A multicomponent model of the infrared emission from Comet Halley

A model based on a mixture of coated silicates and amorphous carbon grains produces a good spectral match to the available Halley data and is consistent with the compositional and morphological information derived from interplanetary dust particle studies and Halley flyby data. The dark appearance of comets may be due to carbonaceous coatings on the dominant (by mass) silicates. The lack of a 10 micrometer feature may be due to the presence of large silicate grains. The optical properties of pure materials apparently are not representative of cometary materials. The determination of the optical properties of additional silicates and carbonaceous materials would clearly be of use

The Formation of N- and O-Heterocycles from the Irradiation of Benzene and Naphthalene in H2O/NH3- Containing Ices

Aromatic hydrocarbons are an important class of molecules for both astrochemistry and astrobiology (Fig. 1). Within this class of molecules, polycyclic aromatic hydrocarbons (PAHs) are known to be ubiquitous in many astrophysical environments, and are likely present in interstellar clouds and protostellar disks. In dense clouds, PAHs are expected to condense onto grains as part of mixed molecular ice mantles dominated by small molecules like H2O,CH3OH, NH3, CO, and CO2. These ices are exposed to ionizing radiation in the form of cosmic rays and ambient high-energy X-ray and UV photons

The Formation of N- and O-Heterocycles from the Irradiation of Benzene and Naphthalene in H2O- and NH3-Containing Ices

Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous in many astrophysical environments, and are likely present in interstellar clouds and protostellar disks [1]. In dense molecular clouds,PAHs and other gas-phase species are expected tocondense onto grains to form mixed molecular ice mantles dominated by small molecules like H2O, CH3OH, NH3, CO, and CO2 [2]. These icy mantleslikely undergo energetic processing from ionizing radiation in the form of cosmic rays and high-energy photons

Angular Alignment Testing of Laser Mirror Mounts Under Temperature Cycling

A number of commercial and custom-built laser mirror mounts were tested for angular alignment sensitivity during temperature cycling from room temperature (20 C) to 40 C. A Nd:YAG laser beam was reflected off a mirror that was held by the mount under test and was directed to a position-sensitive detector. Horizontal and vertical movement of the reflected beam was recorded, and the angular movement, as a function of temperature (coefficient of thermal tilt (CTT)) was calculated from these data. In addition, the amount of hysteresis in the movement after cycling from room temperature to 40 C and back was determined. All commercial mounts showed greater angular movement than the simpler National Aeronautics and Space Administration Lidar Atmospheric Sensing Experiment (NASA LASE) custom mirror mounts

Nucleobases and other Prebiotic Species from the Ultraviolet Irradiation of Pyrimidine in Astrophysical Ices

Nucleobases are N-heterocycles that are the informational subunits of DNA and RNA, and are divided into two families: pyrimidine bases (uracil, cytosine, and thymine) and purine bases (adenine and guanine). Nucleobases have been detected in meteorites and their extraterrestrial origin confirmed by isotope measurement. Although no Nheterocycles have ever been observed in the ISM, the positions of the 6.2-m interstellar emission features suggest a population of such molecules is likely to be present. In this work we study the formation of pyrimidine-based molecules, including nucleobases, as well as other species of prebiotic interest, from the ultraviolet (UV) irradiation of pyrimidine in combinations of H2O, NH3, CH3OH, and CH4 ices at low temperature, in order to simulate the astrophysical conditions under which prebiotic species may be formed in the interstellar medium and icy bodies of the Solar System. Experimental: Gas mixtures are prepared in a glass mixing line (background pressure approx. 10(exp -6)-10(exp -5) mbar). Relative proportions between mixture components are determined by their partial pressures. Gas mixtures are then deposited on an aluminum foil attached to a cold finger (15-20 K) and simultaneously irradiated with an H2 lamp emitting UV photons (Lyman and a continuum at approx.160 nm). After irradiation samples are warmed to room temperature, at which time the remaining residues are recovered to be analyzed with liquid and gas chromatographies. Results: These experiments showed that the UV irradiation of pyrimidine mixed in these ices at low temperature leads to the formation of several photoproducts derived from pyrimidine, including the nucleobases uracil and cytosine, as well as their precursors 4(3H)-pyrimidone and 4-aminopyrimidine (Fig. 1). Theoretical quantum calculations on the formation of 4(3H)-pyrimidone and uracil from the irradiation of pyrimidine in pure H2O ices are in agreement with their experimental formation pathways. In those residues, other species of prebiotic interest such as urea and the amino acids glycine and alanine could also be identified. However, no pyrimidine derivatives containing CH3 groups, including the third nucleobase thymine, could be identified, suggesting that the addition of methyl groups to pyrimidine is not an efficient process

Design and Build a Compact Raman Sensor for Identification of Chemical Composition

A compact remote Raman sensor system was developed at NASA Langley Research Center. This sensor is an improvement over the previously reported system, which consisted of a 532 nm pulsed laser, a 4-inch telescope, a spectrograph, and an intensified charge-coupled devices (CCD) camera. One of the attractive features of the previous system was its portability, thereby making it suitable for applications such as planetary surface explorations, homeland security and defense applications where a compact portable instrument is important. The new system was made more compact by replacing bulky components with smaller and lighter components. The new compact system uses a smaller spectrograph measuring 9 x 4 x 4 in. and a smaller intensified CCD camera measuring 5 in. long and 2 in. in diameter. The previous system was used to obtain the Raman spectra of several materials that are important to defense and security applications. Furthermore, the new compact Raman sensor system is used to obtain the Raman spectra of a diverse set of materials to demonstrate the sensor system's potential use in the identification of unknown materials

The Stardust – a successful encounter with the remarkable comet Wild 2

On January 2, 2004 the Stardust spacecraft completed a close flyby of comet Wild2 (P81). Flying at a relative speed of 6.1 km/s within 237km of the 5 km nucleus, the spacecraft took 72 close-in images, measured the flux of impacting particles and did TOF mass spectrometry

Identifying Organic Molecules in Space: The AstroBiology Explorer (ABE) Mission Concept

The AstroBiology Explorer (ABE) mission concept consists of a dedicated space observatory having a 60 cm class primary mirror cooled to T 2000 of about 1500 objects including galaxies, stars, planetary nebulae, young stellar objects, and solar system objects. Keywords: Astrobiology, infrared, Explorers, interstellar organics, telescope, spectrometer, space, infrared detector

Carbonates Found in Stardust Aerogel Tracks

Preliminary examination of particles collected from Comet Wild 2 suggest that this comet is chondritic and formed under multiple processes. The lack of any hydrated minerals strongly suggests that most, if not all of these processes were anhydrous [1,2,3]. However, carbonates were found in particles extracted from 4 different tracks in the aerogel. It is our belief that these carbonates have a terrestrial origin and are a contaminant in these samples