The relation of steady evaporating drops fed by an influx and freely evaporating drops

We discuss a thin film evolution equation for a wetting evaporating liquid on a smooth solid substrate. The model is valid for slowly evaporating small sessile droplets when thermal effects are insignificant, while wettability and capillarity play a major role. The model is first employed to study steady evaporating drops that are fed locally through the substrate. An asymptotic analysis focuses on the precursor film and the transition region towards the bulk drop and a numerical continuation of steady drops determines their fully non-linear profiles. Following this, we study the time evolution of freely evaporating drops without influx for several initial drop shapes. As a result we find that drops initially spread if their initial contact angle is larger than the apparent contact angle of large steady evaporating drops with influx. Otherwise they recede right from the beginning

Exploration of Shared Genetic Architecture Between Subcortical Brain Volumes and Anorexia Nervosa

In MRI scans of patients with anorexia nervosa (AN), reductions in brain volume are often apparent. However, it is unknown whether such brain abnormalities are influenced by genetic determinants that partially overlap with those underlying AN. Here, we used a battery of methods (LD score regression, genetic risk scores, sign test, SNP effect concordance analysis, and Mendelian randomization) to investigate the genetic covariation between subcortical brain volumes and risk for AN based on summary measures retrieved from genome-wide association studies of regional brain volumes (ENIGMA consortium, n = 13,170) and genetic risk for AN (PGC-ED consortium, n = 14,477). Genetic correlations ranged from − 0.10 to 0.23 (all p > 0.05). There were some signs of an inverse concordance between greater thalamus volume and risk for AN (permuted p = 0.009, 95% CI: [0.005, 0.017]). A genetic variant in the vicinity of ZW10, a gene involved in cell division, and neurotransmitter and immune system relevant genes, in particular DRD2, was significantly associated with AN only after conditioning on its association with caudate volume (pFDR = 0.025). Another genetic variant linked to LRRC4C, important in axonal and synaptic development, reached significance after conditioning on hippocampal volume (pFDR = 0.021). In this comprehensive set of analyses and based on the largest available sample sizes to date, there was weak evidence for associations between risk for AN and risk for abnormal subcortical brain volumes at a global level (that is, common variant genetic architecture), but suggestive evidence for effects of single genetic markers. Highly powered multimodal brain- and disorder-related genome-wide studies are needed to further dissect the shared genetic influences on brain structure and risk for AN

A new continuum model of the incoherent interface compared with growth of a spinel rim on an olivine grain

In a polymorphic change in which the phases differ only by a reversible difference in specific volume, kinematics requires a unit mass to suffer deviatoric strain in the instant it is transformed. Unlike the Eshelby stress–free strain, this strain is a property of the motion. Its existence must be considered when formulating the constitutive relation for the product of an incoherent transformation. To show this, two models are compared: in both, the (Nabarro) condition of vanishing shear stress is imposed at the incoherent interface; they differ only in the treatment of the deviatoric strain at issue. In the existing model, deviatoric stress within a unit mass of product is determined by total deviatoric strain from its initial state as parent phase. In the new model, lattice reconstruction is assumed to erase all memory within the unit mass of deviatoric strain suffered before, or during, its transformation. The existing model is not consistent with experiments on the olivine spinel–phase change in single crystals. It predicts that when the pressure applied exceeds a critical value, samples should transform completely at almost constant rate; instead, growth is seen to slow, and may even cease. The new model predicts this. Without adjustable constants, fair agreement is obtained with experiments on samples having 75–200 ppmw of water. Because elastic deformation by itself can explain those observations, the very thin rims seen on even drier samples suggest that water may be essential to lattice reconstruction in this phase change

The evaporating meniscus in a channel

We consider the evaporating meniscus of a perfectly wetting liquid in a channel whose superheated walls are at common temperature. Heat flows by pure conduction from the walls to the phase interface; there, evaporation induces a small-scale liquid flow concentrated near the contact lines. Liquid is continually fed to the channel, so that the interface is stationary, but distorted by the pressure differences caused by the small-scale flow. To determine the heat flow, we make a systematic analysis of this free-boundary problem in the limit of vanishing capillary number based on the velocity of the induced flow. Because surface tension is then large, the induced flow can distort the phase interface only in a small inner region near the contact lines; the effect is to create an apparent contact angle Θ depending on capillary number. Though, in general, there can be significant heat flow within that small inner region, the presence of an additional small parameter in the problem implies that, in practice, heat flow is significant only within the large outer region where the interface shape is determined by hydrostatics and Θ. We derive a formula for the heat flow, and show that the channel geometry affects the heat flow only through the value of the interface curvature at the contact line. Consequently, the heat flow relation for a channel can be applied to other geometries

