134 research outputs found
Verification of Interactions between Silica and Epoxidized Squalene as a Model for Epoxidized Natural Rubber
Unmodified squalene (Sq) and epoxidised squalene (ESq), as models for natural rubber and epoxidised natural rubber, were mixed with silica in a reactor at 140 – 145ºC, which corresponds to the optimal mixing dump temperature of silica-filled natural rubber or epoxidised natural rubber compounds. The mixtures were prepared with and without bis-(triethoxysilylpropyl) tetrasulphide (TESPT) silane coupling agent. The bound silica in the mixtures was extracted and checked for its composition by using Fourier-transform infrared (FTIR) spectroscopy. The results indicate that Sq and ESq with the help of TESPT can chemically link to the silica surface, as the FTIR spectra of purified bound silicas show absorption peaks of hydrocarbon structures. The epoxidised squalene also produces chemical interaction with silica in the absence of TESPT, but to a lesser extent compared to the one with TESPT, as indicated by the absorption intensity. On the other hand, the silica in the Sq mixture without TESPT shows no trace of hydrocarbon, indicating that there is no noticeable chemical interaction involve
Petroleum-based Safe Process Oils in NR and NR/SBR Blends: Effects of Oil Types on Properties of Carbon Black Filled Compounds
Rezepturoptimierung für kieselsäureverstärkte Naturkautschukmischungen
The rubber formulation plays a significant role in the properties of NR compounds filled with silica. In this work, the influences of various silicas, silane coupling agents and diphenylguanidine (DPG) on the properties of compounds and vulcanizates, i. e. cure characteristics, Mooney viscosity, flocculation kinetics, bound rubber content, Payne effect, tan δ at 60 °C, tensile and tear properties are investigated. The results demonstrate that compound viscosity and curing behavior, as well as vulcanizate properties of the silica-filled NR are much improved by incorporating silane coupling agents. Bis-triethoxysilylpropyltetrasulfide (TESPT) clearly gives better overall properties than the disulfide-based silane (TESPD), except for scorch safety. DPG acts as a synergist to sulfenamide primary accelerators, as well as activator for the silanization reaction. Highly dispersible (HD) silicas can significantly enhance the degree of dispersion, and so lead to higher filler-rubber interaction. As a consequence, the HD silicas provide better dynamic and mechanical properties for filled NR vulcanizates compared to conventional (CV) counterparts. The optimal quantities of both, silane coupling agent and DPG, required in the formulation are correlated to the cetyl trimethylammonium bromide (CTAB) specific surface area of the silicas. Furthermore, the results reveal that the silica structure as characterized by the dibutylphthalate (DBP) adsorption also strongly influences the reinforcing efficienc
Bio-based Rubber Process Oils for Low Rolling Resistance Silica-Reinforced Natural Rubber Tire Tread Compounds
Multifunctional Peroxidegas Alternative Crosslink Agents for Dynamically Vulcanized Expoxidized Natural Rubber/Polypropylene Blends
Commonly used dicumyl peroxide (DCP) in combination with coagent, triallyl cyanurate (TAC), as a crosslinking agent is well acceptable for dynamically vulcanized rubber phase of thermoplastic vulcanizates (TPVs). However, it generally produces volatile decomposition products, which cause a typical unpleasant smell and a blooming phenomenon. In this work, influence of two types of multifunctional peroxides: 2,4-diallyloxy-6-tert-butylperoxy-1,3,5-triazine (DTBT) and 1-(2-tert-butylperoxyisopropyl)-3-isopropenyl benzene (TBIB), on properties of TPVs based on epoxidized natural rubber (ENR)/polypropylene (PP) blends were investigated. The conventional peroxide/coagent combinations, i.e., DCP/TAC and tert-butyl cumyl peroxide (TBCP)/-methyl styrene (-MeS) were also used to prepare the TPVs for a comparison purpose. The TPVs with multifunctional peroxide, DTBT, provided good mechanical properties and phase morphology of small dispersed vulcanized rubber domains in the PP matrix which were comparable with the DCP/TAC cured TPVs. However, the TPVs with TBIB/-MeS and TBCP/-MeS showed comparatively low values of the tensile properties as well as rather large phase morphology. The results were interpreted by three main factors: the kinetic aspects of the various peroxides, solubility parameters of respective peroxide/coagent combinations in the ENR and PP phases, and the tendency to form unpleasantly smelling byproducts
Enhancing Filler-Rubber Compatability of Silica-Reinforced Tire Tread Compounds by using Chemicallt Modified Natural Rubbers
- …