A Case of Chronic Infectious Arthritis of the Temporomandibular Joint Associated with Osteomyelitis without Malocclusion

Infectious arthritis of the temporomandibular joint (TMJ) is rare, and previous reports have identified malocclusion resulting from condylar deformity and displacement of the condyle as one of the clinical characteristics of the disease. Here we report the case of a 33-year-old man with chronic infectious arthritis of the TMJ without malocclusion associated with osteomyelitis of the right mandible. Based on radiological findings of more prominent inflammation at the TMJ than in other regions and on the observed efficacy of antibiotic administration, we made a diagnosis of suppurative arthritis of the TMJ. Based on our empirical experience, including the present case, we speculate that refusal to cooperate with medical care may be a factor in the development of infectious arthritis of the TMJ

TRICE‐2/SuperDARN Observations and Comparison With the Associated MMS Magnetopause Crossing

Two sounding rockets, designated TRICE‐2, were launched on 8 December 2018 into the northern cusp region. The two rockets were designated the high‐ and low‐flyers, respectively, and launched 2 min apart to investigate cusp structures, specifically their spatial or temporal nature. 2 hr prior to the cusp encounter by the TRICE‐2 rockets, the MMS satellites, located in the magnetopause boundary layer, observed switching ion beams under very similar IMF conditions as later observed by TRICE‐2. The observed ion beam switch in the boundary layer defined the location of the primary dayside X‐line. Both, TRICE‐2 and MMS, also observed the signatures of multiple X‐lines at the magnetopause, overlapping ion‐energy dispersions in the cusp and counterstreaming ion beams in the magnetopause boundary layer, respectively. In addition to the TRICE‐2 cusp observations, ionospheric convection patterns from the SuperDARN radar are used to explain the vastly different cusp ion signatures observed by the TRICE‐2 rockets. While the high‐flyer rocket progressed north through the center of the cusp, the low‐flyer rocket drifted off to the east and crossed into the dusk convection cell, traveling perpendicular to the ionospheric convection direction before reaching the poleward oriented section of the convection cell also observed by the high‐flyer counterpart.</p

Data-driven design of metal–organic frameworks for wet flue gas CO<inf>2</inf> capture

Limiting the increase of CO2 in the atmosphere is one of the largest challenges of our generation1. Because carbon capture and storage is one of the few viable technologies that can mitigate current CO2 emissions2, much effort is focused on developing solid adsorbents that can efficiently capture CO2 from flue gases emitted from anthropogenic sources3. One class of materials that has attracted considerable interest in this context is metal–organic frameworks (MOFs), in which the careful combination of organic ligands with metal-ion nodes can, in principle, give rise to innumerable structurally and chemically distinct nanoporous MOFs. However, many MOFs that are optimized for the separation of CO2 from nitrogen4–7 do not perform well when using realistic flue gas that contains water, because water competes with CO2 for the same adsorption sites and thereby causes the materials to lose their selectivity. Although flue gases can be dried, this renders the capture process prohibitively expensive8,9. Here we show that data mining of a computational screening library of over 300,000 MOFs can identify different classes of strong CO2-binding sites—which we term ‘adsorbaphores’—that endow MOFs with CO2/N2 selectivity that persists in wet flue gases. We subsequently synthesized two water-stable MOFs containing the most hydrophobic adsorbaphore, and found that their carbon-capture performance is not affected by water and outperforms that of some commercial materials. Testing the performance of these MOFs in an industrial setting and consideration of the full capture process—including the targeted CO2 sink, such as geological storage or serving as a carbon source for the chemical industry—will be necessary to identify the optimal separation material