Interface Kinetics, Grain-Scale Deformation, and Polymorphism

Deviatoric stress generated within subducting slabs by the olivine-spinel transformation has been modeled by assuming the phases to be simply connected rather than comprising a mixture in which one phase is embedded within another. Here, we use a simplified model to explain how transformation strain is incorporated into a continuum model, and we then use the simplified model to explain quantitatively the origin of the unreasonably large deviatoric stresses predicted by existing slab models. We review experiments on the transformation of single-crystal samples and argue that they are consistent with the occurrence, at the grain scale, of deviatoric stresses comparable with those predicted (erroneously) to exist at the slab scale by those slab models. Using a simple example, we show that although large deviatoric stresses can exist at the grain scale, their average over a sample containing many grains can be hydrostatic. This leads us to the problem of modeling the microscale structure. We outline the thermodynamics needed for such nonhydrostatic systems, and we illustrate their use and implications with examples

Interface Kinetics, Grain-Scale Deformation, and Polymorphism

Deviatoric stress generated within subducting slabs by the olivine-spinel transformation has been modeled by assuming the phases to be simply connected rather than comprising a mixture in which one phase is embedded within another. Here, we use a simplified model to explain how transformation strain is incorporated into a continuum model, and we then use the simplified model to explain quantitatively the origin of the unreasonably large deviatoric stresses predicted by existing slab models. We review experiments on the transformation of single-crystal samples and argue that they are consistent with the occurrence, at the grain scale, of deviatoric stresses comparable with those predicted (erroneously) to exist at the slab scale by those slab models. Using a simple example, we show that although large deviatoric stresses can exist at the grain scale, their average over a sample containing many grains can be hydrostatic. This leads us to the problem of modeling the microscale structure. We outline the thermodynamics needed for such nonhydrostatic systems, and we illustrate their use and implications with examples

Kinematics and thermodynamics of a growing rim of high-pressure phase

We have reanalysed the problem of growth of a dense product rim on a sphere of parent phase. To decouple the problem of calculating deformation from rheology, we assume spherical symmetry, and incompressible phases. Within the product, the radial deviatoric strain and its time-derivative prove to be of opposite sign: strain is compressive, but the strain rate is tensile. Further, the radial deviatoric strain in the new product adjacent to the interface is invariant in time. Propagation of the phase interface is determined by a competition between two mechanisms: as an element of material is transformed, its shear strain energy is increased; and the core pressure performs work compressing it. For elastic phases, this competition results in metastability. Within a certain pressure range, either phase can occur alone, but the two phases can not coexist. Because this result is inconsistent with experiments by Kawazoe et al. (2010) in which a rim of high-pressure phase (wadsleyite) coexists with a central core of low-pressure phase (olivine), we then incorporate plastic flow. Assuming perfect plasticity, we show that for a given applied pressure exceeding the coexistence pressure, a rim of product can now nucleate if the excess pressure δ. p exceeds a critical value depending on yield stress. Increasing δ. p above this value allows product to grow into the parent phase. There are now two possibilities, depending on the value of δ. p. Growth may eventually cease to produce a state in which the product rim is in equilibrium with a parent core; or growth may follow a more complicated path: within a range of excess pressures, the growth rate can decrease strongly from its initial value to produce a quasi-equilibrium state, before increasing again to a rate similar to that at which transformation began. We interpret these results to mean that if δ. p is increased slowly in a series of experiments with constant yield stress, the sample passes through a series of equilibria until δ. p is large enough for the second type of growth to be possible transformation is then completed rapidly on the timescale set by interface kinetics. This result may be relevant to the problem of deep earthquakes. Lastly, using existing experiments in which a wadsleyite rim grows on an olivine sphere, we apply the theory to estimate the yield strength of wadsleyite: our estimates are consistent with measurements by independent methods. © 2014 Elsevier B.V