Fabrication of Chitin Nanofiber-Reinforced PLA Nanocomposites by an Environmentally Friendly Process

Polylactic acid (PLA) reinforced with chitin nanofibers was produced from a mixture of a colloidal suspension of PLA particles with chitin nanofiber suspension. The dispersion medium was solely water, which was removed by filtration and drying. Nanocomposites were obtained by compression molding of the filtrates. Static tensile test and dynamic mechanical analysis were performed to evaluate the reinforcement as a function of nanofiber content. Chitin nanofibers delivered reinforcement similar to cellulose nanofibers, being especially effective at up to 70 wt% fiber load. The ultimate tensile modulus and strength reached 7.7 GPa and 110 MPa, respectively, at a nanofiber content of 70 wt%

Compression induced shear damage in brittle solids by scattered microcracking

Failure observation and numerical analysis were conducted to understand how shear damage develops in brittle solids under biaxial compression. A biaxial compression often induces shear damaged in brittle solids, which is preceded by a formation of huge number of array cracks. Cracks in the array appeared gradually as applied compression increased. They were almost similar in shape; gently curved but were possible to approximate a troop of straight cracks almost parallel to each other without loss of essential characteristics. Under a uniaxial compression, a brittle material tends to fail exhibiting a crack growth almost parallel to the loading axis. In this situation, the crack propagates rather in a stable fashion since the stress intensity factor at crack tip generally decreases with crack extension. Under a biaxial compression, however, such a stable crack growth is strongly inhibited. Consequently, an array of microcracks often appears as a presage of the macroscopic shear failure. A mechanism of the appearance of damaged zone with increase of applied compression was discussed using a scattered cracking model. It was found that each crack composing the damaged zone has a possibility to open due to crack-to-crack interaction and a localized tensile stress appeared both in the interior and in the exterior of the damaged zone. The localized tension appeared in the interior of the damaged zone may increase a crack density, while that appeared in the exterior of the damaged zone would bring an enlargement of the damaged zone

Properties and roles of bacterial symbionts of polyvinyl alcohol-utilizing mixed cultures.

From several polyvinyl alcohol (PVA)-utilizing mixed cultures, two component bacterial strains essential for PVA utilization were isolated, and their properties and roles in PVA utilization were studied. Each pair of essential component strains consisted of a type I strain, which produced a PVA-degrading enzyme and constituted the predominant population of the mixed culture in PVA, and a type II strain, which produced a certain growth stimulant for the former strain. All of the type I strains were taxonomically identical and assigned as Pseudomonas sp. In contrast, type II strains were taxonomically different from each other, belonging to Pseudomonas spp. and Alcaligenes sp. PVA utilization occurred in each mixed culture of a type I strain with Pseudomonas putida VM15A as a substitute for the type II strain of the original pair and also in each mixed culture of a type II strain with Pseudomonas sp. VM15C. The growth rates of these substituted, mixed cultures differed from each other