8,658 research outputs found
Chemistry of fuel deposits and sediments and their predursors
The mechanism of solid deposit formation on hot engine parts from turbine fuels is investigated. Deposit formation is associated with oxidation of the hydrocarbon fuel. Therefore, oxidation rates and soluble gum formation were measured for several jet turbine fuels and pure hydrocarbon mixtures. Experiments were performed at 130 C using thermal initiation and at 100 C using ditertiary butyl peroxide as a chemical initiator. Correlation of the data shows that the ratio of rate of oxidation to rate of gum formation for a single fuel is not much affected by experimental conditions, even though there are differences in the abilities of different hydrocarbons to initiate and continue the oxidation. This indicates a close association of gum formation with the oxidation process. Oxidations of n-dodecane, tetralin and the more unstable jet fuels are autocatalytic, while those of 2-ethylnaphthalene and a stable jet fuel are self-retarding. However, the ratio of oxidation rate to gum formation rate appear to be nearly constant for each substrate. The effect of oxygen pressure on gum and oxidation formation was also studied. Dependence of gum formation on the concentration of initiator at 100 C is discussed and problems for future study are suggested
Oxidation and formation of deposit precursors in hydrocarbon fuels
The oxidation of two jet turbine fuels and some pure hydrocarbons was studied at 130 C with and without the presence of small amounts of N-methyl pyrrole (NMP) or indene. Tendency to form solid-deposit precursors was studied by measuring soluble gum formation as well as dimer and trimer formation using field ionization mass spectrometry. Pure n-dodecane oxidized fastest and gave the smallest amount of procursors. An unstable fuel oil oxidized much slower but formed large amounts of precursors. Stable Jet A fuel oxidized slowest and gave little precursors. Indene either retarded or accelerated the oxidation of n-dodecane, depending on its concentration, but always caused more gum formation. The NMP greatly retarded n-dodecane oxidation but accelerated Jet A oxidation and greatly increased the latter's gum formation. In general, the additive reacted faster and formed most of the gum. Results are interpreted in terms of classical cooxidation theory. The effect of oxygen pressure on gum formation is also reported
HID-1 controls formation of large dense core vesicles by influencing cargo sorting and trans-Golgi network acidification
Large dense core vesicles (LDCVs) mediate the regulated release of neuropeptides and peptide hormones. They form at the trans-Golgi network (TGN), where their soluble content aggregates to form a dense core, but the mechanisms controlling biogenesis are still not completely understood. Recent studies have implicated the peripheral membrane protein HID-1 in neuropeptide sorting and insulin secretion. Using CRISPR/Cas9, we generated HID-1 KO rat neuroendocrine cells, and we show that the absence of HID-1 results in specific defects in peptide hormone and monoamine storage and regulated secretion. Loss of HID-1 causes a reduction in the number of LDCVs and affects their morphology and biochemical properties, due to impaired cargo sorting and dense core formation. HID-1 KO cells also exhibit defects in TGN acidification together with mislocalization of the Golgi-enriched vacuolar H+-ATPase subunit isoform a2. We propose that HID-1 influences early steps in LDCV formation by controlling dense core formation at the TGN.</jats:p
Influence of surface passivation on ultrafast carrier dynamics and terahertz radiation generation in GaAs
The carrier dynamics of photoexcited electrons in the vicinity of the surface
of (NH4)2S-passivated GaAs were studied via terahertz (THz) emission
spectroscopy and optical-pump THz-probe spectroscopy. THz emission spectroscopy
measurements, coupled with Monte Carlo simulations of THz emission, revealed
that the surface electric field of GaAs reverses after passivation. The
conductivity of photoexcited electrons was determined via optical-pump
THz-probe spectroscopy, and was found to double after passivation. These
experiments demonstrate that passivation significantly reduces the surface
state density and surface recombination velocity of GaAs. Finally, we have
demonstrated that passivation leads to an enhancement in the power radiated by
photoconductive switch THz emitters, thereby showing the important influence of
surface chemistry on the performance of ultrafast THz photonic devices.Comment: 4 pages, 3 figures, to appear in Applied Physics Letter
Wavelength Tunability of Ion-bombardment Induced Ripples on Sapphire
A study of ripple formation on sapphire surfaces by 300-2000 eV Ar+ ion
bombardment is presented. Surface characterization by in-situ synchrotron
grazing incidence small angle x-ray scattering and ex-situ atomic force
microscopy is performed in order to study the wavelength of ripples formed on
sapphire (0001) surfaces. We find that the wavelength can be varied over a
remarkably wide range-nearly two orders of magnitude-by changing the ion
incidence angle. Within the linear theory regime, the ion induced viscous flow
smoothing mechanism explains the general trends of the ripple wavelength at low
temperature and incidence angles larger than 30. In this model, relaxation is
confined to a few-nm thick damaged surface layer. The behavior at high
temperature suggests relaxation by surface diffusion. However, strong smoothing
is inferred from the observed ripple wavelength near normal incidence, which is
not consistent with either surface diffusion or viscous flow relaxation.Comment: Revtex4, 19 pages, 10 figures with JPEG forma
Effect of Three Gorges Reservoir Backwater on Bed Load Transport Discharge of Chongqing Reach by Backwater of Three Gorges Reservoir in Upper Yangtze River
Source: ICHE Conference Archive - https://mdi-de.baw.de/icheArchive
Coupled cavity QED for coherent control of photon transmission (I): Green function approach for hybrid systems with two-level doping
This is the first one of a series of our papers theoretically studying the
coherent control of photon transmission along the coupled resonator optical
waveguide (CROW) by doping artificial atoms for various hybrid structures. We
will provide the several approaches correspondingly based on Green function,
the mean field method and spin wave theory et al. In the present paper we adopt
the two-time Green function approach to study the coherent transmission photon
in a CROW with homogeneous couplings, each cavity of which is doped by a
two-level artificial atom. We calculate the two-time correlation function for
photon in the weak-coupling case. Its poles predict the exact dispersion
relation, which results in the group velocity coherently controlled by the
collective excitation of the doping atoms. We emphasize the role of the
population inversion of doping atoms induced by some polarization mechanism.Comment: 11 pages, 9 figure
Combinatorial screening yields discovery of 29 metal oxide photoanodes for solar fuel generation
Combinatorial synthesis combined with high throughput electrochemistry enabled discovery of 29 ternary oxide photoanodes, 15 with visible light response for oxygen evolution. Y₃Fe₅O₁₂ and trigonal V₂CoO₆ emerge as particularly promising candidates due to their photorepsonse at sub-2.4 eV illumination
Spectral analysis of Gene co-expression network of Zebrafish
We analyze the gene expression data of Zebrafish under the combined framework
of complex networks and random matrix theory. The nearest neighbor spacing
distribution of the corresponding matrix spectra follows random matrix
predictions of Gaussian orthogonal statistics. Based on the eigenvector
analysis we can divide the spectra into two parts, first part for which the
eigenvector localization properties match with the random matrix theory
predictions, and the second part for which they show deviation from the theory
and hence are useful to understand the system dependent properties. Spectra
with the localized eigenvectors can be characterized into three groups based on
the eigenvalues. We explore the position of localized nodes from these
different categories. Using an overlap measure, we find that the top
contributing nodes in the different groups carry distinguished structural
features. Furthermore, the top contributing nodes of the different localized
eigenvectors corresponding to the lower eigenvalue regime form different
densely connected structure well separated from each other. Preliminary
biological interpretation of the genes, associated with the top contributing
nodes in the localized eigenvectors, suggests that the genes corresponding to
same vector share common features.Comment: 6 pages, four figures (accepted in EPL
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