Extensional rheology and elastic instabilities of a wormlike micellar solution in a microfluidic cross-slot device

Wormlike micellar surfactant solutions are encountered in a wide variety of important applications, including enhanced oil recovery and ink-jet printing, in which the fluids are subjected to high extensional strain rates. In this contribution we present an experimental investigation of the flow of a model wormlike micellar solution (cetyl pyridinium chloride and sodium salicylate in deionised water) in a well-defined stagnation point extensional flow field generated within a microfluidic cross-slot device. We use micro-particle image velocimetry (m-PIV) and full-field birefringence microscopy coupled with macroscopic measurements of the bulk pressure drop to make a quantitative characterization of the fluid’s rheological response over a wide range of deformation rates. The flow field in the micromachined cross-slot is first characterized for viscous flow of a Newtonian fluid, and m-PIV measurements show the flow field remains symmetric and stable up to moderately high Reynolds number, Re z 20, and nominal strain rate, _3nom z 635 s1. By contrast, in the viscoelastic micellar solution the flow field remains symmetric only for low values of the strain rate such that _3nom # lM1, where lM ¼ 2.5 s is the Maxwell relaxation time of the fluid. In this stable flow regime the fluid displays a localized and elongated birefringent strand extending along the outflow streamline from the stagnation point, and estimates of the apparent extensional viscosity can be obtained using the stressoptical rule and from the total pressure drop measured across the cross-slot channel. For moderate deformation rates (_3nom $ lM1) the flow remains steady, but becomes increasingly asymmetric with increasing flow rate, eventually achieving a steady state of complete anti-symmetry characterized by a dividing streamline and birefringent strand connecting diagonally opposite corners of the cross-slot. Eventually, as the nominal imposed deformation rate is increased further, the asymmetric divided flow becomes time dependent. These purely elastic instabilities are reminiscent of those observed in crossslot flows of polymer solutions, but seem to be strongly influenced by the effects of shear localization of the micellar fluid within the microchannels and around the re-entrant corners of the cross-slot

Microstructural dynamics and rheology of worm-like diblock copolymer nanoparticle dispersions under a simple shear and a planar extensional flow

We investigate the shear and extensional flow behavior of dispersions composed of two types of worm-like nanoparticles (WLNPs) with comparable cross-sectional diameters, similar persistence lengths but differing contour lengths, and thus differing flexibility. By measuring the flow-induced birefringence (FIB) of WLNP dispersions in two contrasting microfluidic devices, we obtain an experimental quantification of the role of shearing and planar extensional flows at aligning a short and stiff WLNP (S-WLNP) and a relatively long and flexible WLNP (L-WLNP). We show that shear and extensional flows induce the alignment of both types of WLNPs. However, extensional deformations are more effective than shear deformations at triggering the onset of alignment of the WLNP. The difference between shear and extensional deformations for WLNP alignment is explained based on the ratio of extensional and shear viscosity of the solvent fluid (Trouton ratio of the solvent) and a structural parameter related to the WLNP extensibility and flexibility. Under shear flow, these WLNP dispersions display shear-thinning behavior, with an exponential reduction in viscosity with increasing alignment. Under extensional flow, the WLNP alignment leads to extensional thinning, making WLNP ideal additives for industrial and biotechnology formulations exposed to extensional dominated flows (e.g., jetting, spraying, and printing processes)

Non-Newtonian flow of polymer solutions around spheres and through porous media

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Measuring the vulnerability of marine social-ecological systems: A prerequisite for the identification of climate change adaptations

Reducing the vulnerability of coastal communities to marine climate change requires that communities have some intrinsic capacity to adapt. To assist adaptation planning and the implementation of adaptation strategies, identifying barriers and enablers to adaptation is important. Adaptive capacity, resource dependence, local climate change exposure and biological sensitivity were used to assess socioeconomic vulnerability to climate change in three Australian coastal communities: St Helens, Tasmania; Bowen, Queensland; and Geraldton, Western Australia. Higher adaptive capacity was associated with larger population size (i.e., Geraldton) whereas greater resource dependence, and lower human and natural capital were associated with smaller populations (St Helens and Bowen). Socioeconomic vulnerability was greatly influenced by climate exposure and sensitivity with the moderately sized Bowen having the highest socioeconomic vulnerability to climate change. Adaptation strategies that utilized available assets, improved adaptive capacity, or reduced socioeconomic vulnerability were identified in partnership with local communities, including increased and diversified employment opportunities, the re-establishment of local fish markets, and improved education and communication. The level of resources, or “capitals,” available to communities can indicate where barriers and enablers to adaptation exist. Identified barriers to adaptation included a heavy reliance on one sector for employment and a lack of physical capital. We demonstrate that knowledge of intrinsic community characteristics can be beneficial for prioritizing adaptation actions to reduce socioeconomic vulnerability to marine climate change