Properties of Graphene: A Theoretical Perspective

In this review, we provide an in-depth description of the physics of monolayer and bilayer graphene from a theorist's perspective. We discuss the physical properties of graphene in an external magnetic field, reflecting the chiral nature of the quasiparticles near the Dirac point with a Landau level at zero energy. We address the unique integer quantum Hall effects, the role of electron correlations, and the recent observation of the fractional quantum Hall effect in the monolayer graphene. The quantum Hall effect in bilayer graphene is fundamentally different from that of a monolayer, reflecting the unique band structure of this system. The theory of transport in the absence of an external magnetic field is discussed in detail, along with the role of disorder studied in various theoretical models. We highlight the differences and similarities between monolayer and bilayer graphene, and focus on thermodynamic properties such as the compressibility, the plasmon spectra, the weak localization correction, quantum Hall effect, and optical properties. Confinement of electrons in graphene is nontrivial due to Klein tunneling. We review various theoretical and experimental studies of quantum confined structures made from graphene. The band structure of graphene nanoribbons and the role of the sublattice symmetry, edge geometry and the size of the nanoribbon on the electronic and magnetic properties are very active areas of research, and a detailed review of these topics is presented. Also, the effects of substrate interactions, adsorbed atoms, lattice defects and doping on the band structure of finite-sized graphene systems are discussed. We also include a brief description of graphane -- gapped material obtained from graphene by attaching hydrogen atoms to each carbon atom in the lattice.Comment: 189 pages. submitted in Advances in Physic

White-box cryptography:don’t forget about grey-box attacks

\u3cp\u3eDespite the fact that all current scientific white-box approaches of standardized cryptographic primitives have been publicly broken, these attacks require knowledge of the internal data representation used by the implementation. In practice, the level of implementation knowledge required is only attainable through significant reverse-engineering efforts. In this paper, we describe new approaches to assess the security of white-box implementations which require neither knowledge about the look-up tables used nor expensive reverse-engineering efforts. We introduce the differential computation analysis (DCA) attack which is the software counterpart of the differential power analysis attack as applied by the cryptographic hardware community. Similarly, the differential fault analysis (DFA) attack is the software counterpart of fault injection attacks on cryptographic hardware. For DCA, we developed plugins to widely available dynamic binary instrumentation (DBI) frameworks to produce software execution traces which contain information about the memory addresses being accessed. For the DFA attack, we developed modified emulators and plugins for DBI frameworks that allow injecting faults at selected moments within the execution of the encryption or decryption process as well as a framework to automate static fault injection. To illustrate the effectiveness, we show how DCA and DFA can extract the secret key from numerous publicly available non-commercial white-box implementations of standardized cryptographic algorithms. These approaches allow one to extract the secret key material from white-box implementations significantly faster and without specific knowledge of the white-box design in an automated or semi-automated manner.\u3c/p\u3

Theory of orthogonal interactions of CO molecules on a one-dimensional substrate

A minimal model based on density-functional theory is proposed and solved to explain the unusual chemisorption properties of carbon-monooxide (CO) molecules on Cu(110)-(2 × 1)-O quasi-one-dimensional (1D) surface reported in Feng. The striking features of CO adsorption include (1) the strong lifting of the host Cu atom by 1 Å, and (2) the highly anisotropic CO-CO interaction leading to self-assembly into a nanograting structure. Our model implies that the 1D nature of the surface band is the key to these two features. We illustrate how formation of a chemical bond through specific orbital interactions between an adsorbate and 1D dispersive states of the substrate can impact the surface geometrical and electronic structure. © 2012 American Physical Society.We thank DOE-BES Division of Chemical Sciences, Geosciences, and Biosciences for support through Grant No. DE-FG02-09ER16056, W. M. Keck foundation, Ministerio de Ciencia e Innovación (Grant No. FIS2010-19609-C02-00) and G.V.-UPV/EHU (Grant No. IT-366-07) for financial support.Peer Reviewe