2,355 research outputs found
Role of p-f Hybridization in the Metal-Non-Metal Transition of PrRu4P12
Electronic state evolution in the metal-non-metal transition of PrRu4P12 has
been studied by X-ray and polarized neutron diffraction experiments. It has
been revealed that, in the low-temperature non-metallic phase, two inequivalent
crystal-field (CF) schemes of Pr3+ 4f^2 electrons with Gamma_1 and Gamma_4^(2)
ground states are located at Pr1 and Pr2 sites forming the bcc unit cell
surrounded by the smaller and larger cubic Ru-ion sublattices, respectively.
This modulated electronic state can be explained by the p-f hybridization
mechanism taking two intermediate states of 4f^1 and 4f^3. The p-f
hybridization effect plays an important role for the electronic energy gain in
the metal-non-metal transition originated from the Fermi surface nesting.Comment: 5 pages, 5 figures. Accepted by J. Phys. Soc. Jp
XANES study of rare-earth valency in LRu4P12 (L = Ce and Pr)
Valency of Ce and Pr in LRu4P12 (L = Ce and Pr) was studied by L2,3-edge
x-ray absorption near-edge structure (XANES) spectroscopy. The Ce-L3 XANES
spectrum suggests that Ce is mainly trivalent, but the 4f state strongly
hybridizes with ligand orbitals. The band gap of CeRu4P12 seems to be formed by
strong hybridization of 4f electrons. Pr-L2 XANES spectra indicate that Pr
exists in trivalent state over a wide range in temperature, 20 < T < 300 K. We
find that the metal-insulator (MI) transition at TMI = 60 K in PrRu4P12 does
not originate from Pr valence fluctuation.Comment: 4 page
Optical Conductivity and Electronic Structure of CeRu4Sb12 under High Pressure
Optical conductivity [s(w)] of Ce-filled skutterudite CeRu4Sb12 has been
measured at high pressure to 8 GPa and at low temperature, to probe the
pressure evolution of its electronic structures. At ambient pressure, a
mid-infrared peak at 0.1 eV was formed in s(w) at low temperature, and the
spectral weight below 0.1 eV was strongly suppressed, due to a hybridization of
the f electron and conduction electron states. With increasing external
pressure, the mid-infrared peak shifts to higher energy, and the spectral
weight below the peak was further depleted. The obtained spectral data are
analyzed in comparison with band calculation result and other reported physical
properties. It is shown that the electronic structure of CeRu4Sb12 becomes
similar to that of a narrow-gap semiconductor under external pressure.Comment: 8 pages, 9 figure
Shock compression and isentropic release of granite
New equation of state data for a weathered granite shocked to about 125 GPa are reported and combined with the Westerly granite data of McQueen, Marsh & Fritz (1967). The shock velocity (U_s)-particle velocity (U_p) relations can be fitted with two linear regressions: U_s= 4.40 + 0.6U_p for a range of U_p up to about 2 km s^(-1) and U_s= 2.66 + 1.49U_p for a range of about 2 to 5 km s^(-1). The third-order Birch-Murnaghan equation of state parameters are K_(os) = 51-57 GPa and K'_(os) = 1.4-1.8 for the low-pressure regime and K_(os) = 251 ± 30 GPa and an assumed K'_(os) = 4 for the high-pressure regime. Compressive waveforms in dry and water-saturated granite were measured at 10-15 GPa using the VISAR technique. The measured wave profiles were successfully modelled using a Maxwellian stress-relaxation material model. Water-saturated granite is characterized by a ~25 per cent lower yield strength and a ~75 per cent longer material relaxation time than dry granite
Decoupling between Field-instabilities of Antiferromagnetism and Pseudo-metamagnetism in Rh-doped CeRu2Si2 Kondo Lattice
Doping Kondo lattice system CeRu2Si2 with Rh-8% (Ce(Ru0.92Rh0.08)2Si2) leads
to drastic consequences due to the mismatch of the lattice parameters between
CeRu2Si2 and CeRh2Si2. A large variety of experiments clarifies the unusual
properties of the ground state induced by the magnetic field from longitudinal
antiferromagnetic (AF) mode at H = 0 to polarized paramagnetic phase in very
high magnetic field. The separation between AF phase, paramagnetic phase and
polarized paramagnetic phase varying with temperature, magnetic field and
pressure is discussed on the basis of the experiments down to very low
temperature. Similarities and differences between Rh and La substituted alloys
are discussed with emphasis on the competition between transverse and
longitudinal AF modes, and ferromagnetic fluctuations.Comment: 10 pages, 21 figures, accepted for publication in J. Phys. Soc. Jp
Unconventional resistivity at the border of metallic antiferromagnetism in NiS2
We report low-temperature and high-pressure measurements of the electrical
resistivity \rho(T) of the antiferromagnetic compound NiS_2 in its
high-pressure metallic state. The form of \rho(T) suggests that metallic
antiferromagnetism in NiS_2 is quenched at a critical pressure p_c=76+-5 kbar.
