14 research outputs found
Statistical mechanics of permanent random atomic and molecular networks: Structure and heterogeneity of the amorphous solid state
Under sufficient permanent random covalent bonding, a fluid of atoms or small
molecules is transformed into an amorphous solid network. Being amorphous,
local structural properties in such networks vary across the sample. A natural
order parameter, resulting from a statistical-mechanical approach, captures
information concerning this heterogeneity via a certain joint probability
distribution. This joint probability distribution describes the variations in
the positional and orientational localization of the particles, reflecting the
random environments experienced by them, as well as further information
characterizing the thermal motion of particles. A complete solution, valid in
the vicinity of the amorphous solidification transition, is constructed
essentially analytically for the amorphous solid order parameter, in the
context of the random network model and approach introduced by Goldbart and
Zippelius [Europhys. Lett. 27, 599 (1994)]. Knowledge of this order parameter
allows us to draw certain conclusions about the stucture and heterogeneity of
randomly covalently bonded atomic or molecular network solids in the vicinity
of the amorphous solidification transition. Inter alia, the positional aspects
of particle localization are established to have precisely the structure
obtained perviously in the context of vulcanized media, and results are found
for the analogue of the spin glass order parameter describing the orientational
freezing of the bonds between particles.Comment: 31 pages, 5 figure
Connecting the vulcanization transition to percolation
The vulcanization transition is addressed via a minimal
replica-field-theoretic model. The appropriate long-wave-length behavior of the
two- and three-point vertex functions is considered diagrammatically, to all
orders in perturbation theory, and identified with the corresponding quantities
in the Houghton-Reeve-Wallace field-theoretic approach to the percolation
critical phenomenon. Hence, it is shown that percolation theory correctly
captures the critical phenomenology of the vulcanization transition associated
with the liquid and critical states.Comment: 9 pages, 5 figure
Randomly Crosslinked Macromolecular Systems: Vulcanisation Transition to and Properties of the Amorphous Solid State
As Charles Goodyear discovered in 1839, when he first vulcanised rubber, a
macromolecular liquid is transformed into a solid when a sufficient density of
permanent crosslinks is introduced at random. At this continuous equi- librium
phase transition, the liquid state, in which all macromolecules are
delocalised, is transformed into a solid state, in which a nonzero fraction of
macromolecules have spontaneously become localised. This solid state is a most
unusual one: localisation occurs about mean positions that are distributed
homogeneously and randomly, and to an extent that varies randomly from monomer
to monomer. Thus, the solid state emerging at the vulcanisation transition is
an equilibrium amorphous solid state: it is properly viewed as a solid state
that bears the same relationship to the liquid and crystalline states as the
spin glass state of certain magnetic systems bears to the paramagnetic and
ferromagnetic states, in the sense that, like the spin glass state, it is
diagnosed by a subtle order parameter.
In this review we give a detailed exposition of a theoretical approach to the
physical properties of systems of randomly, permanently crosslinked
macromolecules. Our primary focus is on the equilibrium properties of such
systems, especially in the regime of Goodyear's vulcanisation transition.Comment: Review Article, REVTEX, 58 pages, 3 PostScript figure
Somatosensory conflicts in complex regional pain syndrome type 1 and fibromyalgia syndrome
The somatosensory system is an integral component of the motor control system that facilitates the recognition of location and experience of peripheral stimuli, as well as body part position and differentiation. In chronic pain, this system may be disrupted by alterations in peripheral and cortical processing. Clinical symptoms that accompany such changes can be difficult for patients to describe and health care practitioners to comprehend. Patients with chronic pain conditions such as complex regional pain syndrome or fibromyalgia typically describe a diverse range of somatosensory changes. This article describes how sensory information processing can become disturbed in fibromyalgia syndrome and complex regional pain syndrome and how symptoms can potentially be explained by the mechanisms that generate them. © 2009 Springer Science+Business Media, LLC