of Hb D was greater in schoolchildren from Delhi (1.1%) than in Mumbai (0.7%). Hb S trait (0.2%) was observed exclusively in children from Mumbai. A low incidence of Hb E trait (0.04%) was seen in children in Mumbai. A higher incidence is reported from the East. The number of cases studied from the eastern region was small as the data from the East (Kolkata) could not be included in the analysis. Conclusion: This study comprises a larger number of children studied for the gene frequency of \u3b2TT and other hemoglobinopathies from India. Population groups with higher gene frequencies require screening programmes and facilities for antenatal diagnosis as well as increased awareness and educational programmes to control the birth of thalassemic homozygotes. The overall carrier frequency of \u3b2TT was 4.05% and reinforces the differential frequency of \u3b2-thalassemia trait in schoolchildren from Delhi and Mumbai and the higher incidence of hemoglobin D in Punjabis as reported previously. The birth incidence calculated thereof for homozygous thalassemics would be 11,316 per year which are added each year to the existing load of homozygous thalassemics. This is much higher than the previously reported number of births annually. Hence suitable control measures need to be undertaken urgently in India

Potentially toxic elemental contamination in Wainivesi River, Fiji impacted by gold - mining activities using chemometric tools and SOM analysis

Potentially toxic element (PTE) contamination in Wainivesi River, Fiji triggered by gold-mining activities is a major public health concern deserving attention. However, chemometric approaches and pattern recognition of PTEs in surface water and sediment are yet hardly studied in Pacific Island countries like Fijian urban River. In this study, twenty-four sediment and eight water sampling sites from the Wainivesi River, Fiji were explored to evaluate the spatial pattern, eco-environmental pollution, and source apportionment of PTEs. This analysis was done using an integrated approach of self-organizing map (SOM), principle component analysis (PCA), hierarchical cluster analysis (HCA), and indexical approaches. The PTE average concentration is decreasing in the order of Fe > Pb > Zn > Ni > Cr > Cu > Mn > Co > Cd for water and Fe > Zn > Pb > Mn > Cr > Ni > Cu > Co > Cd for sediment, respectively. Outcomes of eco-environmental indices including contamination and enrichment factors, and geo-accumulation index differed spatially indicated that majority of the sediment sites were highly polluted by Zn, Cd, and Ni. Cd and Ni contents can cause both ecological and human health risks. According to PCA, both mixed sources (geogenic and anthropogenic such as mine wastes discharge and farming activities) of PTEs for water and sediment were identified in the study area. The SOM analysis identified three spatial patterns, e.g., Cr–Co–Zn–Mn, Fe–Cd, and Ni–Pb–Cu in water and Zn–Cd–Cu–Mn, Cr–Ni and Fe, Co–Pb in sediment. Spatial distribution of entropy water quality index (EWQI) values depicted that northern and northwestern areas possess “poor” to “extremely poor” quality water. The entropy weights indicated Zn, Cd, and Cu as the major pollutants in deteriorating the water quality. This finding provides a baseline database with eco-environmental and health risk measures for the Wainivesi river contamination