16 research outputs found
Evidence for short range orbital order in paramagnetic insulating (Al,V)_2O_3
The local structure of (Al_0.06V_0.94)_2O_3 in the paramagnetic insulating
(PI) and antiferromagnetically ordered insulating (AFI) phase has been
investigated using hard and soft x-ray absorption techniques. It is shown that:
1) on a local scale, the symmetry of the vanadium sites in both the PI and the
AFI phase is the same; and 2) the vanadium 3d - oxygen 2p hybridization, as
gauged by the oxygen 1s absorption edge, is the same for both phases, but
distinctly different from the paramagnetic metallic phase of pure V_2O_3. These
findings can be understood in the context of a recently proposed model which
relates the long range monoclinic distortion of the antiferromagnetically
ordered state to orbital ordering, if orbital short range order in the PI phase
is assumed. The measured anisotropy of the x-ray absorption spectra is
discussed in relation to spin-polarized density functional calculations.Comment: 8 pages, 5 figure
Notes on the algebraic curves in (p,q) minimal string theory
Loop amplitudes in (p,q) minimal string theory are studied in terms of the
continuum string field theory based on the free fermion realization of the KP
hierarchy. We derive the Schwinger-Dyson equations for FZZT disk amplitudes
directly from the W_{1+\infty} constraints in the string field formulation and
give explicitly the algebraic curves of disk amplitudes for general
backgrounds. We further give annulus amplitudes of FZZT-FZZT, FZZT-ZZ and ZZ-ZZ
branes, generalizing our previous D-instanton calculus from the minimal unitary
series (p,p+1) to general (p,q) series. We also give a detailed explanation on
the equivalence between the Douglas equation and the string field theory based
on the KP hierarchy under the W_{1+\infty} constraints.Comment: 61 pages, 1 figure, section 2.5 and Appendix B added, references
added, final version to appear in JHE
Diffusion of gold nanoclusters on graphite
We present a detailed molecular-dynamics study of the diffusion and
coalescence of large (249-atom) gold clusters on graphite surfaces. The
diffusivity of monoclusters is found to be comparable to that for single
adatoms. Likewise, and even more important, cluster dimers are also found to
diffuse at a rate which is comparable to that for adatoms and monoclusters. As
a consequence, large islands formed by cluster aggregation are also expected to
be mobile. Using kinetic Monte Carlo simulations, and assuming a proper scaling
law for the dependence on size of the diffusivity of large clusters, we find
that islands consisting of as many as 100 monoclusters should exhibit
significant mobility. This result has profound implications for the morphology
of cluster-assembled materials
Nanoparticles for Applications in Cellular Imaging
In the following review we discuss several types of nanoparticles (such as TiO2, quantum dots, and gold nanoparticles) and their impact on the ability to image biological components in fixed cells. The review also discusses factors influencing nanoparticle imaging and uptake in live cells in vitro. Due to their unique size-dependent properties nanoparticles offer numerous advantages over traditional dyes and proteins. For example, the photostability, narrow emission peak, and ability to rationally modify both the size and surface chemistry of Quantum Dots allow for simultaneous analyses of multiple targets within the same cell. On the other hand, the surface characteristics of nanometer sized TiO2allow efficient conjugation to nucleic acids which enables their retention in specific subcellular compartments. We discuss cellular uptake mechanisms for the internalization of nanoparticles and studies showing the influence of nanoparticle size and charge and the cell type targeted on nanoparticle uptake. The predominant nanoparticle uptake mechanisms include clathrin-dependent mechanisms, macropinocytosis, and phagocytosis
Sandwich nucleic acid hybridization: a method with a universally usable labeled probe for various specific tests
Nucleic acid hybridization is widely used for scientific applications but essentially restricted to specialized laboratories. The use of recombinant m 13 phages as hybridization probes (Hu and Messing (1980) Gene 17, 271; Messing (1983) Methods Enzymol. 101, 20) offers a considerable advantage over the commonly used recombinant plasmids as the preparation of the DNA probe is very simple and it can easily be labeled directly, e.g. with isotopes with long half-life like 125I (Commerford (1971) Biochemistry 10, 11 (1983); Gu et al. (1983) Cancer (China) 2, 129; Han and Harding (1983) Nucleic Acids Res. 11, 14) and used for hybridization. However, as the application of nucleic acid hybridization for diagnostic and epidemiological purposes becomes almost unavoidable, the logistic problems of keeping numerous individually labeled hybridization probes increase considerably and may reach prohibitory levels in less well-equipped laboratories. In a new sandwich technique, the first step involves hybridization with an unlabeled recombinant m 13 DNA carrying an insert of the desired specificity. In a second step a universally usable labeled probe directed against the m 13 part of the recombinant phage DNA is applied. This reduces considerably the problems of preparing and keeping multiple labeled probes in stock
Extreme values of elastic strain and energy in sine-Gordon multi-kink collisions
In our recent study the maximal values of kinetic and potential energy
densities that can be achieved in the collisions of slow kinks in the
sine-Gordon model were calculated analytically (for , and 3) and
numerically (for ). However, for many physical applications it is
important to know not only the total potential energy density but also its two
components (the on-site potential energy density and the elastic strain energy
density) as well as the extreme values of the elastic strain, tensile
(positive) and compressive (negative). In the present study we give (i) the two
components of the potential energy density and (ii) the extreme values of
elastic strain. Our results suggest that in multi-soliton collisions the main
contribution to the potential energy density comes from the elastic strain, but
not from the on-site potential. It is also found that tensile strain is usually
larger than compressive strain in the core of multi-soliton collision.Comment: 9 pages, 6 figures. arXiv admin note: text overlap with
arXiv:1605.0976