Multimodal Microscale Imaging of Textured Perovskite-Silicon Tandem Solar Cells.

Halide perovskite/crystalline silicon (c-Si) tandem solar cells promise power conversion efficiencies beyond the limits of single-junction cells. However, the local light-matter interactions of the perovskite material embedded in this pyramidal multijunction configuration, and the effect on device performance, are not well understood. Here, we characterize the microscale optoelectronic properties of the perovskite semiconductor deposited on different c-Si texturing schemes. We find a strong spatial and spectral dependence of the photoluminescence (PL) on the geometrical surface constructs, which dominates the underlying grain-to-grain PL variation found in halide perovskite films. The PL response is dependent upon the texturing design, with larger pyramids inducing distinct PL spectra for valleys and pyramids, an effect which is mitigated with small pyramids. Further, optimized quasi-Fermi level splittings and PL quantum efficiencies occur when the c-Si large pyramids have had a secondary smoothing etch. Our results suggest that a holistic optimization of the texturing is required to maximize light in- and out-coupling of both absorber layers and there is a fine balance between the optimal geometrical configuration and optoelectronic performance that will guide future device designs

Transparent Electrodes in Silicon Heterojunction Solar Cells: Influence on Contact Passivation

Charge carrier collection in silicon heterojunction solar cells occurs via intrinsic/doped hydrogenated amorphous silicon layer stacks deposited on the crystalline silicon wafer surfaces. Usually, both the electron and hole collecting stacks are externally capped by an n-type transparent conductive oxide, which is primarily needed for carrier extraction. Earlier, it has been demonstrated that the mere presence of such oxides can affect the carrier recombination in the crystalline silicon absorber. Here, we present a detailed investigation of the impact of this phenomenon on both the electron and hole collecting sides, including its consequences for the operating voltages of silicon heterojunction solar cells. Based on our findings, we define guiding principles for improved passivating contact design for high-efficiency silicon solar cells

Efficient Near-Infrared-Transparent Perovskite Solar Cells Enabling Direct Comparison of 4-Terminal and Monolithic Perovskite/Silicon Tandem Cells

Combining market-proven silicon solar cell technology with an efficient wide band gap top cell into a tandem device is an attractive approach to reduce the cost of photovoltaic systems. For this, perovskite solar cells are promising high-efficiency top cell candidates, but their typical device size (<0.2 cm2), is still far from standard industrial sizes. We present a1cm2 near-infrared transparent perovskite solar cell with 14.5% steady- state efficiency, as compared to 16.4% on 0.25 cm2. By mechanically stacking these cells with silicon heterojunction cells, we experimentally demonstrate a 4-terminal tandem measurement with a steady-state efficiency of 25.2%, with a 0.25 cm2 top cell. The developed top cell processing methods enable the fabrication of a 20.5% efficient and 1.43 cm2 large monolithic perovskite/silicon heterojunction tandem solar cell, featuring a rear-side textured bottom cell to increase its near-infrared spectral response. Finally, we compare both tandem configurations to identify efficiency-limiting factors and discuss the potential for further performance improvement

Fully textured monolithic perovskite/silicon tandem solar cells with 25.2% power conversion efficiency

Tandem devices combining perovskite and silicon solar cells are promising candidates to achieve power conversion efficiencies above 30% at reasonable costs. State-of-the-art monolithic two-terminal perovskite/silicon tandem devices have so far featured silicon bottom cells that are polished on their front side to be compatible with the perovskite fabrication process. This concession leads to higher potential production costs, higher reflection losses and non-ideal light trapping. To tackle this issue, we developed a top cell deposition process that achieves the conformal growth of multiple compounds with controlled optoelectronic properties directly on the micrometre-sized pyramids of textured monocrystalline silicon. Tandem devices featuring a silicon heterojunction cell and a nanocrystalline silicon recombination junction demonstrate a certified steady-state efficiency of 25.2%. Our optical design yields a current density of 19.5 mA cm−2 thanks to the silicon pyramidal texture and suggests a path for the realization of 30% monolithic

