Dicarba-closo-dodecarborane-containing half-sandwich complexes of ruthenium, osmium, rhodium and iridium : biological relevance and synthetic strategies

This review describes how the incorporation of dicarba-closo-dodecarboranes into half-sandwich complexes of ruthenium, osmium, rhodium and iridium might lead to the development of a new class of compounds with applications in medicine. Such a combination not only has unexplored potential in traditional areas such as Boron Neutron Capture Therapy agents, but also as pharmacophores for the targeting of biologically important proteins and the development of targeted drugs. The synthetic pathways used for the syntheses of dicarba-closo-dodecarboranes-containing half-sandwich complexes of ruthenium, osmium, rhodium and iridium are also reviewed. Complexes with a wide variety of geometries and characteristics can be prepared. Examples of addition reactions on the metal centre, B–H activation, transmetalation reactions and/or direct formation of metal–metal bonds are discussed (103 references)

Probing the cool ISM in galaxies via 21cm HI absorption

Recent targeted studies of associated HI absorption in radio galaxies are starting to map out the location, and potential cosmological evolution, of the cold gas in the host galaxies of Active Galactic Nuclei (AGN). The observed 21 cm absorption profiles often show two distinct spectral-line components: narrow, deep lines arising from cold gas in the extended disc of the galaxy, and broad, shallow lines from cold gas close to the AGN (e.g. Morganti et al. 2011). Here, we present results from a targeted search for associated HI absorption in the youngest and most recently-triggered radio AGN in the local universe (Allison et al. 2012b). So far, by using the recently commissioned Australia Telescope Compact Array Broadband Backend (CABB; Wilson et al. 2011), we have detected two new absorbers and one previously-known system. While two of these show both a broad, shallow component and a narrow, deep component (see Fig. 1), one of the new detections has only a single broad, shallow component. Interestingly, the host galaxies of the first two detections are classified as gas-rich spirals, while the latter is an early-type galaxy. These detections were obtained using a spectral-line finding method, based on Bayesian inference, developed for future large-scale absorption surveys (Allison et al. 2012a).Comment: 1 page, 1 figure, published in Proceedings of IAU Symposium No. 29

HI in four star-forming low-luminosity E/S0 and S0 galaxies

We present HI data cubes of four low-luminosity early-type galaxies which are currently forming stars. These galaxies have absolute magnitudes in the range M_B=-17.9 to -19.9 (H_o=50 km/s/Mpc). Their HI masses range between a few times 10^8 and a few times 10^9 M_sun and the corresponding values for M_HI/L_B are between 0.07 and 0.42, so these systems are HI rich for their morphological type. In all four galaxies, the HI is strongly centrally concentrated with high central HI surface densities, in contrast to what is typically observed in more luminous early-type galaxies. In two galaxies (NGC 802 and ESO 118-G34), the kinematics of the HI suggests that the gas is in a strongly warped disk, which we take as evidence for recent accretion of HI. In the other two galaxies (NGC 2328 and ESO 027-G21) the HI must have been part of the systems for a considerable time. The HI properties of low-luminosity early-type galaxies appear to be systematically different from those of many more luminous early-type galaxies, and we suggest that these differences are due to a different evolution of the two classes. The star formation history of these galaxies remains unclear. Their UBV colours and Halpha emission-line strengths are consistent with having formed stars at a slowly-declining rate for most of the past 10^10 years. However, the current data do not rule out a small burst of recent star formation overlaid on an older stellar population.Comment: To appear in AJ, LateX, figures in gif format, paper also available at http://www.nfra.nl/~morganti/LowLu

Application of a Bayesian Method to Absorption Spectral-Line Finding in Simulated ASKAP Data

The large spectral bandwidth and wide field of view of the Australian SKA Pathfinder radio telescope will open up a completely new parameter space for large extragalactic HI surveys. Here we focus on identifying and parametrising HI absorption lines which occur in the line of sight towards strong radio continuum sources. We have developed a method for simultaneously finding and fitting HI absorption lines in radio data by using multi-nested sampling, a Bayesian Monte Carlo algorithm. The method is tested on a simulated ASKAP data cube, and is shown to be reliable at detecting absorption lines in low signal-to-noise data without the need to smooth or alter the data. Estimation of the local Bayesian evidence statistic provides a quantitative criterion for assigning significance to a detection and selecting between competing analytical line-profile models.Comment: 8 pages, 5 figures and 1 table; accepted for publication in PAS