Polyaniline nanofiber based surface acoustic wave gas sensors - effect of nanofiber diameter on H2 response

A template-free rapidly mixed reaction was employed to synthesize polyaniline nanofibers using chemical oxidative polymerization of aniline. Hydrochloric acid (HCl) and camphor sulfonic acid (CSA) were used in the synthesis to obtain 30- and 50-nm average diameter polyaniline nanofibers. The nanofibers were deposited onto layered ZnO/64 degrees YX LiNbO3 surface-acoustic-wave transducers. The sensors were tested toward hydrogen (H-2) gas while operating at room temperature. The dopant for the polyaniline nanofiber synthesis was found to have a significant effect on the device sensitivity. The sensor response was found to be larger for the 50-nmdiameter CSA-doped nanofiber based sensors, while the response and recovery times were faster for the 30-nm diameter HCl-doped nanofibers

Simulation and Optimization of Waste Heat to Electricity through Organic Rankine Cycles (ORCs): a Case Study in an Oil Refinery

Energy efficiency has become a global problem that is detrimental to the chemical industries technically, economically and to the environment. Organic Rankine Cycle (ORC) is a promising technology that can solve this problem by recovering heat from low-grade waste heat sources by using organic working fluids. The heat source for the ORC system used in this article is air leaving air coolers in an oil refinery with a temperature of 140o C. The heat exchanger data for this refinery was used in the simulation of a basic cycle and a regenerative cycle using ASPEN HYSYS V.10. These ORC systems were simulated using hydrocarbons, refrigerants, and alternative refrigerants as the working fluids to compare their performance at three different condensation temperatures which are 15o C, 35o C, and 50o C. The system was optimized using the HYSYS optimizer to reach the optimum conditions for each working fluid. Results of this study have proven that the alternative working fluids R1234ze (Z) and R1224yd (Z) perform very well when compared to hydrocarbon working fluids and outperform the regular refrigerants. For the basic cycle which yielded the optimum results, R1234ze (Z) produced 1258.90 kW of turbine work and has a thermal efficiency of 11.31%. Hence, they are promising working fluids and are highly recommended to be used in the future since they perform highly economically in addition to being environmentally friendly

Influence of cracks on the soil-atmosphere interaction: numerical coupled model of thermo- atmosphereporous media

Soil shrinks as it desiccates, and the magnitude of shrinkage can be large for clayey soils. The drying of soil leads to cracks formation, causing high suctions to develop within. Cracks expose the deep soil and more evaporation can be expected in dry periods. To illustrate the effect of cracking, a numerical model of soil-atmosphere interaction has been developed taking into account the thermo-fluid coupling of an unsaturated clay soil. The model is used to simulate the evolution of evaporation during the drying process. The main results show a significant influence of the presence of cracks on the evaporation. This study also offers a simple method for taking into account the presence of cracks in the soil-atmosphere exchange

Congenital coronary artery anomalies in adult population detected using dual source ECG-gated CTA in a single institution

Background: Congenital anomalies of the coronary arteries (CAs) are rare and are often diagnosed incidentally during a conventional coronary angiography. Recently, the incidence of these congenital defects is on the rise particularly after the introduction of the electrocardiography (ECG) gated coronary computed tomographic angiography (CCTA). This innovative radiological screening modality has led to the most precise mapping of the course of the CAs on computed tomographic scan. The aim of the study is to determine the prevalence and describe the CAs congenital anomalies and their variations in Kuwaiti population at a single institution experience. Materials and methods: We analysed the CCTA data obtained consecutively from 842 patients (2013–2014), retrospectively. The inclusion criteria for patients’ selection were: atypical chest pain, equivocal ECG, assessment of patency of coronary stents or grafts and pre-operative screening. Information was acquiesced using a dual-source CT scanner with ECG gating. Results: Data analysis revealed that 22 (2.61%) patients were found to have CA anomalies out of the 842 patients who underwent CCTA. Out of these CA anomalies, 13 cases showed more than two ostia, 7 cases showed the ectopic origin of a CA from opposite sinus or non-aortic sinus, 2 cases showed single coronary ostium and 1 case showed coronary artery with pulmonary fistula. Also, myocardial bridging was identified in 78 (9.26%) patients whereas ramus intermedius branch was identified in 160 (19%) patients. Conclusions: The prevalence of CA anomalies in Kuwait was 2.6%, which is relatively higher than previously reported studies from different countries

H2 and NO2 gas sensors with ZnO nanobelt layer on 36° LiTaO3 and 64° LiNbO3 SAW transducers

Single crystal nanobelts of ZnO were synthesized and deposited onto 36° YX LiTaO<sub>3</sub> and 64° YX LiNbO<sub>3</sub> surface acoustic wave (SAW) devices for gas sensing applications. Sensor response, defined as the change in resonant frequency, was measured for H<sub>2</sub> and NO<sub>2</sub> between 20 and 200°C. Measured sensor responses were 3.5 kHz towards 10 ppm NO<sub>2</sub> for a 64° LiNbO<sub>3</sub> SAW transducer operating at 160°C and 3 kHz towards 1% H<sub>2</sub> for a 36° LiTaO<sub>3</sub> SAW transducer operating at 185°C temperature

Titanium dioxide-based 64 degrees YX LiNbO3 surface acoustic wave hydrogen gas sensors

Amorphous titanium dioxide (TiO2) and gold (Au) doped TiO2-based surface acoustic wave (SAW) sensors have been investigated as hydrogen gas detectors. The nanocrystal-doped TiO2 films were synthesized through a sol-gel route, mixing a Ti-butoxide-based solution with diluted colloidal gold nanoparticles. The films were deposited via spin coating onto 64° YX LiNbO3 SAW transducers in a helium atmosphere. The SAW gas sensors were operated at various temperatures between 150 and 310°C. It was found that gold doping on TiO2 increased the device sensitivity and reduced the optimum operating temperature

Titanium dioxide based 64° YX LiNbO3 surface acoustic wave hydrogen gas sensors

Amorphous titanium dioxide (TiO2) and gold (Au) doped TiO2-based surface acoustic wave (SAW) sensors have been investigated as hydrogen gas detectors. The nanocrystal-doped TiO2 films were synthesized through a sol-gel route,mixing a Ti-butoxide-based solution with diluted colloidal gold nanoparticles. The films were deposited via spin coating onto 64\ub0 YX LiNbO3 SAWtransducers in a helium atmosphere. The SAW gas sensors were operated at various temperatures between 150 and 310 \ub0C. It was found that gold doping on TiO2 increased the device sensitivity and reduced the optimum operating temperature

Collaborative workshops at scale: a method for non-facilitated virtual collaborative design workshops

This article introduces a method for conducting a fully online collaborative design workshop requiring no facilitation which we refer to as a Self-guided Collaborative Online Workshop (SCOW). The article provides three main contributions. Firstly, we present a process for the conversion of a face-to-face facilitated design workshop into a SCOW using a method we call the “playboard” which draws on concepts from CSCL literature. Secondly, we evaluate the efficacy of SCOWs using an iterative evaluation with 75 participants, including measures for participant satisfaction, subjective and objective learning outcomes, quality of the online and self-guided experience, and comparison with face-to-face workshops. Results across all measures indicate that the self-guided workshop was as successful as the in-person facilitated original. Moreover, participants reported advantages of the more scalable format including improved access to those with non-visible disabilities and in the Global South. Finally, based on our findings, we present a set of recommendations for others interested in using SCOWs as an inclusive and scalable way to support collaborative experiences