Development of Highly Efficient Perovskite-on-Silicon Tandem Solar Cells

Crystalline Silicon (c-Si) solar cells are dominating the photovoltaic (PV) market. Owing to their large manufacturing capacity, reliability and efficiency, c-Si solar cells are now cost-competitive with other non-renewable electricity sources in many places. The price of c-Si modules has been decreasing drastically for the past decades. They now account for less than half of the cost of a PV system. Other costs come from the balance-of-system and these are rather inflexible. And so increasing efficiency of solar modules is the most efficient approach to lower the cost of PV electricity. One issue is that c-Si cells are approaching their efficiency limit. One strategy to increase efficiency beyond this limit relies on adding another solar cell on c-Si to form a tandem solar cell as thermalisation losses are reduced. Metal lead halide perovskite solar cells are promising top cell candidates for c-Si based on their high optoelectronic properties, band gap tunability, high efficiencies, ease of manufacturing and low material costs. By combining both technologies, efficiencies >30% are realistic, well above best-in-class c-Si cells. This thesis aims to produce high efficiency perovskite solar cells for 2-terminal monolithic tandems on c-Si. First, we develop a perovskite fabrication method, which employs thermal evaporation to produce a lead halide template and then organohalide spin-coating. By varying composition at each step, the perovskite band gap can be tuned in the range 1.6-1.8 eV, ideal values for 2-terminal tandems. The use of the template makes the deposition compatible with various substrate textures. Then, we develop a recombination junction that features nanocrystalline hydrogenated silicon layers (nc-Si:H). When used with a font-side polished c-Si bottom cell, it shows a superior optical performance compared to standard transparent conductive oxides thanks to a better matching of refractive indices. Owing to its low conductivity, the top cell leakage current is reduced, enabling to scale-up the cell area. Then, perovskite/c-Si tandems featuring a double-side textured c-Si wafer are demonstrated, achieving a certified efficiency of 25.2%. This efficiency, the highest at the time of publication, is enabled by low reflection losses and efficient light trapping thanks to the c-Si pyramids present on both sides. More importantly, this double-side texture yields an optically close-to-optimum system that is simpler and more efficient compared to alternatives. Furthermore, this top cell process flow does not require any modification to existing c-Si manufacturing production lines as these use front-side textured c-Si. In the second part, we replace the spin-coating of organohalides by a vapour transport deposition (VTD) using a home-made vapour transport deposition setup that offers large processing flexibility. Using a thermally evaporated lead iodide template and methylammonium iodide vapours, perovskite solar cells with an efficiency > 12% are made. Thanks to the presence of a showerhead, a homogeneous perovskite growth is obtained on 6 inch textured c-Si substrates, the industry standard. The VTD of formaminidium iodide (FAI) is more challenging. A trimerisation of FAI forms sym-triazine, which does not react with the template to form the perovskite. Still, in the presence of ammonium cations, sym-triazine can be cleaved to form formamidine, thus offering an alternative pathway to deposit perovskite layers

Vapor deposition of metal halide perovskite thin films: Process control strategies to shape layer properties

Vapor-based processes are particularly promising to deposit the perovskite thin film absorber of solar cells. These deposition methods are up-scalable, involve a controlled solvent-free environment, have the ability to conformally coat rough substrates, involve soft, low-energy deposition conditions, are compatible with shadow masks for patterning, and are already widely deployed at the industrial level. Still, solar cells featuring layers processed with these methods have not yet reached the same performance as their solution-processed counterparts, in part, due the complexity of controlling the sublimation of the organic precursors. This Research Update will discuss the different vapor-based deposition processes that have been reported to deposit perovskite thin films and will discuss reaction chamber designs that provide an enhanced control over the deposition process. The second part of this Research Update will then link experimental observations regarding layer properties depending on process conditions to theoretical concepts describing the sublimation and condensation of precursors and the growth of the perovskite thin film

Ammonia-assisted vapour transport deposition of formamidinium salts for perovskite thin films

Formamidinium (FA) cations commonly used in perovskite semiconductors tend to form sym-triazine when sublimed in vacuum, a process that hampers the deposition process. Here we find that ammonia, when used as a carrier gas for formamidinium halides transport, cleaves the sym-triazine ring back to formamidinium, hence enhancing the deposition efficiency

Light Management: A Key Concept in High-Efficiency Perovskite/Silicon Tandem Photovoltaics

The remarkable recent progress in perovskite photovoltaics affords a novel opportunity to advance the power conversion efficiency of market-dominating crystalline silicon (c-Si) solar cells. A severe limiting factor in the development of perovskite/c-Si tandems to date has been their inferior light-harvesting ability compared to single-junction c-Si solar cells, but recent innovations have made impressive headway on this front. Here, we provide a quantitative perspective on future steps to advance perovskite/c-Si tandem photovoltaics from a light-management point of view, addressing key challenges and available strategies relevant to both the 2-terminal and 4-terminal perovskite/c-Si tandem architectures. In particular, we discuss the challenge of achieving low optical reflection in 2-terminal cells, optical shortcomings in state-of-the-art devices, the impact of transparent electrode performance, and a variety of factors which influence the optimal bandgap for perovskite top-cells. Focused attention in each of these areas will be required to make the most of the tandem opportunity.Australian Renewable Energy Agency; Australian Research Council; Bundesministerium für Bildung und Forschung (PRINTPERO); the Initiating and Networking funding of the Helmholtz Association; the European Union’s Horizon2020 program (ACTPHAST); Karlsruhe School of Optics & Photonics (KSOP); Swiss National Science Foundation via NRP70 Energy Turnaround PV2050 and Swiss National Science Foundation Bridge (176552) projects

Vapor Transport Deposition of Methylammonium Iodide for Perovskite Solar Cells

Vapor-based processes are promising options to deposit metal halide perovskite solar cells in an industrial environment due to their ability to deposit uniform layers over large areas in a controlled environment without resorting to the use of (possibly toxic) solvents. In addition, they yield conformal layers on rough substrates, an important aspect in view of producing perovskite/ crystalline silicon tandem solar cells featuring a textured silicon wafer for light management. While the inorganic precursors of the perovskite are well suited for thermal evaporation in high vacuum, the sublimation of the organic ones is more complex to control due to their high vapor pressure. To tackle this issue, we developed a vapor transport deposition chamber for organohalide deposition that physically dissociates the organic vapor evaporation zone from the deposition chamber. Once evaporated, organic vapors, here methylammonium iodide (MAI), are transported to the deposition chamber by a carrier gas through a showerhead, ensuring a spatially homogeneous conversion of PbI2 templates to the perovskite phase. The method enables the production of homogeneous perovskite layers on a textured 6 in. wafer. Furthermore, small-scale methylammonium lead iodide solar cells are also processed to validate the quality of the absorbers produced by this hybrid thermal evaporation/vapor transport deposition process