Potential Use of Petroleum-based Sulfur in Rubber Industry

AbstractPotential use of petroleum-based sulfur generally classified as a by-product from refinery process is investigated as vulcanizing agent in rubber, and compared with commercial rhombic sulfur. Styrene-butadiene rubber (SBR) and nitrile rubber (NBR) are used as rubber matrices. Results obtained show that, between 2 types of sulfurs, the SBR system reveals similarity in cure behaviors whereas the NBR system demonstrates faster cure behavior when vulcanized by petroleum-based sulfur. However, rheological properties, mechanical properties, and dynamic mechanical properties of both rubbers show comparable results regardless of sulfur type. The results suggest the strong potential utilization of petroleum-based sulfur as vulcanizing agent as an alternative to the commercial rhombic sulfur usually used in rubber vulcanization

Influence of Carbon Black/Silica Hybrid Ratio on Properties of Passenger Car Tire Sidewall

Influence of carbon black (CB)/precipitated silica (SiO2) hybrid ratio on properties of a passenger car tire (PCT) sidewall based on natural rubber (NR) and butadiene rubber (BR) blend was investigated. Rubbers filled with various hybrid filler ratios at a constant loading of 50 phr were prepared and tested. The filler reinforcement efficiency in association with crucial properties of the tire sidewall were of interest. Results show the enhanced rubber–filler interaction with increasing SiO2 fraction leading to the improvement in many vulcanizate properties including hardness, tensile strength, tear strength and fatigue resistance, at the expense of cure efficiency and hysteretic behaviors (i.e., reduced heat build-up resistance and increased dynamic set). The results also suggest the improvement in tire sidewall performance of the NR/BR vulcanizates reinforced with CB/SiO2 hybrid filler, compared to that of the CB-filled vulcanizate

Effects of Blend Ratio and SBR Type on Properties of Carbon Black-Filled and Silica-Filled SBR/BR Tire Tread Compounds

This work aimed at investigating the effects of blend ratio between styrene butadiene rubber (SBR) and butadiene rubber (BR) and SBR type (E-SBR and S-SBR) on properties of SBR/BR tire tread compounds. Influences of these parameters on properties of the tread compounds reinforced by 80 parts per hundred rubber (phr) of carbon black (CB) and silica were also compared. Results reveal that hardness, strengths, and wet grip efficiency were impaired whereas rolling resistance was improved with increasing BR proportion. Surprisingly, the presence of BR imparted poorer abrasion resistance in most systems, except for the CB-filled E-SBR system in which an enhanced abrasion resistance was observed. Obviously, S-SBR gave superior properties (tire performance) compared to E-SBR, particularly obvious in the silica-filled system. Compared with CB, silica gave comparable strengths, better wet grip efficiency, and lower rolling resistance. Carbon black, however, offered greater abrasion resistance than silica

Measurement and modelling of the influence of hystersis on the internal temperature rise of rubber components

SIGLEAvailable from British Library Document Supply Centre-DSC:DXN021161 / BLDSC - British Library Document Supply CentreGBUnited Kingdo

Measurement and modelling of the influence of hysteresis on the internal temperature rise of rubber components

Finite element analysis (FEA) is a numerical analysis method which is used widely to obtain approximate solutions in many fields of engineering. With sophisticated computer hardware and software. FEA has recently become an effective tool in the design of rubber components. [Continues.