2,527 research outputs found
Dielectric Response in Microscopically Heterogeneous Dielectrics: Example of KTaO_3:Nb
New experimental data on solid solutions of quantum paraelectrics with
KTaO_3:Nb as an example are considered within a framework of a quantum theory
of ferroelectric phase transitions. In order to describe the effect of local
heterogeneities a percolation type theory together with a random field approach
were employed.Comment: 4 figure
In situ visualization of Ni-Nb bulk metallic glasses phase transition
We report the results of the Ni-based bulk metallic glass structural
evolution and crystallization behavior in situ investigation. The X-ray
diffraction (XRD), transmission electron microscopy (TEM), nano-beam
diffraction (NBD), differential scanning calorimetry (DSC), radial distribution
function (RDF) and scanning probe microscopy/spectroscopy (STM/STS) techniques
were applied to analyze the structure and electronic properties of Ni63.5Nb36.5
glasses before and after crystallization. It was proved that partial surface
crystallization of Ni63.5Nb36.5 can occur at the temperature lower than for the
full sample crystallization. According to our STM measurements the primary
crystallization is originally starting with the Ni3Nb phase formation. It was
shown that surface crystallization drastically differs from the bulk
crystallization due to the possible surface reconstruction. The mechanism of
Ni63.5Nb36.5 glass alloy 2D-crystallization was suggested, which corresponds to
the local metastable (3x3)-Ni(111) surface phase formation. The possibility of
different surface nano-structures development by the annealing of the
originally glassy alloy in ultra high vacuum at the temperature lower, than the
crystallization temperature was shown. The increase of mean square surface
roughness parameter Rq while moving from glassy to fully crystallized state can
be caused by concurrent growth of Ni3Nb and Ni6Nb7 bulk phases. The simple
empirical model for the estimation of Ni63.5Nb36.5 cluster size was suggested,
and the obtained values (7.64 A, 8.08 A) are in good agreement with STM
measurements data (8 A-10 A)
The super-oscillating superlens
We demonstrate a lens that creates a sub-wavelength focal spot beyond the near-field by exploiting the phenomenon of super-oscillation
Noninvasive Embedding of Single Co Atoms in Ge(111)2x1 Surfaces
We report on a combined scanning tunneling microscopy (STM) and density
functional theory (DFT) based investigation of Co atoms on Ge(111)2x1 surfaces.
When deposited on cold surfaces, individual Co atoms have a limited diffusivity
on the atomically flat areas and apparently reside on top of the upper
pi-bonded chain rows exclusively. Voltage-dependent STM imaging reveals a
highly anisotropic electronic perturbation of the Ge surface surrounding these
Co atoms and pronounced one-dimensional confinement along the pi-bonded chains.
DFT calculations reveal that the individual Co atoms are in fact embedded in
the Ge surface, where they occupy a quasi-stationary position within the big
7-member Ge ring in between the 3rd and 4th atomic Ge layer. The energy needed
for the Co atoms to overcome the potential barrier for penetration in the Ge
surface is provided by the kinetic energy resulting from the deposition
process. DFT calculations further demonstrate that the embedded Co atoms form
four covalent Co-Ge bonds, resulting in a Co4+ valence state and a 3d5
electronic configuration. Calculated STM images are in perfect agreement with
the experimental atomic resolution STM images for the broad range of applied
tunneling voltages.Comment: 19 pages, 15 figures, 3 table
Coulomb singularity effects in tunnelling spectroscopy of individual impurities
Non-equilibrium Coulomb effects in resonant tunnelling processes through deep
impurity states are analyzed. It is shown that Coulomb vertex corrections to
the tunnelling transfer amplitude lead to a power-law singularity in current-
voltage characteristicsComment: 7 pages, 2 figure
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