3 research outputs found

    Bilingual Researcher Profiles: Modeling Dutch Researchers in both English and Dutch Using the VIVO Ontology

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    <p>In this poster we describe the process of mapping researcher information from the Dutch National Academic Research and Collaborations Information System (NARCIS) to the VIVO ontology. Our goal is to use the VIVO ontology to accurately represent these researchers and their organizations, while remaining true to the native language and structure of the Dutch university. To achieve this, we first created an extension ontology to account for differences in the Dutch naming structure and differences in university position description and alignment. Secondly, through the use of language attribute tags, we recorded data in both English and Dutch to achieve better access by both the native Dutch population and the larger English based research community. Finally, we leveraged the SKOS ontology to take advantage of a classification structure, already created by NARCIS, to describe researcher expertise uniformly across the system. <em>Presented at ASIST 2013, Nov 1-6, Montreal, Canada</em></p

    Determination of Mobile Ion Densities in Halide Perovskites via Low-Frequency Capacitance and Charge Extraction Techniques

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    Mobile ions in perovskite photovoltaic devices can hinder performance and cause degradation by impeding charge extraction and screening the internal field. Accurately quantifying mobile ion densities remains a challenge and is a highly debated topic. We assess the suitability of several experimental methodologies for determining mobile ion densities by using drift-diffusion simulations. We found that charge extraction by linearly increasing voltage (CELIV) underestimates ion density, but bias-assisted charge extraction (BACE) can accurately reproduce ionic lower than the electrode charge. A modified Mott–Schottky (MS) analysis at low frequencies can provide ion density values for high excess ionic densities, typical for perovskites. The most significant contribution to capacitance originates from the ionic depletion layer rather than the accumulation layer. Using low-frequency MS analysis, we also demonstrate light-induced generation of mobile ions. These methods enable accurate tracking of ionic densities during device aging and a deeper understanding of ionic losses

    Mass Spectrometry-Based Visualization of Molecules Associated with Human Habitats

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    The cars we drive, the homes we live in, the restaurants we visit, and the laboratories and offices we work in are all a part of the modern human habitat. Remarkably, little is known about the diversity of chemicals present in these environments and to what degree molecules from our bodies influence the built environment that surrounds us and vice versa. We therefore set out to visualize the chemical diversity of five built human habitats together with their occupants, to provide a snapshot of the various molecules to which humans are exposed on a daily basis. The molecular inventory was obtained through untargeted liquid chromatography–tandem mass spectrometry (LC–MS/MS) analysis of samples from each human habitat and from the people that occupy those habitats. Mapping MS-derived data onto 3D models of the environments showed that frequently touched surfaces, such as handles (e.g., door, bicycle), resemble the molecular fingerprint of the human skin more closely than other surfaces that are less frequently in direct contact with humans (e.g., wall, bicycle frame). Approximately 50% of the MS/MS spectra detected were shared between people and the environment. Personal care products, plasticizers, cleaning supplies, food, food additives, and even medications that were found to be a part of the human habitat. The annotations indicate that significant transfer of chemicals takes place between us and our built environment. The workflows applied here will lay the foundation for future studies of molecular distributions in medical, forensic, architectural, space exploration, and environmental applications
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