Characteristics of fine particulate non-polar organic compounds in Guangzhou during the 16th Asian Games: Effectiveness of air pollution controls

The concentrations of organic compounds, including n-alkanes and polycyclic aromatic hydrocarbons (PAHs), in fine particles (PM2.5) were measured in an urban area of Guangzhou before, during, and after the 16th Asian Games (9-30 November 2010). Higher average concentrations of n-alkanes and PAHs occurred in the nighttime, presumably due to a restriction on motor vehicle operation during the day and the accumulation of pollutants due to temperature inversions at night. The carbon preference index, contributions of wax n-alkanes, and PAHs diagnostic ratios indicated that the main sources of n-alkanes and PAHs were anthropogenic, especially motor vehicle emissions. The CMAQ model was used to estimate the percentages of biogenic organic aerosol in the total organic aerosol, then the ratios of source marker PAHs to biogenic organic carbon were used to evaluate the air pollution control policies effectiveness during the Asian Games.</p

Associations between toenail arsenic concentration and dietary factors in a New Hampshire population

BACKGROUND: Dietary factors such as folate, vitamin B12, protein, and methionine are important for the excretion of arsenic via one-carbon metabolism in undernourished populations exposed to high levels of arsenic via drinking water. However, the effects of dietary factors on toenail arsenic concentrations in well-nourished populations exposed to relatively low levels of water arsenic are unknown. METHODS: As part of a population-based case–control study of skin and bladder cancer from the USA, we evaluated relationships between consumption of dietary factors and arsenic concentrations in toenail clippings. Consumption of each dietary factor was determined from a validated food frequency questionnaire. We used general linear models to examine the associations between toenail arsenic and each dietary factor, taking into account potentially confounding effects. RESULTS: As expected, we found an inverse association between ln-transformed toenail arsenic and consumption of vitamin B12 (excluding supplements) and animal protein. Unexpectedly, there were also inverse associations with numerous dietary lipids (e.g., total fat, total animal fat, total vegetable fat, total monounsaturated fat, total polyunsaturated fat, and total saturated fat). Finally, increased toenail arsenic concentrations were associated with increased consumption of long chain n-3 fatty acids. CONCLUSION: In a relatively well-nourished population exposed to relatively low levels of arsenic via water, consumption of certain dietary lipids may decrease toenail arsenic concentration, while long chain n-3 fatty acids may increase toenail arsenic concentration, possibly due to their association with arsenolipids in fish tissue