Electron energy analyzer

Electrostatic deflection analyzer with three spherically concentric grids allows production of electrons within a small volume at the center of the inner sphere. By applying a retarding potential between the middle and inner spheres, the energies of the electrons can be measured

Absorption cross sections of minor constituents in planetary atmospheres from 1050 to 2100 angstrom

Absorption cross sections of minor constituent gases in planetary atmospheres from 1050 to 2100

Studies of photoabsorption by atomic hydrogen, oxygen, and nitrogen

Quantitative measurement of atomic photoionization cross sections of atomic hydrogen, oxygen, and nitroge

On the ionization potential of molecular oxygen

The ionization potential of O2 was measured by the technique of high resolution photoelectron spectroscopy taking into account the influence of rotational structure on the shape of the vibrational bands. A value of 12.071 + or - .001 eV (1027.1 + or - 0.1 A) was found for the ionization potential. A lowering of the ionization potential caused by a branch-head when delta N = -2 gave an appearance potential for ionization of 12.068 + or - .001 eV (1027.4 + or - 0.1 A)

Vibrational intensity distributions for continuum photoionization of oxygen

Results from measurements of vibrational intensity distributions for continuum photoionization of O2 are reported. Measurements were made using the 584 and 304 A He lines. The photoionization cross section of O2 shows a substantial dip in magnitude over a 20 A band centered about 590 A; thus the possibility exists that a 584 A photoelectron spectrum of O2 includes an autoionized contribution and the vibrational intensity distributions may not correspond to those of continuum ionization. Oxygen photoionization cross section shows no structure around 304 A and purley continuum ionization is expected

Dissociative and double photoionization of CO2 from threshold to 90 A

The molecular photoionization, dissociative photoionization and double photoionization cross sections for CO2 were measured from their onsets down to 90 A by using various combinations of mass spectrometers (a coincidence time-of-flight mass spectrometer and a magnetic mass spectrometer) and light sources (synchrotron radiation, and glow and spark discharge). It is concluded that the one broad peak and the three shoulders in the total adsorption cross section curve between 640 and 90 A are caused completely by dissociative ionization processes. Several peaks observed in the cross section curve for the total fragmentation CO(+)3, O(+) and C(+) are compared with those in the photoelectron spectrum reported for CO2

Collecting efficiency of a cylindrical mirror electron energy analyzer with preretarding lens

The electron collecting efficiency of a cylindrical mirror energy analyzer incorporating retardation of the electrons prior to analysis has been determined over the range 0 to 30 eV by two methods. The first method requires the use of a vacuum ultraviolet monochromator to produce monoenergetic electrons of different energies; the second method involves measuring the energy-brightness relationship of the retarding optics and should be applicable to any deflection analyzer with pre-retarding optics. The results of the two methods are compared and the limitations of the latter method are discussed

Vibrational intensity distributions in the photoelectron spectrum of hydrogen

The intensity distribution over the H2(+) vibrational levels up to a quantum number of 15 was measured for H2 photoelectron spectra at a photon wavelength of 584 A. The data show reasonable agreement with recent calculations only in the quantum number of 0 through 8. The higher levels are populated significantly lower than predicted by theory

Photoionization branching ratios and vibrational intensity distribution for N2, CO; and CO2 between 53 and 75 nm

The probability of radiation producing ions in specific electronic and vibrational levels was documented. For example, when a narrow band-pass of solar ionizing photons is incident on an atmospheric species it is now possible to describe, accurately, how the radiant energy is shared among the various electronic states of the ions produced. The molecules studied were N2, CO, and CO2. These molecules were photoionized by radiation between 53 and 75 nm. The effects of autoionization are discussed and continuum vibrational intensities are tabulated and compared with theoretical Franck-Condon factors where available. The branching ratios and partial cross sections for ionization into various electronic states are tabulated

Absolute photoionization cross sections of atomic oxygen

The absolute values of photoionization cross sections of atomic oxygen were measured from the ionization threshold to 120 A. An auto-ionizing resonance belonging to the 2S2P4(4P)3P(3Do, 3So) transition was observed at 479.43 A and another line at 389.97 A. The experimental data is in excellent agreement with rigorous close-coupling calculations that include electron correlations in both the initial and final states