Near p_c the temperature variation of \rho(T) is similar to that observed in
NiS_{2-x}Se_x near the critical composition x=1 where the Neel temperature
vanishes at ambient pressure. In both cases \rho(T) varies approximately as
T^{1.5} over a wide range below 100 K. However, on closer analysis the
resistivity exponent in NiS_2 exhibits an undulating variation with temperature
not seen in NiSSe (x=1). This difference in behaviour may be due to the effects
of spin-fluctuation scattering of charge carriers on cold and hot spots of the
Fermi surface in the presence of quenched disorder, which is higher in NiSSe
than in stoichiometric NiS_2.Comment: 7 page
Magnetic Phase Diagram and Metal-Insulator Transition of NiS2-xSex
Magnetic phase diagram of NiS2-xSex has been reexamined by systematic studies
of electrical resistivity, uniform magnetic susceptibility and neutron
diffraction using single crystals grown by a chemical transport method. The
electrical resistivity and the uniform magnetic susceptibility exhibit the same
feature of temperature dependence over a wide Se concentration. A distinct
first order metal-insulator (M-I) transition accompanied by a volume change was
observed only in the antiferromagnetic ordered phase for 0.50<x<0.59. In this
region, the M-I transition makes substantial effects to the thermal evolution
of staggered moments. In the paramagnetic phase, the M-I transition becomes
broad; both the electrical resistivity and the uniform magnetic susceptibility
exhibit a broad maximum around the temperatures on the M-I transition-line
extrapolated to the paramagnetic phase.Comment: 6 pages, 8 figures, corrected EPS fil
Spin fluctuations in CuGeO probed by light scattering
We have measured temperature dependence of low-frequency Raman spectra in
CuGeO, and have observed the quasi-elastic scattering in the
polarization above the spin-Peierls transition temperature. We attribute it to
the fluctuations of energy density in the spin system. The magnetic specific
heat and an inverse of the magnetic correlation length can be derived from the
quasi-elastic scattering. The inverse of the magnetic correlation length is
proportional to at high temperatures. We compare the
specific heat with a competing- model. This model cannot explain
quantitatively both the specific heat and the magnetic susceptibility with the
same parameters. The origin of this discrepancy is discussed.Comment: 17 pages, REVTeX, 5 Postscript figures; in press in PR
Multipole State of Heavy Lanthanide Filled Skutterudites
We discuss multipole properties of filled skutterudites containing heavy
lanthanide Ln from a microscopic viewpoint on the basis of a seven-orbital
Anderson model. For Ln=Gd, in contrast to naive expectation, quadrupole moments
remain in addition to main dipole ones. For Ln=Ho, we find an exotic state
governed by octupole moment. For Ln=Tb and Tm, no significant multipole moments
appear at low temperatures, while for Ln=Dy, Er, and Yb, dipole and
higher-order multipoles are dominant. We briefly discuss possible relevance of
these multipole states with actual materials.Comment: 5 pages, 3 figure
Study of Removal of Volatile Organic Compound (VOC) and Related Atomic and Molecular Processes in Plasma Reactors
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