67,119 research outputs found
K X-Ray Energies and Transition Probabilities for He-, Li- and Be-like Praseodymium ions
Theoretical transition energies and probabilities for He-, Li- and Be-like
Praseodymium ions are calculated in the framework of the multi-configuration
Dirac-Fock method (MCDF), including QED corrections. These calculated values
are compared to recent experimental data obtained in the Livermore SuperEBIT
electron beam ion trap facility
Comments on "State equation for the three-dimensional system of 'collapsing' hard spheres"
A recent paper [I. Klebanov et al. \emph{Mod. Phys. Lett. B} \textbf{22}
(2008) 3153; arXiv:0712.0433] claims that the exact solution of the
Percus-Yevick (PY) integral equation for a system of hard spheres plus a step
potential is obtained. The aim of this paper is to show that Klebanov et al.'s
result is incompatible with the PY equation since it violates two known cases:
the low-density limit and the hard-sphere limit.Comment: 4 pages; v2: title chang
On the equivalence between the energy and virial routes to the equation of state of hard-sphere fluids
The energy route to the equation of state of hard-sphere fluids is
ill-defined since the internal energy is just that of an ideal gas and thus it
is independent of density. It is shown that this ambiguity can be avoided by
considering a square-shoulder interaction and taking the limit of vanishing
shoulder width. The resulting hard-sphere equation of state coincides exactly
with the one obtained through the virial route. Therefore, the energy and
virial routes to the equation of state of hard-sphere fluids can be considered
as equivalent.Comment: 2 page
QED and relativistic corrections in superheavy elements
In this paper we review the different relativistic and QED contributions to
energies, ionic radii, transition probabilities and Land\'e -factors in
super-heavy elements, with the help of the MultiConfiguration Dirac-Fock method
(MCDF). The effects of taking into account the Breit interaction to all orders
by including it in the self-consistent field process are demonstrated. State of
the art radiative corrections are included in the calculation and discussed. We
also study the non-relativistic limit of MCDF calculation and find that the
non-relativistic offset can be unexpectedly large.Comment: V3, May 31st, 200
How `sticky' are short-range square-well fluids?
The aim of this work is to investigate to what extent the structural
properties of a short-range square-well (SW) fluid of range at a
given packing fraction and reduced temperature can be represented by those of a
sticky-hard-sphere (SHS) fluid at the same packing fraction and an effective
stickiness parameter . Such an equivalence cannot hold for the radial
distribution function since this function has a delta singularity at contact in
the SHS case, while it has a jump discontinuity at in the SW case.
Therefore, the equivalence is explored with the cavity function .
Optimization of the agreement between y_{\sw} and y_{\shs} to first order
in density suggests the choice for . We have performed Monte Carlo (MC)
simulations of the SW fluid for , 1.02, and 1.01 at several
densities and temperatures such that , 0.2, and 0.5. The
resulting cavity functions have been compared with MC data of SHS fluids
obtained by Miller and Frenkel [J. Phys: Cond. Matter 16, S4901 (2004)].
Although, at given values of and , some local discrepancies
between y_{\sw} and y_{\shs} exist (especially for ), the SW
data converge smoothly toward the SHS values as decreases. The
approximate mapping y_{\sw}\to y_{\shs} is exploited to estimate the internal
energy and structure factor of the SW fluid from those of the SHS fluid. Taking
for y_{\shs} the solution of the Percus--Yevick equation as well as the
rational-function approximation, the radial distribution function of the
SW fluid is theoretically estimated and a good agreement with our MC
simulations is found. Finally, a similar study is carried out for short-range
SW fluid mixtures.Comment: 14 pages, including 3 tables and 14 figures; v2: typo in Eq. (5.1)
corrected, Fig. 14 redone, to be published in JC
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